CAS: 1814-88-6; 1,1,1,2,2-Pentafluoropropane

该化合物是属于全氟化合物类别的氟化碳氢化合物,其特点是分子式C3H2F5,表明三碳丙烷主干柱有5个氟原子;该化合物是室温无色气体,具有低毒性,适合各种应用,包括制冷剂和气溶胶推进剂;氟化亚原子的高电子能有助于其稳定性和低再活动性,这是许多工业工艺中可取的特性;此外,与其他氟化化合物相比,1,11,1,2,2-五氟丙烷的全球升温潜力相对较低,使用中的环境因素也与此相一致;必须谨慎处理这一物质,因为如果释放到大气中,它会助长臭氧消耗;总体而言,它的独特特性使它在化学和材料科学领域成为有价值的化合物.

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CAS号431-31-2 1,1,1,2,3-五氟丙烷 | CAS号2730-62-3 2-氯-3,3,3-三氟丙烯 | CAS号593-53-3 氟甲烷 | CAS号79-38-9 三氟氯乙烯 | CAS号422-56-0 3,3-二氯-1,1,1,2,... | CAS号507-55-1 1,3-二氯-1,1,2,2,... | CAS号422-05-9 1H,1H-五氟丙醇 | CAS号116-14-3 四氟乙烯 | CAS号338-75-0 2,3-二氯-1,1,1-三氟丙烷 | CAS号1645-83-6 1,3,3,3-四氟-1-丙烯 | CAS号721945-86-4 2,3,3,3-tetrafl... | CAS号754-12-1 2,3,3,3-四氟-1-丙烯

合成工艺路线路线简述

    📜1,1,1,2,2-Pentachloropropane置于氯化锑(V) 氢氟酸体系中,化学反应 2.0H,反应生成1,1,1,2,2-五氟丙烷
    参考文献:Wo2009/3157
    标题:Wo2009/3157

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    专利信息


    专利号:US-9126995-B2
    优先权日:2011-11-08
    标题:Method for catalytic asymmetric synthesis of optically active isoxazoline compound and optically active isoxazoline compound
    发明人:TOYAMA KEN-ICHI; MORIYAMA YUJI; MATOBA KAZUTAKA; YAOSAKA MANABU; IKEDA EITATSU
    权利人:NISSAN CHEMICAL IND LTD
    摘要:There is provided a method for catalytic asymmetric synthesis of optically active isoxazoline compound and an optically active isoxazoline compound. A method for catalytic asymmetric synthesis of optically active isoxazoline compound of a formula (6) including reacting an α,β-unsaturated carbonyl compound of a formula (1) and a hydroxylamine in a solvent in the presence of a base by adding a chiral phase transfer catalyst. An optically active isoxazoline compound of a formula (13) that can be synthesized by the method.

    专利号:US-7767826-B2
    优先权日:2007-10-05
    标题 :Process for the synthesis of L-(+)-ergothioneine
    发明人:TRAMPOTA MIROSLAV
    权利人:PHARMATECH INTERNATIONAL INC
    摘要:This invention relates to a novel process for the preparation of optically pure L-(+)-ergothioneine. The process for the chemical synthesis of L-ergothioneine comprises steps which consist of reacting L-histidine alkyl ester with an acid halide, chloroformate or pyrocarbonate in the presence of a base, hydrolysis of the alkyl-(S,Z)-2,4,5-triamidopent-4-enoate to obtain a (S)-alkyl 2,5-diamido-4-oxopentanoate, acid catalyzed hydrolysis of the (S)-alkyl 2,5-diamido-4-oxopentanoate followed by reaction with a metal thiocyanate to obtain the thiohistidine, protection of the sulfur of thiohistidine as the tert-butyl thioether, dialkylation of the primary amine to obtain a tertiary amine, quaternization of the tertiary amine, and removal of the protecting group to obtain the desired (S)-3-(2-mercapto-1H-imidazol-5-yl)-2-(trialkylammonio)propanoate (I). This process affords a better yield and is capable of practical application at large scale.

    专利号:WO-2015155713-A1
    优先权日:2014-04-09
    标题 :Process for the regioselective synthesis of 1,3, 4 -substituted pyrazoles
    发明人:MEAZZA GIOVANNI; MEREGHETTI PIERANGELO; SILLANI LAURA; FORGIA DANIELE; BELLANDI PAOLO
    权利人:ISAGRO SPA
    摘要:A process is described for the synthesis of pyrazoles having general formula (I) comprising the following steps: a) a mixture comprising an alkyl-hydrazine having formula (II) RNH-NH 2 and a compound having general formula (III) Rx 1 -X 1 -Rx-X 2 -Rx 2 , b) the mixture obtained in step a) is reacted with a compound having formula (IV), obtaining a 1,3,4-substituted pyrazole having general formula (I), according to the reaction scheme 1.

