CAS: 1775-27-5; 2-Bromo-1-Indanone

上下游产品

2-bromo-1-indanol trans-2-bromo-1-indanol inden-1-one 3-azido-1H-indene H-indeno[1,2-d]thiazole2-phenyl-8H-indeno[1,2-d]thiazole d]thiazol-2-one3,8-dihydro-indeno[1,2-d]thiazol-2-one 2-(phenylthio)-2,3-dihydro-1H-inden-1-one 2-bromo-1-indanol

2,3-二氢-1H-茚-1-醇置于oxone,溴化铵体系中,用 甲醇,水 用作溶剂,化学反应 24.0H,以52%的收率获得2-溴-1-茚满酮
参考文献:一种新的通用一锅策略,可使用溴化铵和过氧化氢从仲醇合成α-溴酮†
标题:一种新的通用一锅策略,可使用溴化铵和过氧化氢从仲醇合成α-溴酮†
摘要:已开发出一种新的,高效的绿色方案,用于使用廉价,空气稳定且无毒的试剂(例如nh 4 Br和oxone)从仲醇一锅合成α-溴代酮.该反应通过两个连续步骤进行,例如仲醇的氧化和原位生成的酮的氧化溴化.
Doi:10.1039/c7Nj00052A

专利信息

专利号:WO-2021038581-A1
优先权日:2019-08-30
标题 :A one step synthesis of 2-substituted benzo[b]thiophenes
发明人：SEKAR GOVINDASAMY; POONGUZHALI ELAMVAZHUTHI
权利人:INDIAN INST TECH MADRAS
摘要:The invention pertains to a one step synthesis of 2-substituted benzo[ b ]thiophene of general formula wherein the synthesis of 2-substituted benzo[ b ]thiophenes is by reacting the starting materials substituted or unsubstituted 2-halogenobenzaldehyde and substituted or unsubstituted acetyl/phenacyl bromide with a catalyst, a sulphur source and phase transfer catalyst in an aqueous medium with atmospheric air and at temperature in the range of 25°C-30°C.

专利号:US-9796653-B2
优先权日:2015-12-21
标题 :Methods of preparing α,β-unsaturated or α-halo ketones and aldehydes
发明人：BAXENDALE IAN R; SHARLEY JAMES S; Miranda Amadeo Fernández; PÉREZ ANA MARIA COLLADO
权利人:INT FLAVORS & FRAGRANCES INC
摘要:Copper(II) bromide mediated oxidation of acylated enol and use of the reaction in the synthesis of α,β-unsaturated or α-bromo ketones or aldehydes are disclosed. The method provides an efficient and practical process for manufacturing dehydrohedione (DHH) and many other versatile α,β-unsaturated or α-bromo ketones or aldehydes in large scales to avoid using precious metal compounds.

专利号:EP-0931786-B1
优先权日:1995-09-01
标 题:Synthesis and use of retinoid compounds having negative hormone and/or antagonist activities

专利号:WO-9709297-A2
优先权日:1995-09-01
标 题:Synthesis and use of retinoid compounds having negative hormone and/or antagonist activities

专利号:EP-0931786-A2
优先权日:1995-09-01
标 题 :Synthesis and use of retinoid compounds having negative hormone and/or antagonist activities