CAS: 258864-54-9; Trihexyl(Tetradecyl)Phosphonium Chloride

该化合物是属于磷盐类的一种离子液体,其特点是长的烷链,有助于其独特的特性,例如低挥发性和高热稳定性.六氟基和四十二基基组的存在,提高了其在有机溶剂中的溶解性,同时提供了一定程度的疏水性.这种化合物通常表现出高程度的离子传导性,使其在各种电化学应用中有用.此外,它有一个相对较低的熔点,允许它保持在室温中的液体状态,促进其在多种化学工艺中的使用.三氟乙基磷也因其在催化,提取过程中和作为有机合成的溶剂的潜在用途而闻名.其环境影响是一个持续研究的领域,因为离子液体往往被视为传统有机溶剂的更环保替代品.

结构式图片

相似化合物

81741-28-8 81741-28-8 15294-63-0

欧盟法规

REACH注册ECHA物质C&L通报

上下游产品

myristyl chloride trihexylphosphine watertetradecyl(trihexyl)phosphonium bistriflamide Heptanophenone 1-phenylpentadecan-1-one 1-(2-aminophenyl)pentadecan-1-one

合成工艺路线路线简述

    📜氯代十四烷,三己基膦 反应 24.0H,以90%的收率获得三己基(四癸基)氯化膦
    参考文献:Phosphonium Ionic Liquid Catalyzed An Efficient Synthesis Of Chalcones
    标题:Phosphonium Ionic Liquid Catalyzed An Efficient Synthesis Of Chalcones
    摘要:描述了一种使用膦盐离子液体催化剂[phosilcl]合成查耳酮的清洁高效方法.该方法具有多种优势,如温和的反应条件,简便的后处理过程,高产率且环境友好.此外,绿色溶剂离子液体在后续反应中被回收并重复使用多次.
    Doi:10.2174/157017809789124966

    海关参考信息

    专利信息


    专利号:US-8637695-B2
    优先权日:2011-12-30
    标 题:Synthesis of organohalosilane monomers from conventionally uncleavable Direct Process Residue
    发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
    权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
    摘要:Disclosed herein is a catalytic process for the synthesis of organohalosilane monomers from tetraorganodihalodisilanes and other compounds that are not cleaved during the conventional hydrochlorination of Direct Process Residue. The process is characterized by the use of a catalyst containing (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

    专利号:US-8703952-B2
    优先权日:2008-12-12
    标题:Synthesis of 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline and analogues and intermediates
    发明人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID
    权利人:WILLIAMSON CRAIG; STOREY JOHN MERVYN DAVID; WISTA LAB LTD
    摘要:The present invention pertains generally to methods of preparing certain 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds and their analogues, and especially to methods of preparing dimebon. The present invention also pertains to methods of preparing certain intermediate compounds which find use in the synthesis of the 9-(arylalkyl)-1,2,3,4-tetrahydro-γ-carboline compounds.

    专利号:US-2010191010-A1
    优先权日:2007-07-02
    标题 :Process for the synthesis of carbamates using co2
    发明人:BOSMAN JORIS KAREL PETER; CARR ROBERT HENRY
    权利人:HUNTSMAN INT LLC
    摘要:Process for the synthesis of non cyclic carbamate derivatives from amine compounds, alcohols and CO 2 in the presence of ionic liquids and optionally in the presence of a base.

    专利号:US-8697901-B2
    优先权日:2011-12-30
    标题 :Synthesis of organohalosilane monomers via enhanced cleavage of direct process residue
    发明人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID
    权利人:LEWIS KENRICK MARTIN; NEELY JOHN DAVID; MOMENTIVE PERFORMANCE MAT INC
    摘要:Discloses herein is a catalytic process for producing organohalosilane monomers from a high-boiling residue resulting from the Direct Reaction of an organohalide with silicon. The high-boiling residue contains more conventionally cleavable compounds than conventionally uncleavable compounds. The process includes heating the residue in the presence of a catalyst comprising (1) one or more heterocyclic amines and/or one or more heterocyclic ammonium halides, and (2) one or more quaternary Group 15 onium compounds.

    专利号:US-2007100184-A1
    优先权日:2005-10-27
    标题 :Alkylation of aromatic compounds
    发明人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    权利人:HARMER MARK A; JUNK CHRISTOPHER P; VICKERY JEMMA
    摘要:The present invention relates to the synthesis of alkylated aromatic compounds using ionic liquids as the solvent. Alkylated aromatic compounds are synthesized by reacting an aromatic compound with a monoolefin in the presence of an acid catalyst.

    专利号:US-12168720-B2
    优先权日:2019-02-19
    标 题:Synthesis of functionalized polymers through devulcanization from waste containing elastomers
    发明人:DEZ ISABELLE; GAUMONT ANNIE-CLAUDE; NOËL JEAN-NICOLAS
    权利人:CENTRE NAT RECH SCIENT; UNIV CAEN; ECOLE NAT SUPERIEURE DINGENIEURS DE CAEN
    摘要:A method for synthesising polymers through devulcanisation from waste containing elastomers, the method including:a) contacting the waste containing elastomers with a solvent in the presence of a devulcanisation agent,b) heating the mixture produced in step a), at a temperature of between 20° C. and 250° C. for a period of between 15 minutes and 24 hours in the presence of a devulcanisation agent, the concentration of devulcanisation agent, and the ratio between the concentration of devulcanisation agent, expressed as parts per hundred of elastomer (phr) and a volume of solvent, expressed in ml, is:greater than 0.3 phr/ml of solvent or less than 0.2 phr/ml of solvent when the method is carried out in air,greater than 0.06 phr/ml of solvent when the method is carried out in an inert atmosphere.

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    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Pajkert, R.; Röschenthaler, G.-V., Science of Synthesis Knowledge Updates, (2022) 1, 397.
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