CAS: 884507-39-5; 1-(4-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)Benzyl)Pyrrolidine
该化合物是一种含有丙烯基替代苯基组的碳酸酯衍生物,该化合物主要用作铃木-米亚乌拉交叉反应的中间体,能够合成复杂的双亚菊结构;四甲基二氧基甲醇会增强有机溶剂的稳定性和溶性,便利处理和储存;其苯基苯丙酰胺组在进一步功能化方面提供多种用途,使其在制药和材料科学研究中具有价值;该产品具有高纯度和持续的再活动性,确保催化转化的可靠性能;在惰性条件下使用,它是在合成有机化学中构建碳联结的基本再生剂.
- 英文名称1-(4-(4,4,5,5-Tetramethyl-1,3,2-Dioxaborolan-2-yl)Benzyl)Pyrrolidine
- 中文名称4-(吡咯烷-1基甲基)苯基硼酸频那醇酯
- IUPAC名称1-(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl)pyrrolidine
- 其它别名4-(吡咯烷-1基甲基)苯基硼酸频那醇酯; 4-(1-吡啶基甲基)苯硼酸频呐醇酯; 4-(Pyrrolidin-1-Ylmethyl)Benzeneboronic Acid, Pinacol Ester
- CAS编号884507-39-5
- MFCD编号:MFCD08690299
- 分子式:C17H26BNO2分子量:287.21
- 产品CID: 1895388
- 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物
物理性质
MSDS等安全信息
上下游产品
CAS号123-75-1 四氢吡咯 | CAS号138500-85-3 4-溴甲基苯硼酸频哪酯 | CAS号302348-51-2 4-(羟甲基)苯硼酸频哪醇酯 | CAS号59016-93-2 4-(羟甲基)苯硼酸 | CAS号76-09-5 频哪醇合成工艺路线路线简述
- 128376-64-7 = 884507-39-5
反应条件:1.1 Reagents: Zinc Chloride,Sodium Cyanoborohydride Solvents: Methanol; 4 H,Rt
标题:Modulation Of Proteasome Machinery By Natural And Synthetic Analogues Of The Marine Bioactive Compound Petrosaspongiolide M
作者:Margarucci,Luigi; Et Al
参考文献:Chembiochem 日期:2012 卷标:13(7) 页码:982-986]
302348-51-2 = 884507-39-5
反应条件:1.1 Catalysts: Sodium Carbonate,Bis(Dichloro(η6-P-Cymene)Ruthenium),Bis[2-(Diphenylphosphino)Phenyl] Ether Solvents: Xylene; Rt -> 155 °C; 24 H,155 °C
标题:Synthesis Of Amines With Pendant Boronic Esters By Borrowing Hydrogen Catalysis
作者:Ma,Winson M. J.; Et Al
参考文献:Organic Letters 日期:2013 卷标:15(18) 页码:4850-4853]
76-09-5 + 59016-93-2 = 884507-39-5
反应条件:1.1 Solvents: Toluene; 2 H,Reflux2.1 Catalysts: Sodium Carbonate,Bis(Dichloro(η6-P-Cymene)Ruthenium),Bis[2-(Diphenylphosphino)Phenyl] Ether Solvents: Xylene; Rt -> 155 °C; 24 H,155 °C
标题:Synthesis Of Amines With Pendant Boronic Esters By Borrowing Hydrogen Catalysis
作者:Ma,Winson M. J.; Et Al
参考文献:Organic Letters 日期:2013 卷标:15(18) 页码:4850-4853]
76-09-5 + 87199-17-5 = 884507-39-5
反应条件:1.1 Solvents: Ethyl Acetate; 4 H,Rt1.2 Reagents: Sodium Sulfate,Calcium Chloride; Rt2.1 Reagents: Zinc Chloride,Sodium Cyanoborohydride Solvents: Methanol; 4 H,Rt
标题:Modulation Of Proteasome Machinery By Natural And Synthetic Analogues Of The Marine Bioactive Compound Petrosaspongiolide M
作者:Margarucci,Luigi; Et Al
参考文献:Chembiochem 日期:2012 卷标:13(7) 页码:982-986
📜4-羟甲基苯硼酸置于[ruthenium(II)(η6-1-Methyl-4-Isopropyl-Benzene)(Chloride)(μ-Chloride)]2,Sodium Carbonate,双(2-二苯基磷苯基)醚体系中,用 5,5-Dimethyl-1,3-Cyclohexadiene,甲苯 作为反应溶剂,化学反应 26.0H,反应生成 4-(吡咯烷-1基甲基)苯基硼酸频那醇酯
参考文献:Synthesis Of Amines With Pendant Boronic Esters By Borrowing Hydrogen Catalysis
标题:Synthesis Of Amines With Pendant Boronic Esters By Borrowing Hydrogen Catalysis
摘要:Amine Alkylation Reactions Of Alcohols Have Been Performed In The Presence Of Boronic Ester Groups To Provide Products Which Are Known To Have Use As Molecular Sensors. The Boronic Ester Moiety Could Be Present In Either The Alcohol Or Amine Starting Material And Was Not Compromised In The Presence Of A Ruthenium Catalyst.
DOI:10.1021/ol402271A
海关参考信息
- 2902300000-甲苯
2905122000-异丙醇
2905143000-叔丁醇
2905310000-1,2-乙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
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合成参考文献
参考DOI号:10.1021/ol402271a
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