CAS: 676525-77-2; [ir(Dtbbpy)(Ppy)2]Pf6

📜Ammonium Hexafluorophosphate,[iridium(Iii)(μ-Chloro)(2-Phenylpyridine)2]2,4,4'-二叔丁基-2,2'-二吡啶 以 Not Given 作为反应溶剂,化学反应生成 (4,4'-二叔丁基-2,2'-联吡啶)双[(2-吡啶基)苯基]铱(Iii)六氟磷酸盐
参考文献:带有芳基三唑环金属化配体的增强型发光铱(iii)配合物
标题:带有芳基三唑环金属化配体的增强型发光铱(iii)配合物
摘要:在这里,我们报道了通过"点击化学"制备的4-芳基-1-苄基-1 H-1,2,3-三唑(atl)的合成及其作为环金属化配体并入新的含二亚胺的杂铱(iii)络合物中的过程(n ∧ N)的辅助配体2,2'-联吡啶(bpy)和4,4'-二-叔丁基-2,2'-联吡啶(dtbubpy).根据装饰的不同,这些络合物在室温(rt)的乙腈(acn)溶液中会从黄色发射到天蓝色.其发射能量稍微蓝移和它们的光致发光量子效率是显着高于类似的高级(25和80%之间)(c ∧ N)2的ir(n ∧ N)+型配合物,其中c ∧n是装饰的2-苯基吡啶并配体.这种增加的亮度部分是由于存在苄基,其在空间上屏蔽了铱金属中心.两个atl配合物的x射线晶体学分析证实了这一观点.它们的电化学是可逆的,因此使这些配合物适合包含在发光电化学电池(leec)中.并行的计算机研究支持了实验结果,并表明,对于本研究包括的所有复合物,最大的占据
DOI:10.1021/ic2014013

专利信息

专利号:US-12291596-B2
优先权日:2018-11-30
标 题 :Radical cascade-enabled synthesis of precision polymers with complex main-chain structures
发明人：NIU JIA; HUANG HANCHU; WANG WENQI
权利人:THE TRUSTEES OF BOSTON COLLEGE
摘要:Radical cascade reactions enabling sequence-controlled ring-closing polymerization and ring-opening polymerization for the controlled synthesis of polymers with complex main-chain structures are provided. Facile syntheses leading to low-strain macrocyclic monomers consisting of the ring-opening triggers and extended main-chain structures are also provided. The present disclosure further provides methods for excellent control over polymer molecular weights and molecular weight distributions and high chain-end fidelity allows for the preparation of polymeric systems with well-defined architectures. Further provided are the general nature of the radical cascade-triggered transformations in polymer chemistry, and its application to the synthesis of polymers with diverse main-chain structural motifs with tailored functions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

专利号:CN-114874119-A
优先权日:2022-03-06
标题 :Method for Photocatalytic Synthesis of 3,4-Dialkylated-4-pyrrolin-2-one Derivatives

专利号:CN-114560801-A
优先权日:2022-02-20
标题 :Method for photocatalytic synthesis of 3-cyanoalkyl-4-pyrroline-2-one and derivatives thereof

专利号:CN-114773284-A
优先权日:2022-05-21
标 题 :Synthesis of Visible Light Mediated Dihydroisoxazoles

专利号:CN-115010635-A
优先权日:2022-05-18
标题 :Synthesis method of (E) -beta-selenoethylsulfone compound

专利号:CN-114773284-B
优先权日:2022-05-21
标题:Synthesis method of visible light mediated dihydroisoxazole