📜癸酸乙酯置于potassium Fluoride,Lithium Diisopropyl Amide体系中,化学反应 70.5H,反应生成 四硝基苯氯甲酸酯 参考文献:The Chemistry Of .Alpha.-Silyl Carbonyl Compounds. 11. Reaction Of .Alpha.-Silyl Esters With Grignard Reagents: A Synthesis Of .Beta.-Keto Silanes And Ketones. Preparation Of The Douglas Fir Tussock Moth Pheromone 标题:The Chemistry Of .Alpha.-Silyl Carbonyl Compounds. 11. Reaction Of .Alpha.-Silyl Esters With Grignard Reagents: A Synthesis Of .Beta.-Keto Silanes And Ketones. Preparation Of The Douglas Fir Tussock Moth Pheromone 摘要: DOI:10.1021/jo00225A053
专利号:US-7517828-B2 优先权日:2003-04-25 标 题 :Chiral broensted acid catalyst for asymmetric synthesis and method of asymmetric synthesis with the catalyst 发明人:AKIYAMA TAKAHIKO 权利人:TOAGOSEI CO LTD 摘要:A compound usable as an asymmetric synthesis catalyst which can be easily synthesized without using any metal such as a lanthanoid group element; a method of asymmetric synthesis with the compound; and a chiral compound obtained by the asymmetric synthesis method. A Broensted acid is used as a catalyst in asymmetric synthesis, the chiral Broensted acid being represented by formula (1) below or formula (3) below. The asymmetric synthesis method employs the catalyst. Asymmetric synthesis with the catalyst gives a chiral compound.
专利号:US-4525255-A 优先权日:1982-11-16 标 题:Photochemical reactions for commercial synthesis 发明人:GUILLET JAMES E 权利人:GUILLET JAMES E 摘要:Photochemical reactions are conducted using floating polymer beads on the surface of a moving body of water. The polymer bead is impregnated with a reactant, floated on the water in direct sunlight so as to expose the reactant to solar radiation, collected at a downstream location, treated to remove product from the polymer, and then the bead can be recycled. The process can be used to collect and store solar energy in chemical form, or for conducting photochemical synthesis to produce useful chemical products.
专利号:US-4609444-A 优先权日:1982-11-16 标题 :Photochemical reactions for commercial synthesis 发明人:GUILLET JAMES E 权利人:SOLARCHEM CORP 摘要:Photochemical reactions are conducted using polymer beads arranged as a monolayer, e.g. floating on the surface of a moving body of water. The polymer bead is impregnated with a reactant, floated on the water or otherwise exposed as a monolayer in direct sunlight so as to expose the reactant to solar radiation, collected at a downstream location, treated to remove product from the polymer, and then the bead can be recycled. The process can be used to collect and store solar energy in chemical form, or for conducting photochemical synthesis to produce useful chemical products.
专利号:JP-H0628724-B2 优先权日:1982-11-16 标 题:Photochemical reactions for the synthesis of commercial bases.
专利号:US-2006276329-A1 优先权日:2003-04-25 标题:Asymmetric synthesis catalyst based on chiral brsnsted acid and method of asymmetric synthesis with the catalyst
专利号:EP-1623971-A1 优先权日:2003-04-25 标 题:Asymmetric-synthesis catalyst based on chiral broensted acid and method of asymmetric synthesis with the catalyst
[参考文献]: Azza H Rageh, Et Al. Boronate Affinity-Assisted Mekc Separation Of Highly Hydrophilic Urinary Nucleosides Using Imidazolium-Based Ionic Liquid Type Surfactant As Pseudostationary Phase. Electrophoresis. 2015 Mar;36(5):784-95.
合成参考文献
摘要:Zaidlewicz, M.; Pakulski, M. M., Science of Synthesis: Stereoselective Synthesis, (2011) 2, 114. 摘要:S109 | PARCEDC | List of 7074 potential endocrine disrupting compounds (EDCs) by PARC T4.2 | DOI:10.5281/zenodo.10944198