CAS: 12068-85-8; Irondisulfide

该化合物是化学化合物,其特点是独特的金属光线和青黄黄黄,通常出现在立方晶体中,通常在沉积岩石,热液静脉中发现,并成为各种采矿活动的副产品,而铁矿石含量高,可引起环境关切,当它氧化,产生硫酸和导致酸性矿排水时,可引发环境关切;该化合物在环境条件下相对稳定,但可与强酸和强碱发生反应;就其物理特性而言,FES2在莫赫斯规模上坚硬6至6.5,其具体重度从4.8到5.2不等;Pyriter还被用于各种工业应用,包括硫磺和硫酸的生产,并有可能用于可再生能源技术,如太阳能电池,但其经济价值往往因与采矿废物和环境影响有关而被掩盖.

结构式图片

相似化合物

12068-85-8 1308-56-1

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disulfur thiozone sulfur iron

合成工艺路线路线简述

    📜硫二聚体,Thiozone,Sulfur,铁粉 以 Solid Matrix 用作溶剂,化学反应生成Iron Sulfide,白铁矿,硫精砂,,Monoiron(Iv) Tetrasulfide
    参考文献:8族过渡金属硫化物分子的红外光谱和密度泛函理论计算
    标题:8族过渡金属硫化物分子的红外光谱和密度泛函理论计算
    摘要:小硫分子与激光烧蚀后的过量氩气中的fe,Ru和os原子发生反应并在7 K处冷凝.通过硫34同位素位移,硫同位素混合物的光谱以及密度的频率从基体红外光谱中识别出反应产物功能计算.对于第8组金属,分别在540.2,535.5和537.5 Cm-1处观测到ms 2二硫化物分子的最强吸收,并且将523.2 Cm-1的谱带分配给固态氩中的fes振动基波.所述的fes 2-在542.1厘米在光谱中检测到阴离子-1.Rus 2吸收显示出已解决的天然钌同位素分裂.还提供了具有不同结构的侧面结合的m(s 2)异构体和ms 4分子的证据,包括fe(s 2)2,(s 2)rus 2和四面体oss 4.尽管oso 4是一个众所周知的分子,但我们认为这是oss 4的首次实验观察.
    Doi:10.1021/jp900994C

    专利信息


    专利号:US-9935319-B2
    优先权日:2011-06-17
    标题 :Synthesis of hetero ionic compounds using dialkylcarbonate quaternization
    发明人:FRIESEN CODY A; WOLFE DEREK; JOHNSON PAUL BRYAN
    权利人:FLUIDIC INC
    摘要:Methods of preparing hetero ionic complexes, and ionic liquids from bisulfate salts of heteroatomic compounds using dialkylcarbonates as a primary quaternizing reactant are disclosed. Also disclosed are methods of making electrochemical cells comprising the ionic liquids, and an electrochemical cell comprising an alkaline electrolyte and a hetero ionic complex additive.

    专利号:US-8673260-B2
    优先权日:2012-01-04
    标 题 :Development of earth-abundant mixed-metal sulfide nanoparticles for use in solar energy conversion
    发明人:PLASS KATHERINE
    权利人:FRANKLIN AND MARSHALL COLLEGE
    摘要:This invention relates to a process for the phase-controlled synthesis of ternary and quaternary mixed-metal sulfide nanoparticles by reacting soft metal ions with hard metal ions in a high-boiling organic solvent in the presence of a complexing and activating ligands to control the reactivity of the metal ions. Ternary and quaternary mixed metal sulfides nanoparticles of copper, sulfur, and iron, aluminum, tin, and silicon are preferred. This invention also relates to the phase controlled preparation of polymorphs of bornite nanoparticles and the phase controlled preparation of stabilized α- and γ-chalconite nanoparticles.

    专利号:US-10337030-B2
    优先权日:2016-07-07
    标 题 :Microbially-mediated method for synthesis of metal chalcogenide nanoparticles
    发明人:MOON JI WON; PHELPS TOMMY JOE; OREMLAND RONALD; GRAHAM DAVID E; IVANOV ILIA N; JACOBS CHRISTOPHER B; JANG GYOUNG GUG; KIDDER MICHELLE K; JOSHI POORAN C; ARMSTRONG BETH L
    权利人:UT BATTELLE LLC; U S GEOLOGICAL SURVEY
    摘要:A method for producing metal chalcogenide nanoparticles, the method comprising: (i) producing hydrogen chalcogenide-containing vapor from a microbial source, wherein said microbial source comprises: (a) chalcogen-reducing microbes capable of producing hydrogen chalcogenide vapor from a chalcogen-containing source; (b) a culture medium suitable for sustaining said chalcogen-reducing microbes; (c) at least one chalcogen-containing compound that can be converted to hydrogen chalcogenide vapor by said chalcogen-reducing microbes; and (d) at least one nutritive compound that provides donatable electrons to said chalcogen-reducing microbes during consumption of the nutritive compound by said chalcogen-reducing microbes; and (ii) directing said hydrogen chalcogenide-containing vapor into a metal-containing solution comprising a metal salt dissolved in a solvent to produce metal chalcogenide nanoparticles in said solution, wherein said chalcogen is sulfur or selenium, and said chalcogenide is sulfide or selenide, respectively. The invention is also directed to metal chalcogenide nanoparticle compositions produced as above and having distinctive properties.

