CAS: 495-62-5; 1-Methyl-4-(6-Methylhept-5-En-2-Ylidene)Cyclohex-1-Ene

该化合物是一种自然形成的化学配方C15H24的松树,其特点是双环结构;在室内温度下,黄色液体是无色的,无色的,以其令人愉快的花粉芳香而闻名,使其在香味和口味行业中具有价值. -乙二苯主要来自各种基本油类,特别是甘菊和姜等某些植物的油类.其分子结构具有双重结合和环己烷环的结合,有助于其再活性和有机合成的潜在应用.化合物在水中表现出低溶性,但在有机溶剂中却可溶性,这在很多磷属典型.此外,对乙二苯进行了研究,以了解其潜在的生物活动,包括抗微生物和抗炎炎特性.与许多有机化合物一样,在处理和使用时,应参考安全数据,因为如果大量摄入或吸入,这可能构成风险.

结构式图片

相似化合物

495-61-4 99-85-4 591-49-1

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

4-methyl-1-(1'-propanalethylidene)-3-cyclohexene isopropyltriphenylphosphonium iodide (E)-3,7,11-trimethyl-1,6,10-dodecatrien-3-ol catechol (Z,Z)-monofarnesyl etherterephthalic acid succinic acid levulinic acid acetone

合成工艺路线路线简述

    Squalene 反应生成 4-(1,5-二甲基-4-己烯亚基)-1-甲基环己烯
    参考文献:Heilbron; Kamm; Owens,Journal Of The Chemical Society,1926,P. 1634,1642
    标题:Heilbron; Kamm; Owens,Journal Of The Chemical Society,1926,P. 1634,1642

    海关参考信息

    专利信息


    专利号:US-2018105838-A1
    优先权日:2015-03-11
    标 题:Process for de novo microbial synthesis of terpenes
    发明人:SCHRADER JENS; BUCHHAUPT MARKUS; SONNTAG FRANK; KRONER CORA; BRÜSER HEIKE; Schröder Hartwig; PELZER RALF
    权利人:BASF SE
    摘要:The invention relates to microbial terpene production. Known methods for microbial production of terpenes are mostly based on the direct conversion of sugars. Therefore alternative substrates, in particular alternative carbon sources, for use in microbial terpene production were desirable. The invention relates to a methylotrophic bacterium containing recombinant DNA coding for at least one polypeptide with enzymatic activity for heterologous expression in said bacterium, wherein said at least one polypeptide with enzymatic activity is selected from the group consisting an enzyme of a heterologous mevalonate pathway, a heterologous terpene synthase and optionally a heterologous synthase of a prenyl diphosphate precursor. The invention further relates in particular to a method for de novo microbial synthesis of sesquiterpenes or diterpenes from methanol and/or ethanol.

    专利号:US-11384367-B2
    优先权日:2016-12-22
    标题:Synthesis of bioproducts from lignin-derived aromatics by genetically modified microorganisms
    发明人:GLADDEN JOHN M; SKERKER JEFFREY M; KEASLING JAY D; KIRBY JAMES; YAEGASHI JUNKO
    权利人:UNIV CALIFORNIA; NAT TECH & ENG SOLUTIONS SANDIA LLC; BATTELLE MEMORIAL INSTITUTE FOR MANAGEMENT AND OPERATION OF PACIFIC NORTHWEST NAT LABORATORY; NATIONAL TECH AND ENGINEERING SOLUTIONS OF SANDIA LLC
    摘要:The present invention provides for a method of converting a depolymerized lignin aromatic compound into a bioproduct, comprising: (a) providing a composition comprising a depolymerized lignin aromatic compound, optionally a depolymerized cellulose, and optionally a depolymerized hemicellulose, and (b) introducing a genetically modified microorganism to the composition, wherein the genetically modified microorganism is capable of converting the depolymerized lignin aromatic compound into a bioproduct; such that the depolymerized lignin aromatic compound is converted into a bioproduct.

    专利号:US-11052374-B2
    优先权日:2018-12-20
    标题:Surfactant-templated synthesis of nanostructured xerogel adsorbent platforms
    发明人:DE LEON PATRICIA IGNACIO; LAIBLE PHILIP D; MEYER MACKENZIE ELIZABETH; POVINELLI CHRISTOPHER R; TRACEY KILLIAN L; ARENAS DANIEL YOAV
    权利人:UCHICAGO ARGONNE LLC
    摘要:A process for separations and recovery from mixtures via specific adsorption using high-surface area, flexible silica-based nanostructured gel adsorbents and articles of manufacture relating to same.

    专利号:US-10144840-B2
    优先权日:2013-03-13
    标题 :One-pot, high-performance recycling of polymer waste using renewable polymer synthesis
    发明人:HEARON KEITH
    权利人:POLY6 TECH
    摘要:Curable formulations, cured formulations, and mixtures and composites thereof are described herein, as well as methods of making and using the formulations, mixtures, and composites.

    专利号:DE-102015103608-A1
    优先权日:2015-03-11
    标题 :Process for the microbial de novo synthesis of terpenes

    专利号:CN-107429223-A
    优先权日:2015-03-11
    标 题 :Methods for de novo microbial synthesis of terpenoids
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    主要参考文献


    1: Jou YJ, Chen CJ, Liu YC, Way TD, Lai CH, Hua CH, Wang CY, Huang SH, Kao JY, Lin CW. Quantitative phosphoproteomic analysis reveals γ-bisabolene inducing p53-mediated apoptosis of human oral squamous cell carcinoma via HDAC2 inhibition and ERK1/2 activation. Proteomics. 2015 Oct;15(19):3296-309. doi: 10.1002/pmic.201400568. Epub 2015 Aug 13. pii: E601. doi: 10.3390/molecules21050601. doi: 10.3389/fbioe.2014.00021. eCollection 2014.
    4: Aschenbrenner AK, Kwon M, Conrad J, Ro DK, Spring O. Identification and characterization of two bisabolene synthases from linear glandular trichomes of sunflower (Helianthus annuus L., Asteraceae). Phytochemistry. 2016 Apr;124:29-37. doi: 10.1016/j.phytochem.2016.01.009. Epub 2016 Feb 12. doi: 10.1021/sb5002517. Epub 2014 Jul 9. doi: 10.1007/s11103-015-0381-3. Epub 2015 Oct 6. doi: 10.1002/ptr.5543. Epub 2015 Dec 15. Epub 2014 Jan 17. doi: 10.1021/ja4106489. Epub 2014 Feb 3. doi: 10.1021/acs.orglett.6b01519. Epub 2016 Jun 24. doi: 10.1016/j.bmcl.2015.12.022. Epub 2015 Dec 8. doi: 10.1016/j.yebeh.2012.02.020. Epub 2012 Apr 5. doi: 10.1128/AEM.02155-14. Epub 2014 Aug 22.
    14: Mao SC, Guo YW, van Soest R, Cimino G. Trans-dimer D, a novel dimeric sesquiterpene with a bis-bisabolene skeleton from a Hainan sponge Axinyssa variabilis. J Asian Nat Prod Res. 2011 Aug;13(8):770-5. doi: 10.1080/10286020.2011.588949.

    合成参考文献


    参考文献:10.1080/10286020.2011.588949
    摘要:Mao S, Guo Y, van Soest R, Cimino G. Trans-dimer D, a novel dimeric sesquiterpene with a bis-bisabolene skeleton from a Hainan spongeAxinyssa variabilis. Journal of Asian Natural Products Research. 2011 Aug;13(8):770–5. doi: 10.1080/10286020.2011.588949.
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