CAS: 17454-53-4; Cyclohexano-18-Crown-6

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CAS号77094-42-9 (1R,2R)-2-(2-(2... | CAS号19249-03-7 三乙二醇二对甲苯磺酸酯 | CAS号286-20-4 环氧环己烷 | CAS号110-83-8 环己烯 | CAS号1460-57-7 反式-1,2-环己二醇 | CAS号112-27-6 三甘醇

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    专利号:US-7091338-B2
    优先权日:2001-11-15
    标 题 :Purification of 4,4′(5′)- di-t-butylcyclohexano-18-crown-6
    发明人:BOND ANDREW H; BARRANS JR RICHARD E; HORWITZ E PHILIP
    权利人:PG RES FOUNDATION
    摘要:A purification method is disclosed for a predetermined water-insoluble extractant present in a liquid phase composition that additionally contains one or more additional extractants, synthesis reaction starting materials, and reaction byproducts dissolved as solutes in an organic diluent. An ion-containing compound is admixed with the composition to form an extractant/ion complex in the organic diluent phase that has an affinity for a new phase that is greater than the affinity for the first-named phase. The predetermined extractant/ion complex is separated from the diluent by using the new phase affinity, and the extractant/ion complex is preferably although not necessarily recovered. The extractant/ion complex is separated into extractant and ion. The extractant is recovered. Exemplary extractants include polyethers, crown ethers, crown thioethers, calixarenes, polyamines, cryptands, porphyrins and the like.

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    合成参考文献


    参考文献:10.1007/bf00743590
    摘要:Trigub LP, Kuz'min VE. Effect of rigid fragments on the conformation of crown-ethers. Journal of Structural Chemistry. 1990 May;31(3):471–4. doi: 10.1007/bf00743590.
    参考文献:10.1007/bf00641344
    摘要:Ashirmatov MA, Sadybakasov BK, Afanas'ev VA. Mechanism and dissociation paths of the active fragment in N-methyl-N′-(β-D-xylopyranosyl)-N-nitrosourea. Theoretical and Experimental Chemistry. 1990 May;26(3):328–32. doi: 10.1007/bf00641344.
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