    专利号:US-2016251367-A1
    优先权日:2014-11-13
    标 题:Synthesis of tritoqualine salts
    发明人:TERRASSE GAETAN; COTEREAU Vincent; BUR CATHERINE
    权利人:CHRYSALIS PHARMA
    摘要:A formulation of tritoqualine salt having the purpose of improving the solubility of these novel compounds and having the following general structure:

    专利号:US-9768333-B2
    优先权日:2009-02-03
    标题:Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles
    发明人:PHELPS TOMMY J; LAUF ROBERT J; MOON JI-WON; RONDINONE ADAM JUSTIN; LOVE LONNIE J; DUTY CHAD EDWARD; MADDEN ANDREW STEPHEN; LI YILIANG; IVANOV ILIA N; RAWN CLAUDIA JEANETTE
    权利人:UT BATTELLE LLC; UNIV TENNESSEE RES FOUND
    摘要:The invention is directed to a method for producing non-oxide semiconductor nanoparticles, the method comprising: (a) subjecting a combination of reaction components to conditions conducive to microbially-mediated formation of non-oxide semiconductor nanoparticles, wherein said combination of reaction components comprises i) anaerobic microbes, ii) a culture medium suitable for sustaining said anaerobic microbes, iii) a metal component comprising at least one type of metal ion, iv) a non-metal component comprising at least one non-metal selected from the group consisting of S, Se, Te, and As, and v) one or more electron donors that provide donatable electrons to said anaerobic microbes during consumption of the electron donor by said anaerobic microbes; and (b) isolating said non-oxide semiconductor nanoparticles, which contain at least one of said metal ions and at least one of said non-metals. The invention is also directed to non-oxide semiconductor nanoparticle compositions produced as above and having distinctive properties.

    专利号:US-10351423-B2
    优先权日:2015-05-29
    标题 :Processes for synthesis of reducing gaseous mixtures starting from hydrocarbon streams and carbon dioxide
    发明人:SZEGO EDUARDO LUIGI; DERUDI MARCO
    权利人:SZEGO EDUARDO LUIGI; DERUDI MARCO
    摘要:A process for reducing metal ore may include: carrying out a reaction between a stream of carbon dioxide and a stream of at least one hydrocarbon, at pressure greater than or equal to 0.5 atmospheres (atm) and less than or equal to 100 atm and at temperature greater than or equal to 800° C. and less than or equal to 1,350° C., to produce a reducing gaseous stream comprising at least H2, CO, CO2, and water vapor; and/or reducing at least one metal ore using the reducing gaseous stream so as to obtain at least one reduced metal material and at least one exhausted gaseous stream comprising at least CO2 and water vapor.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献

    [参考文献]: J J Lian, Et Al. Molybdenum(Vi) Removal By Using Constructed Wetlands With Different Filter Media And Plants. Water Sci Technol. 2013;67(8):1859-66.
    [参考文献]: John Parnell, Et Al. Long Term Geological Record Of A Global Deep Subsurface Microbial Habitat In Sand Injection Complexes. Sci Rep. 2013:3:1828.
    [参考文献]: Jose M Nieto, Et Al. Acid Mine Drainage In The Iberian Pyrite Belt: 1. Hydrochemical Characteristics And Pollutant Load Of The Tinto And Odiel Rivers. Environ Sci Pollut Res Int. 2013 Nov;20(11):7509-19.
    [参考文献]: M Oggerin, Et Al. Specific Jarosite Biomineralization By Purpureocillium Lilacinum, An Acidophilic Fungi Isolated From Río Tinto. Environ Microbiol. 2013 Aug;15(8):2228-37.
    [参考文献]: N N Adhapure, Et Al. Metal Solubilization From Powdered Printed Circuit Boards By Microbial Consortium From Bauxite And Pyrite Ores. Prikl Biokhim Mikrobiol. 2013 May-Jun;49(3):279-84.

    合成参考文献


    参考文献:10.1016/j.jbiosc.2009.08.007
    摘要:Kamimura K, Okabayashi A, Kikumoto M, Manchur MA, Wakai S, Kanao T. Analysis of iron- and sulfur-oxidizing bacteria in a treatment plant of acid rock drainage from a Japanese pyrite mine by use of ribulose-1, 5-bisphosphate carboxylase/oxygenase large-subunit gene. Journal of Bioscience and Bioengineering. 2010 Mar;109(3):244–8. doi: 10.1016/j.jbiosc.2009.08.007.
    参考文献:10.1007/s00253-011-3465-2
    摘要:González DM, Lara RH, Alvarado KN, Valdez-Pérez D, Navarro-Contreras HR, Cruz R, García-Meza JV. Evolution of biofilms during the colonization process of pyrite by Acidithiobacillus thiooxidans. Applied Microbiology and Biotechnology. 2011 Jul 20;93(2):763–75. doi: 10.1007/s00253-011-3465-2.
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