CAS: 1833-51-8; (Chloromethyl)Dimethyl(Phenyl)Silane

上下游产品

Chloro(chloromethyl)dimethylsilane phenylmagnesium bromide allyl(chloromethyl)dimethylsilane bromobenzenemethoxy(dimethylphenylsilyl)methane methacrylic acid-[(dimethyl-phenyl-silanyl)-methyl ester] dimethyl(ethoxy)phenylsilane toluene

在 C6H5Mgbr体系中,用 Not Given 用作溶剂,以75%的收率获得二甲基氯甲基苯基硅烷
参考文献:氨基甲基硅化合物及其衍生物的制备
标题:氨基甲基硅化合物及其衍生物的制备
摘要:肛门.计算.对于 Ghiioip\ts:C,47.15;H,4.84.发现:C,47.36;H,4.97.(B).-至 2.74 G 的溶液.(0.049 摩尔)氢氧化钾在 35 毫升中.无水乙醇,6.21 克.加入(0.050摩尔)对硫甲酚.将混合物冷却至0",并在0"加入4.4毫升(0.050摩尔)1-氯-硝基乙烷在15毫升无水乙醇中的溶液.将混合物在 0" 下放置 15 小时,然后过滤,得到 2.10 克氯化钾.用 200 毫升水稀释滤液,沉淀出 6 克油.在冰河中用过氧化氢将油氧化乙酸,如上,得到 15% 收率的相同砜(通过物理外观,碱溶解度,熔点和混合熔点),由对甲苯磺酰氯和 1-氯-1-硝基乙烷获得的产物氧化得到.砜的低收率与在进行氧化的油状产品中存在大量对甲苯基二硫化物有关.分离二硫化物并通过熔点和与真实对甲苯基二硫化物的混合熔点确认其身份.(C).-α-硝基乙基对甲苯基砜还通过7
Doi:10.1021/ja01152A092

专利信息

专利号:US-7456298-B2
优先权日:2002-06-03
标题:Synthesis of acetonides from aryl silanes
发明人：MCAULIFFE JOSEPH C; WHITED GREGORY M; SMITH WYATT CHARLES
权利人:GENENCOR INT
摘要:The present invention is related to cis-diols and biological methods of producing cis-diols. The present invention further relates to processes for subsequently converting such silane cis-diols to the more stable acetonide derivatives, as well as a process for converting silane cis-diols to the corresponding catechols and the compounds produced thereby. The present invention also provides chemical methods for the conversion of said silane cis-diols and acetonide compounds to epoxy, saturated and otherwise modified derivatives. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims.

专利号:US-2004033574-A1
优先权日:2002-06-03
标题 :Synthesis of cis-diols from aryl silanes

专利号:US-5202444-A
优先权日:1990-11-27
标题:Optically isomeric inositol and process for making optically active compound
发明人：OZAKI SHOICHIRO; AKIYAMA TAKAHIKO; KAGEYAMA KUNIO; MACHIDA MORIHISA
权利人:YOKOHAMA RUBBER CO LTD
摘要:Optically active diols and hydroxycarboxylic acids and their esters are produced by deriving 1L-1,2:5,6-di-O-cyclohexylidene-chiro-inositol from 1L-chiro-inositol as an asymmetric source, followed by introduction of a selected class of sterically hindering and asymmetrically reactive groups into the first-mentioned compound and by subsequent reduction of the resulting compound. Seven specific inositols are also derivable from synthesis of those ultimate compounds.

专利号:US-2007213550-A1
优先权日:2002-06-03
标题 :Synthesis of cis-diols from aryl silanes

专利号:US-2007213541-A1
优先权日:2002-06-03
标 题 :Synthesis of acetonides from aryl silanes

专利号:ES-2397104-T3
优先权日:2002-12-11
标 题 :Procedure and intermediate products for the synthesis of entecavir