CAS: 32861-85-1; Chlomethoxynil

该化合物是能够抑制某些大叶杂草的生长,同时对谷物作物危害较小;该化合物具有氯化芳香结构的特点,有助于其除草活动;CLOMETHoxyfen通常用于抗生前和出血后治疗,针对特定杂草种;其行动方式涉及破坏植物的激素平衡,导致异常生长,最终导致目标杂草死亡;该物质一般被认为对哺乳动物毒性较低,但与许多农用化学品一样,需要小心处理和应用,以尽量减少对环境的影响;此外,其在土壤中的持久性和对非目标生物的潜在影响是其使用中的重要考虑因素.总的来说,CLOMTHoxyfen在各种农业系统中的杂草管理中的效力受到重视.

结构式图片

物理性质

欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

1-chloro-3-methoxy-4-nitrobenzene 2,4-dichlorophenol2,4-Dichlor-3'-hydroxy-4'-nitrodiphenylether -propionsaeurechlorid2-5-(2',4'-Dichlorphenoxy)-2-nitrophenoxy-propionsaeurechlorid -propionsaeure2-5-(2',4'-Dichlorphenoxy)-2-nitrophenoxy-propionsaeure -propionsaeureethylester2-5-(2',4'-Dichlorphenoxy)-2-nitrophenoxy-propionsaeureethylester

合成工艺路线路线简述

    📜5-氯-2-硝基苯甲醚,2,4-二氯酚置于potassium Carbonate体系中,用 二甲基亚砜 用作溶剂,化学反应 5.0H,以60%的收率获得甲氧除草醚
    参考文献:Nitrodiphenylether,Ihre Herstellung Und Herbizide Wirkung / Nitrodiphenylethers,Their Preparation And Herbicidal Activity
    标题:Nitrodiphenylether,Ihre Herstellung Und Herbizide Wirkung / Nitrodiphenylethers,Their Preparation And Herbicidal Activity
    摘要:硝基二苯醚是一种具有高活性的新型除草剂.这些化合物的合成方法进行了回顾.
    Doi:10.1515/znb-1980-0721

    海关参考信息

    专利信息


    专利号:WO-2024256370-A1
    优先权日:2023-06-13
    标 题 :Synthesis of glufosinate using an amidase-based process
    发明人:ZIMMERMANN GUNTHER; POTT MORITZ STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of preparing glufosinate, comprising the steps of hydrolysing an N-carbamoyl glufosinate amide with an Amidase enzyme to form an N- carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N- carbamoyl amino acid compound.

    专利号:US-2025120400-A1
    优先权日:2021-12-10
    标题:Synthesis of glufosinate using a hydantoinase-based process
    发明人:DITRICH KLAUS; BREUER MICHAEL; POTT MORITZ STEFAN; ZIMMERMANN GUNTHER; SEEMAYER STEFAN
    权利人:BASF SE
    摘要:The present invention relates to a method of manufacturing glufosinate, comprising the steps of hydrolysing a hydantoin with a Hydantoinase enzyme to form a N-carbamoyl amino acid compound followed by cleaving off the carbamoyl moiety of said N-carbamoyl amino acid compound.

    专利号:US-11919928-B2
    优先权日:2016-03-16
    标题 :Method for producing dihydrotentoxin
    发明人:KUBO TAKASHI; MACHIDA MASAYUKI; FUJIOKA TOMONORI; YAMAGUCHI Shigenari; KAWAI KIYOSHI
    权利人:KUMIAI CHEMICAL INDUSTRY CO
    摘要:An object of the present invention is to identify an enzyme having activity of synthesizing dihydrotentoxin that is a tentoxin precursor and an enzyme having activity of synthesizing tentoxin using dihydrotentoxin as a substrate. The present invention concerns a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 16 and having activity of nonribosomal peptide synthesis of dihydrotentoxin and a tentoxin synthesis-related gene encoding a protein comprising the amino acid sequence of SEQ ID NO: 18 and having activity of converting dihydrotentoxin to tentoxin.

    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:TW-I655905-B
    优先权日:2012-07-24
    标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Keum YS, Lee YJ, Kim JH. Metabolism of nitrodiphenyl ether herbicides by dioxin-degrading bacterium Sphingomonas wittichii RW1. J Agric Food Chem. 2008 Oct 8;56(19):9146-51. doi: 10.1021/jf801362k. Epub 2008 Sep 9.
    3: Chiang HC, Duh JR, Wang YS. Butachlor, thiobencarb, and chlomethoxyfen movement in subtropical soils. Bull Environ Contam Toxicol. 2001 Jan;66(1):1-8. Japanese.

    合成参考文献


    摘要:Pesticide Manual., 9(134), 1991
    摘要:Farm Chemicals Handbook., -(C67), 1991
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