CAS: 11113-75-0; Nickel Sulfide

该化合物是镍和硫的无机化合物,一般是黑灰或黑灰固体,以水溶性较低而著称,这种化合物以不同形式出现,包括硫化物镍矿物质,硫化物具有半导体特性,在电子应用中引起兴趣,还用于生产镍合金和在某些化学反应中作为催化剂.该化合物如果浸入或吸入,可能是有毒的,在处理时应采取适当安全措施. 镍硫化物可以在某些条件下氧化成氧化氧化氧化物和二氧化硫,其稳定性和再活性可视具体形式和环境条件而变化,例如温度和压力.

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欧盟法规

统一分类与标签ECHA物质食品接触材料-禁用CMR物质工作场所安全标识要求ECHA物质C&L通报REACH预注册废弃物危险特性清单

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    专利信息


    专利号:US-4139569-A
    优先权日:1977-11-14
    标题:Vapor phase cracking of dicyclopentadiene and synthesis of 2,3-dihydroxycyclopentadiene and cyclopentene
    发明人:LANE JR PARLEY C
    权利人:GOODRICH CO B F
    摘要:Improved process for vapor phase cracking of dicyclopentadiene and synthesis of 2,3-dihydrodicyclopentadiene therefrom. Initially, a feedstock consisting essentially of dicyclopentadiene and cyclopentene is subjected to thermocracking in the vapor phase, resulting in the conversion of dicyclopentadiene to monomeric cyclopentadiene. The presence of cyclopentene in the feed stock is believed to minimize coke formation on the interior walls of the cracking chamber. Subsequent selective catalytic hydrogenation of the resulting mixture converts substantially all of the monomeric cyclopentadiene to cyclopentene. The cyclopentene, prepared in the above manner, can be combined with additional quantitie;s of dicyclopentadiene and the resultant mixture subjected to dimerization in the liquid phase at elevated temperatures, thereby forming the monomer, 2,3-dihydrodicyclopentadiene.

    专利号:EP-0035328-A1
    优先权日:1980-02-14
    标题:Method of synthesizing hydrocarbons and alcohols
    发明人:OZYAGCILAR MEHMET N
    权利人:UNIV SOUTH CAROLINA
    摘要:Improved economies are achieved in the synthesis of hydrocarbons and alcohols from hydrogen/carbon monoxide mixtures by adding steam to a hydrogen-lean synthesis gas derived, e.g., from the gasification of a liquid or solid fossil fuel and carrying out the synthesis in the presence of a catalyst comprising hydrided titanium supported on a metal or inter-metallic compound capable of forming an unstable hydride.

    专利号:US-11932966-B2
    优先权日:2020-04-16
    标 题 :Metal sulfide filled carbon nanotubes and synthesis methods thereof
    发明人:LI WENZHI; POUDEL YUBA
    权利人:LI WENZHI; POUDEL YUBA; THE FLORIDA INTERNATIONAL UNIV BOARD OF TRUSTEES
    摘要:Filled carbon nanotubes (CNTs) and methods of synthesizing the same are provided. An in situ chemical vapor deposition technique can be used to synthesize CNTs filled with metal sulfide nanowires. The CNTs can be completely and continuously filled with the metal sulfide fillers up to several micrometers in length. The filled CNTs can be easily collected from the substrates used for synthesis using a simple ultrasonication method.

    专利号:WO-9113132-A1
    优先权日:1990-03-01
    标 题:Synthesis of a crystalline silicoaluminophosphate
    发明人:MILLER STEPHEN J
    权利人:CHEVRON RES
    摘要:A silicoaluminophosphate molecular sieve is disclosed and is characterized in that the P2O5 to alumina mole ratio at the surface is about 0.80 or less, the P2O5 to alumina mole ratio of the bulk is 0.96 or greater and the silicon content at the surface is greater than that of the bulk.

    专利号:US-5158665-A
    优先权日:1988-02-12
    标 题 :Synthesis of a crystalline silicoaluminophosphate
    发明人:MILLER STEPHEN J
    权利人:CHEVRON RES & TECH
    摘要:A method is disclosed for preparing a silicoaluminophosphate molecular sieve, characterized in that the P 2 O 5 to alumina mole ratio at the surface is about 0.85 or less, the P 2 O 5 to aluminia mole ratio of the bulk is 0.94 or greater and the silicon content at the surface is greater than that of the bulk, from a reaction mixture containing particles less than 80 microns in diameter.

    专利号:US-5208005-A
    优先权日:1988-02-12
    标题 :Synthesis of a crystalline silicoaluminophosphate
    发明人:MILLER STEPHEN J
    权利人:CHEVRON RES & TECH
    摘要:A method is disclosed for preparing a silicoaluminophosphate molecular sieve, characterized in that the P2O5 to alumina mole ratio at the surface is about 0.80 or less, the P2O5 to alumina mole ratio of the bulk is 0.96 or greater and the silicon content at the surface is greater than that of the bulk, from a reaction mixture containing particles less than 80 microns in diameter.

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    合成参考文献


    摘要:L41: ATSDR - Agency for Toxic Substances and Disease Registry (2005). Toxicological profile for nickel. U.S. Public Health Service in collaboration with U.S. Environmental Protection Agency (EPA).
    参考文献:10.1002/anie.201508232
    摘要:Hartmann NJ, Wu G, Hayton TW. Synthesis of a "Masked" Terminal Nickel(II) Sulfide by Reductive Deprotection and its Reaction with Nitrous Oxide. Angew Chem Int Ed Engl. 2015 Dec 01;54(49):14956–9.
    摘要:Lü JC, Chen JK, Ji WD, Jiang YG, Shi LY, Wu ZL, He M, Zeng BH. [Study on lung carcinogenesis associated genes in human lung squamous cell carcinoma and malignant transformation of human bronchial epithelial cells induced by carcinogen]. Zhonghua Yi Xue Za Zhi. 2003 Dec 25;83(24):2146–51.
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