CAS: 14686-14-7; Trans-3-Heptene

该化合物是一种属于烷族的不饱和碳氢化合物,其特点是其七碳链中第三和第四碳原子之间的双重结合.分子式为C7H14,表明其分子式为C7H14,表明其具有一种双重结合,它有助于其与饱和碳氢化合物相比的再活性." Trans"配置表明,双环联的替代体在对面,它影响着它的物理特性,如沸点和熔点. Trans-3-heptene是室内温度下无色液体,有明显的气味.它比水密度小,在水中不溶,但在有机溶剂中溶解.该化合物用于有机合成,可以作为生产各种化学品的中间体.由于存在双重结合,转三-heptene可以受到典型的对烷的反应,例如氢化,卤化和聚合.在处理这一化合物时,应当采取安全防范措施,因为它可能易燃,如果吸入或吸入,也可能对健康造成危险.

结构式图片

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ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

CAS号31844-98-1 1-溴-1-丁烯成品 | CAS号927-77-5 丙基溴化镁 | CAS号2384-92-1 (3E)-hepta-1,3-diene | CAS号75560-87-1 S-(pyridin-2-yl... | CAS号123-19-3 二丙基甲酮 | CAS号106-35-4 3-庚酮 | CAS号142-82-5 正庚烷 | CAS号589-55-9 4-庚醇 | CAS号592-76-7 1-庚烯 | CAS号592-76-7 1-庚烯 | CAS号592-77-8 2-庚烯 | CAS号108-88-3 甲苯 | CAS号149-57-5 异辛酸 | CAS号99-66-1 丙戊酸

合成工艺路线路线简述

    📜4-庚醇置于硫酸体系中,化学反应生成反-3-庚烯
    参考文献:Plate; Tarasowa,Zhurnal Obshchei Khimii,1950,Vol. 20,P. 1092,1094,1095,1096;Engl.Ausg.S.1133
    标题:Plate; Tarasowa,Zhurnal Obshchei Khimii,1950,Vol. 20,P. 1092,1094,1095,1096;Engl.Ausg.S.1133

    海关参考信息

    专利信息


    专利号:US-7247752-B2
    优先权日:2004-10-01
    标 题 :Methods for the synthesis of astaxanthin
    发明人:LOCKWOOD SAMUEL F; TANG PENG CHO; NADOLSKI GEOFF; JACKSON HENRY L; FANG ZHIQIANG; DU YISHU; YANG MIN; GEISS WILLIAM; WILLIAMS RICHARD; BURDICK DAVID
    权利人:CARDAX PHARMACEUTICALS INC
    摘要:A method used for synthesizing intermediates for use in the synthesis of carotenoids and carotenoid analogs, and/or carotenoid derivatives. In some embodiments, the invention includes methods for synthesizing optically active intermediates useful for the synthesis of optically active carotenoids. Synthesis of optically active carotenoids, in one embodiment, may be accomplished by forming an optically active dihydroxy intermediate from ketoisopherone. The optically active dihydroxy intermediate may be converted into optically active astaxanthin derivatives.

    专利号:US-7973171-B2
    优先权日:2005-06-13
    标题:Process for synthesis of dialkoxyorganoboranes
    发明人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    权利人:BURKHARDT ELIZABETH; ATKINS WILLIAM
    摘要:The invention relates to a process for the synthesis of dialkoxyorganoboranes, in particular to a process for the synthesis of dialkoxyorganoboranes by an ester exchange reaction. Moreover, the invention relates to a process for the synthesis of organo-oxazaborolidine catalysts (organo-CBS) and of trialkylboroxins. Furthermore, the invention relates to methods of using dialkoxyorganoboranes for the preparation of organo-CBS catalysts and in Suzuki-type coupling reactions.

    专利号:US-2024228455-A1
    优先权日:2021-04-27
    标 题 :Synthesis of cbn and cbnv
    发明人:KAVARANA MALCOLM J
    权利人:TEEWINOT LIFE SCIENCES CORP
    摘要:The invention includes chemical synthesis for preparing cannabinol (CBN) and cannabinovarin (CBNV). The process is suitable for inter alia the large-scale synthesis of pharmaceutical grade CBN and CBNV.

    专利号:WO-2023102600-A1
    优先权日:2021-12-06
    标题:Synthesis of amphiphilic block copolymers and polymeric nanofibers produced therefrom
    发明人:ZETTERLUND PER B; ISHIZUKA FUMI; KIM HYUN JIN; CHATANI SHUNSUKE; NIINO HIROSHI
    权利人:NEWSOUTH INNOVATIONS PTY LTD
    摘要:The present disclosure relates to the field of synthesis of block copolymers, and polymeric nanofibers having a core-shell morphology produced therefrom. The present disclosure relates to the field of synthesis of block copolymers where one block is more hydrophobic than the other block and is a different composition. The disclosure also relates to uses of these polymeric nanofibers in various applications, such as reinforcing a polymeric matrix and for coatings applications.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-2008125587-A1
    优先权日:2006-05-25
    标 题 :Synthesis of triazole compounds that modulate HSP90 activity
    发明人:CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
    权利人:CHIMMANAMADA DINESH U; LEE CHI-WAN; JAMES DAVID; ZHANG SHIJIE; YING WEIWEN; CHAE JUNGHYUN; PRZEWLOKA TERESA
    摘要:The present invention provides novel methods of preparing triazole compounds which inhibit the activity of Hsp90. One embodiment of the invention is directed to methods for preparing a triazole compound represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising the steps of: a) reacting an amide represented by the following Structural Formula: n n n n n n n n n n with a thionation reagent to form a thioamide; b) reacting the thioamide of step a) with hydrazine to form a hydrazonamide; c) reacting the hydrazonamide of step b) with a carbonylation or a thiocarbonylation reagent. n In one embodiment, the present invention is a method of synthesis of a compound of formula (IA) n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof, comprising reacting a compound of formula (IIA) n n n n n n n n n n with an oxidizing agent, thereby producing a compound of formula (IA). n The present invention is also directed to a method of preparing a compound or a tautomer thereof represented by the following Structural Formula: n n n n n n n n n n or a tautomer, a pharmaceutically acceptable salt, solvate, or clathrate, or a prodrug thereof. The method comprises the step of reacting a first starting compound represented by the following Structural Formula: n n n n n n n n n n in the presence of a mercuric salt, with a second starting compound represented by the following Structural Formula:

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    主要参考文献

    参考标题:Synthesis Of Olefins By Nickel-Catalyzed Decarbonylation Of S-(2-Pyridyl) Thioates
    作者:Toshio Goto,Makoto Onaka,Teruaki Mukaiyama |发布日期:1980.6.5
    摘要:S-(2-Pyridyl) Thioates, Especially Derived From Secondary And Tertiary Carboxylic Acids, Are Decarbonylated By Use Of A Catalytic Amount Of Nickel Chloride And Zinc Powder To Give Olefins In Good Yields.

    合成参考文献


    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 794.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 816.
    摘要:Aitken, R. A.; Aitken, K. M., Science of Synthesis, (2010) 47, 1051.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 780.
    摘要:Kostikov, R. R.; Khlebnikov, A. F.; Sokolov, V. V., Science of Synthesis, (2010) 47, 813.
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