    专利号:US-9512250-B2
    优先权日:2012-02-23
    标 题 :Manganese catalyzed photopolymerization of fluorinated monomers
    发明人:ASANDEI ALEXANDRU D
    权利人:UNIV CONNECTICUT
    摘要:The disclosure discloses initiating systems for the radical polymerization of alkenes, and especially fluorine substituted alkenes. The polymerization is catalyzed by a metal carbonyl, preferably manganese carbonyl. The polymerization is initiated directly from alkyl halides at room temperature under visible white light. The polymers also allow the synthesis of block copolymers. The process comprises polymerizing at least one alkene monomer in the presence of a halide radical initiator, carbonyl catalyst and a solvent, under reaction conditions and for a time sufficient to polymerize the at least one alkene monomer to form a polymer. The present disclosure provides a method for living polymerization of alkene monomers which provides a high level of macromolecular control over the polymerization process and which leads to uniform and controllable polymeric products. This disclosure also provides a method for activating any halide (Cl, Br, I) chain ends of such polymers for the synthesis of block copolymerizations.

    专利号:US-2014199585-A1
    优先权日:2013-01-17
    标 题 :Low Symmetry Molecules And Phosphonium Salts, Methods Of Making And Devices Formed There From
    发明人:RUPERT BENJAMIN L; BEER LEANNE
    权利人:ESIONIC ES INC
    摘要:Synthesis of molecules and salts is disclosed having low average symmetry and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as electrolytes in energy storage devices such as batteries, electrochemical double layer capacitors (EDLCs) or supercapacitors or ultracapacitors, electrolytic capacitors, as electrolytes in dye-sensitized solar cells (DSSCs), as electrolytes in fuel cells, as a heat transfer medium, high temperature reaction and/or extraction media, among other applications. In particular, synthesis methods and processes to form molecules and salts having low average symmetry using mixed Grignard reagents are disclosed.

    专利号:US-8563789-B2
    优先权日:2007-06-27
    标题 :Process for the manufacture of hydrofluoroolefins
    发明人:ELSHEIKH MAHER Y; BONNET PHILIPPE; CHEN BENJAMIN BIN
    权利人:ELSHEIKH MAHER Y; BONNET PHILIPPE; CHEN BENJAMIN BIN; ARKEMA INC
    摘要:In this invention we are disclosing a process for the synthesis of hydrocchlorofluoro olefins (HCFO) and/or hydrofluoroolefins (HFO). The process is based on the steps of fluorination of hydrochloropropenes or hydrochloropropanes to form hydrochlorofluoropropenes and/or hydrofluoropropenes, followed by gas phase, catalytic fluorination of the hydrochlorofluoropropenes to form hydrofluoropropenes.

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    参考文献:10.1055/s-0041-1738615
    摘要:Base-Promoted Reductive Coupling of (Trifluoromethyl)arenes. Synfacts. 2022 Sep 20;18(10):1139. doi: 10.1055/s-0041-1738615.
    参考文献:10.1007/s10765-023-03219-w
    摘要:Tang N, Gu W, Sun D, Tang X, Yang Z, Lu J. Isothermal Vapor–Liquid Equilibrium for the Binary System of Trans-1,3,3,3-tetrafluoropropene and 1,1,1,3,3-Pentafluoropropane. Int J Thermophys. 2023 Jun 28;44(8). doi: 10.1007/s10765-023-03219-w.
    参考文献:10.1007/978-3-031-53364-8_2
    摘要:Yadav K, Sircar A, Shah M. Sustainable Power Generation Cycles Using Geothermal Water. 2024. In: Geothermal Fields of India.
    参考文献:10.1007/978-3-031-97693-3_14
    摘要:Wijayasekera SC, Hewage K, Razi F, Sadiq R. Beyond Hydrogen: The Multigeneration Potential of Waste Gasification for Multiple Value-Added Products. 2025. In: Lecture Notes in Civil Engineering.
    参考文献:10.1016/j.jbmt.2007.11.005
    摘要:Kostopoulos D, Rizopoulos K. Effect of topical aerosol skin refrigerant (Spray and Stretch technique) on passive and active stretching. Journal of Bodywork and Movement Therapies. 2008 Apr;12(2):96–104. doi: 10.1016/j.jbmt.2007.11.005.
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