专利号:US-7091338-B2 优先权日:2001-11-15 标 题 :Purification of 4,4′(5′)- di-t-butylcyclohexano-18-crown-6 发明人:BOND ANDREW H; BARRANS JR RICHARD E; HORWITZ E PHILIP 权利人:PG RES FOUNDATION 摘要:A purification method is disclosed for a predetermined water-insoluble extractant present in a liquid phase composition that additionally contains one or more additional extractants, synthesis reaction starting materials, and reaction byproducts dissolved as solutes in an organic diluent. An ion-containing compound is admixed with the composition to form an extractant/ion complex in the organic diluent phase that has an affinity for a new phase that is greater than the affinity for the first-named phase. The predetermined extractant/ion complex is separated from the diluent by using the new phase affinity, and the extractant/ion complex is preferably although not necessarily recovered. The extractant/ion complex is separated into extractant and ion. The extractant is recovered. Exemplary extractants include polyethers, crown ethers, crown thioethers, calixarenes, polyamines, cryptands, porphyrins and the like.
参考文献:10.1007/bf00743590 摘要:Trigub LP, Kuz'min VE. Effect of rigid fragments on the conformation of crown-ethers. Journal of Structural Chemistry. 1990 May;31(3):471–4. doi: 10.1007/bf00743590. 参考文献:10.1007/bf00641344 摘要:Ashirmatov MA, Sadybakasov BK, Afanas'ev VA. Mechanism and dissociation paths of the active fragment in N-methyl-N′-(β-D-xylopyranosyl)-N-nitrosourea. Theoretical and Experimental Chemistry. 1990 May;26(3):328–32. doi: 10.1007/bf00641344.