CAS: 591-47-9; 4-Methylcyclohexene

该化合物是一种环烷,其特点是六人碳环,双环和四碳的甲基组;其分子式为C7H12,表明它是环己烷的衍生物,并有额外的甲基替代成分;该化合物一般是一种室内温度无色液体,具有一种独特的气味;其反应性为人所知,特别是由于存在双环联而产生的反应,使其在各种有机合成应用中有用. 4-甲基环己烷也是某些聚合物生产的一个成分,并且可以参与较复杂的有机分子的合成.其物理特性包括相对较低的沸点和有机溶剂中的中溶性.应当考虑到安全因素,因为它可能是易燃的,如果吸入或浸入,可能会对健康造成危害.建议在一个通风良好的地区进行适当的处理和储存,以减轻这些风险.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

p-methylcyclohexanol 3-methylcyclohexyl bromide trans-4-methylcyclohexan-1-ol 4-methylcyclohexanone oxime r.4t)(+/-)-1ξ-methyl-cyclohexanediol-(3r.4t) 1-(2,5-dimethyl-phenyl)-1-methyl-cyclohexane 4-ethyl-1-methyl-2-(1-methyl-cyclohexyl)-benzene p-tolyl-ethane1-(5-ethyl-2-methyl-phenyl)-1-p-tolyl-ethane

合成工艺路线路线简述

    📜3-环己烯甲醛置于氢氧化钾,一水合肼体系中,化学反应生成 4-甲基-1-环己烯
    参考文献:Factors Influencing Conformational Preferences In Cyclohexenes
    标题:Factors Influencing Conformational Preferences In Cyclohexenes
    摘要:
    DOI:10.1021/ja00312A030

    海关参考信息

    专利信息


    专利号:US-7034096-B2
    优先权日:2002-02-19
    标题:Ring-expansion of cyclic olefins metathesis reactions with an acyclic diene
    发明人:CHOI TAE-LIM; LEE CHOON WOO; KIM HYUNJIN M; GRUBBS ROBERT H
    权利人:CALIFORNIA INST OF TECHN
    摘要:This invention relates generally to synthetic procedures that include the step of ring-opening metathesis of cyclic olefins and reaction with an acyclic diene co-reactant to produce olefin macrocycles by ring expansion, or alternatively. The ring expansion of the cyclic olefin is provided by three types of sequential olefin metathesis (ring-opening, cross, and ring-closing olefin metathesis). More particularly, the invention pertains to synthesis of olefin macrocycles via olefin metathesis reactions using a Group 8 transition metal complex as the metathesis catalyst. Macrocycles provided herein have a variety of uses in the pharmaceutical, biomedical, organic synthesis and chemical industries, such as the production of crown ethers that are useful as metal complexing species.

    专利号:US-10669160-B2
    优先权日:2018-04-30
    标题:Heterogeneous wet synthesis process for preparation of high purity tungsten pentahalide
    发明人:LIU YUMIN; LI FENG; WAN ZHIWEN; FAFARD CLAUDIA; WIESE STEFAN; HUSSON GUILLAUME; NIKIFOROV GRIGORY; SUI BIN; GIRARD JEAN-MARC
    权利人:AIR LIQUIDE; AIR LIQUIDE AMERICAN
    摘要:Synthesis of tungsten pentahalide compositions having low impurity profiles are disclosed. The specific impurity profile permits deposition of high purity tungsten-containing films using vapor deposition processes or other semiconductor manufacturing processes without introduction of performance-impacting contaminants.

    专利号:US-10975012-B2
    优先权日:2017-09-28
    标 题 :Synthesis of cyclic organic compounds
    发明人:PADILLA-ACEVEDO ANGELA I
    权利人:UNIVATION TECH LLC
    摘要:A method comprising synthesizing a cyclic organic compound (3) via reaction of an substituted alkene (1) with an unsubstituted or substituted acrylic acid (2) in the presence of a sulfonic acid reagent to make the cyclic organic compound (3) R1(H)Câ•?C(H)R2 (1)

    专利号:US-7351781-B2
    优先权日:2001-04-24
    标题 :Synthesis of vinyl polymers by controlled radical polymerization
    发明人:WHITE DANIELA; O'DWYER JAMES B
    权利人:PPG IND OHIO INC
    摘要:A controlled free radical polymerization process, which includes the steps of: adding a monofunctional iniferter compound to an oxygen-free solvent; heating the solution to a temperature sufficient to allow the iniferter compound to form two carbon centered radical residues; adding a first monomer composition comprising one or more monomers to the solution containing the radical containing residues; polymerizing the first monomer composition to form a quasi-living polymer; and optionally polymerizing a second monomer composition comprising one or more monomers, which are different than the first monomer composition. The resulting non-random copolymer having the general formula:n nφ-[-A p -B s -] t -φn nwhere A and B are different compositions of ethylenically unsaturated monomers; p is an integer from 1 to 1,000; s is an integer from 0 to 1,000; t is an integer from 1 to 100; and φ is a residue from the iniferter.

    专利号:US-4847429-A
    优先权日:1987-08-03
    标 题:Synthesis of phenylhydroquinones
    发明人:LENTZ CARL M; GUSTAFSON BRUCE L; VAN SICKLE DALE E; BOWERS JR JOSEPH S
    权利人:EASTMAN KODAK CO
    摘要:Process is disclosed for the preparation of phenylhydroquinones by the alkylation of hydroquinone (or derivatives thereof) with the cyclohexyl moieties, cyclohexanol or cyclohexene (or derivatives thereof), followed by dehydrogenation of the intermediate cyclohexylhydroquinone.

    专利号:US-11059840-B2
    优先权日:2017-09-28
    标题 :Synthesis of cyclic organic compounds and metallocenes
    发明人:PADILLA-ACEVEDO ANGELA I; KUHLMAN ROGER L
    权利人:UNIVATION TECH LLC
    摘要:A method comprising synthesizing a cyclic organic compound via reaction of an unsubstituted or substituted cyclohexene with an unsubstituted or substituted acrylic acid in the presence of phosphoric and/or sulfonic acid reagent to make the cyclic organic compound. Also, a method of synthesizing a ligand for a transition metal, and a related substituted ligand-metal complex and catalyst, from the unsubstituted or substituted cyclohexene and unsubstituted or substituted acrylic acid. Also, the cyclic organic compound, ligand, and substituted ligand-metal complex and catalyst synthesized thereby. Also a method of polymerizing an olefin with the catalyst to give a polyolefin, and the polyolefin made thereby.

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Chessum, N.; Couty, S.; Jones, K., Science of Synthesis, (2009) 48, 281.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 860.
    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1018.
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