CAS: 3878-44-2; Triphenylphosphine Selenide

该化合物是有机合成和协调化学中广泛用作多用途试剂的有机化合物,其主要优点包括稳定性,易处理性以及作为转移剂在制备素,碳氢化合物和金属复合物中的效用.该化合物的强健磷乙烯化物结构确保了核循环和催化应用中的可靠的反应性.它因其在温和条件下将引入有机框架的作用而特别受到重视,从而使其成为药物,材料科学和催化学研究者的首选选择.其晶体形式有利于精确地在反应中使用异质测量法.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

triphenylphosphine (diphenylmethylene)triphenylphosphorane triphenylphosphorane(4-methylphenyl)phenylmethylenetriphenylphosphorane triphenylphosphorane(4-chlorophenyl)phenylmethylenetriphenylphosphorane triphenyl-phosphine oxide ; compound with 3,4,5,6-tetrachloro-pyr°C atechol diphenylmethylphosphine selenide triphenylphosphine sulfide

合成工艺路线路线简述

    📜三苯基瞵硫置于sodium Hydrogen Selenide体系中,用 乙醚,二氯甲烷 作为反应溶剂,化学反应 2.0H,反应生成 硒化三苯膦
    参考文献:基于甲硫基和甲基硒化salts盐化学方法的膦硫基-膦基硒代化合物的新型立体选择性互变,膦基硒代衍生物的还原和pishchimuka的复古重排
    标题:基于甲硫基和甲基硒化salts盐化学方法的膦硫基-膦基硒代化合物的新型立体选择性互变,膦基硒代衍生物的还原和pishchimuka的复古重排
    摘要:已发现硫代诺素向硒代化合物的相互转化可以保持磷的构型,并且已经提出了该过程的机理.已经开发了硫膦酸酯通过the盐的异构化为硫代异构体的反应,并被认为是"复古的pishchimuka"重排.
    DOI:10.1016/s0040-4020(01)81908-6

    海关参考信息

    专利信息


    专利号:WO-2024061900-A1
    优先权日:2022-09-20
    标题 :Quantum dot shell synthesis
    发明人:WALRAVENS WILLEM; NAKONECHNYI IGOR; MACINTYRE BROWN ALASDAIR ANGUS; PRATO MODESTINO RAFAEL ALBERTO; GRIGEL VALERIIA
    权利人:QUSTOMDOT BV
    摘要:The invention relates to the synthesis of core/shell/shell quantum dots, particularly to a novel shell synthesis method.

    专利号:US-12163079-B2
    优先权日:2019-08-12
    标 题 :Synthesis of blue-emitting ZnSe1-xTex alloy nanocrystals with low full width at half-maximum
    发明人:NEWMEYER BENJAMIN; IPPEN CHRISTIAN; MA RUIQING
    权利人:SHOEI CHEMICAL IND CO
    摘要:The invention pertains to the field of nanotechnology. The invention provides highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers display a low full width at half-maximum and a high quantum yield. The invention also provides methods of producing the nanostructures.

    专利号:US-11053439-B2
    优先权日:2019-02-05
    标题:Methods for synthesis of inorganic nanostructures using molten salt chemistry
    发明人:CURLEY JOHN J; TU ALEXANDER; GUO WENZHOU; WANG CHUNMING; IPPEN CHRISTIAN; HOTZ CHARLES
    权利人:NANOSYS INC
    摘要:The invention relates to highly luminescent nanostructures with strong blue light absorbance, particularly core/shell nanostructures comprising an In(1-x)GaxP core and ZnSe and/or ZnS shell layers, wherein 0
    专利号:US-11753587-B2
    优先权日:2018-05-30
    标 题:Method for synthesis of blue-emitting ZnSe1-xTEx alloy nanocrystals
    发明人:IPPEN CHRISTIAN; TRUSKIER JONATHAN; MANDERS JESSE
    权利人:NANOSYS INC
    摘要:The invention relates to highly luminescent nanostructures, particularly highly luminescent nanostructures comprising a ZnSe 1-x Te x core and ZnS and/or ZnSe shell layers. The invention also relates to methods of producing such nanostructures.

    专利号:US-11634629-B2
    优先权日:2019-07-11
    标 题:Method to improve performance of devices comprising nanostructures
    发明人:KIM DAEKYOUNG; GUO WENZHOU; TU ALEXANDER; CHOW Yeewah Annie; BARRERA DIEGO; IPPEN CHRISTIAN; NEWMEYER BENJAMIN; MA RUIQING
    权利人:NANOSYS INC
    摘要:The invention is in the field of nanostructure synthesis. Provided are highly luminescent core/shell nanostructures with zinc fluoride and zinc acetate bound to their surface. Also provided are methods of preparing the nanostructures, films comprising the nanostructures, and devices comprising the nanostructures.

    专利号:US-2023235224-A1
    优先权日:2019-08-12
    标 题 :SYNTHESIS OF BLUE-EMITTING ZnSe1-xTex ALLOY NANOCRYSTALS WITH LOW FULL WIDTH AT HALF-MAXIMUM

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    摘要:Das, A.; Ramkumar, N.; Veliks, J., Science of Synthesis: Modern Strategies in Organofluorine Chemistry, (2025) 2.
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