CAS: 210230-40-3; Tetrabutylammonium Bis((Trifluoromethyl)Sulfonyl)Amide

相似化合物

405514-94-5 906478-91-9 375395-33-8

上下游产品

N-benzyl-bis(trifluoromethanesulfonimide) tetrabutylammomium bromide calcium(II) bis(trifluoromethanesulfonyl)imide tert-butylammonium hexafluorophosphate(V)

N-Benzyl-Bis(Trifluoromethanesulfonimide),四丁基溴化铵 以 二氯甲烷 用作溶剂,以73%的收率获得n,N,N-三丁基-1-丁铵二[(三氟甲基)磺酰基]亚胺
参考文献:轻松获得双三氟甲烷磺酰亚胺金属盐或鎓盐
标题:轻松获得双三氟甲烷磺酰亚胺金属盐或鎓盐
摘要:的(cf的许多盐3 So 2)2 ñ-阴离子,称为tfsi,是根据一个原始单罐方法制备.首先,将n-苄基三氟甲烷磺酰亚胺(n-苄基三氟酰亚胺)用乙醇处理以形成氧鎓中间体,然后将其用各种碱中和以提供金属或三烷基铵三氟酰亚胺盐.或者,将n-苄基三氟甲酰亚胺直接用三烷基sulf,季铵或phospho的卤化物处理以递送相应的三氟甲酸酯衍生物.ñ-三氟甲酰基苄基也可以与二或三烷基胺和膦反应以得到苄基鎓盐.可以用n-烯丙基三氟甲醚进行类似的反应.因此,Tfsi阴离子可以非常容易且方便地与多种金属或有机阳离子缔合.这些盐可用作电池和燃料电池的电解质,离子液体或路易斯酸.
Doi:10.1016/j.Tet.2009.04.068

专利信息

专利号:US-9267213-B1
优先权日:2005-03-25
标题:Electrochemical deblocking solution for electrochemical oligomer synthesis on an electrode array
发明人：MAURER KARL; COOPER JOHN J
权利人:CUSTOMARRAY INC
摘要:There is disclosed an electrochemical deblocking solution for use on an electrode microarray. There is further disclosed a method for electrochemical synthesis on an electrode array using the electrochemical deblocking solution. The solution and method are for removing acid-labile protecting groups for synthesis of oligonucleotides, peptides, small molecules, or polymers on a microarray of electrodes while substantially improving isolation of deblocking to active electrodes. The method comprises applying a voltage or a current to at least one electrode of an array of electrodes. The array of electrodes is covered by the electrochemical deblocking solution.

专利号:US-10407676-B2
优先权日:2014-12-09
标题 :High efficiency, small volume nucleic acid synthesis
发明人：POEHMERER THOMAS; KUHN PHILLIP; NOTKA FRANK; ZEIDLER ANDREAS; HEIL KORBINIAN; TREFZER AXEL; FONNUM GEIR; KATZEN FEDERICO; ANDERSSON KRISTIAN
权利人:LIFE TECHNOLOGIES CORP; THERMO FISHER SCIENT GENEART GMBH; LIFE TECH AS
摘要:The disclosure generally relates to compositions and methods for the production of nucleic acid molecules. In some aspects, the invention allows for the microscale generation of nucleic acid molecules, optionally followed by assembly of these nucleic acid molecules into larger molecules. In some aspects, the invention allows for efficient production of nucleic acid molecules (e.g., large nucleic acid molecules such as genomes).

专利号:MX-2007011815-A
优先权日:2005-03-25
标题 :ELECTROCHEMICAL UNLOCK SOLUTION FOR ELECTROCHEMICAL SYNTHESIS OF OLIGOMEROS IN AN ARRANGEMENT OF ELECTRODES.

专利号:RU-2007139631-A
优先权日:2005-03-25
标题 :SOLUTION FOR ELECTROCHEMICAL DEPARTMENT IN ELECTROCHEMICAL SYNTHESIS OF OLIGOMERS ON THE ELECTRODE MATRIX

专利号:US-2011217553-A1
优先权日:2007-12-20
标 题 :Frozen Ionic Liquid Microparticles and Nanoparticles, and Methods for their Synthesis and Use
发明人：WARNER ISIAH M; TESFAI AARON; EL-ZAHAB BILAL M; BWAMBOK DAVID; BAKER GARY A; FAKAYODE SAYO O; LOWA MARK; TOLOCKA MICHAEL P; DE ROOY SERGIO
权利人:WARNER ISIAH M; TESFAI AARON; EL-ZAHAB BILAL M; BWAMBOK DAVID; BAKER GARY A; FAKAYODE SAYO O; LOWA MARK; TOLOCKA MICHAEL P; DE ROOY SERGIO
摘要:“Frozen ionic liquid†microparticles and nanoparticles are disclosed, as are alternative methods of making the particles. The particles may be monodisperse or polydisperse, with spherical or other shapes. The particles may be prepared without specialized equipment, and without harsh conditions. The microparticles and nanoparticles have uses in biomedical, materials, analytical, and other fields.