CAS: 50890-67-0; 5H-Cyclopenta[1,2-B:5,4-B']Dipyridin-5-One

该化合物是一种环环状系统,其独特结构包括一个含氮原子的引信系统,其特点是一个环状系统;该化合物的特点是一个二氮芳基脊柱,其中两个氮原子取代芳香系统中的碳原子,从而促成其独特的化学特性;该化合物通常表现出黄色至橙色,并因其在有机电子中的潜在应用而闻名,特别是在开发有机发光二极管和荧光探测器方面,由于其光物理特性,其稳定性和再活性受到周围功能组和溶剂环境的影响,而这正是其实际应用中的重要考虑因素.

结构式图片

相似化合物

77213-41-3 27318-90-7 1182844-62-7

欧盟法规

ECHA物质C&L通报

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CAS号66-71-7 1,10-菲罗啉 | CAS号4199-88-6 5-硝基-1,10-菲咯啉 | CAS号27318-90-7 1,10-菲啰啉-5,6-二酮 | CAS号75899-33-1 6-keto-5-oxim-1... | CAS号7664-93-9 硫酸 | CAS号7446-11-9 三氧化硫 | CAS号7697-37-2 硝酸

合成工艺路线路线简述

    1,10-邻二氮杂菲-5,6-二酮置于sodium Hydroxide体系中,化学反应 0.5H,反应生成 4,5-二氮芴-9-酮
    参考文献:4,5-二氮杂芴n-Glycopyranosyl Azo用作潜在的生物活性金属有机化合物的支架:合成,结构研究和细胞毒活性
    标题:4,5-二氮杂芴n-Glycopyranosyl Azo用作潜在的生物活性金属有机化合物的支架:合成,结构研究和细胞毒活性
    摘要:通过用不同的未保护的单糖处理9 H-4,5-二氮杂芴基-9-In,以合成有用的产率制备了一系列新颖的n 1-(4,5-二氮杂芴-9-Li基)-N 2-甘氨酰呋喃糖基肼.与测试的单糖的反应可立体选择性地提供环状衍生物,其结构对应于n-β-甘露糖基,除了d-与α-端基异构体一致的阿拉伯糖衍生物.还制备了几种配体与金属的摩尔比为2:1的铜(II)配合物.金属配合物可以结合dna序列,并且比dsdna优先稳定g-四链体dna结构.岩藻糖,鼠李糖和脱氧葡萄糖铜(II)配合物对培养的hela和pc3肿瘤细胞显示出与通常用于化学治疗目的的其他金属配合物(如顺铂)相当的细胞毒活性.
    DOI:10.1016/j.Bioorg.2018.08.019

    海关参考信息

    专利信息


    专利号:US-2021107859-A1
    优先权日:2018-04-06
    标题 :A process for the synthesis of carbon labeled organic compounds
    发明人:AUDISIO DAVIDE; CANTAT THIBAULT; DESTRO GIANLUCA
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A process for the synthesis of a carbon labeled organic compound containing a carbon labeled carboxyl group is described. A method of using carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; a process for manufacturing labeled pharmaceuticals and agrochemicals comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure; and a process for producing tracers comprising synthesis of carbon labeled organic compounds containing a carbon labeled carboxyl group according to the present disclosure are also described.

    专利号:US-10633315-B2
    优先权日:2016-10-19
    标 题:Synthesis of bicyclo[2.2.2]octanes
    发明人:HU YUE RACHEL; HEMBRE ROBERT THOMAS; TUSTIN GERALD CHARLES; BURK CHRISTOPHER HARLAN
    权利人:EASTMAN CHEM CO
    摘要:Provided is a process for the preparation of certain 1,4-bicyclo[2.2.2]octane derivatives. The new synthetic procedure involves treating 1,4-dimethylene cyclohexane with an oxidizing agent in the presence of a transition metal catalyst comprising a palladium compound to afford certain oxo-substituted bicyclo[2.2.2]octane species. The process of the invention thus affords a novel and simplified means for the commercial production of a wide variety of bicyclo[2.2.2]octane derivatives.

    专利号:WO-2024040556-A1
    优先权日:2022-08-26
    标题 :Organic hole injection material and use thereof
    发明人:MENG HONG; LU KE; YAN ZHAOYI; HU ZHAO; HE YAOWU; MENG ZHIMIN; LI TINGTING; CAI YU
    权利人:UNIV PEKING SHENZHEN GRADUATE SCHOOL
    摘要:The present invention relates to an organic hole injection material with a general chemical formula as represented by (I). The hole injection material of the present invention structurally contains two units, i.e., an azafluorene alkene derivative and an electron-deficient group, as well as other aromatic groups, etc., and mainly has the following advantages: the synthesis of the material is relatively simple, which is beneficial for large-scale production and synthesis; the melting point and boiling point of the material are moderate or the material is well dissolved in solvents commonly used in the preparation of devices, such that the preparation of devices by using the material is relatively easy and a high-performance device can be obtained; and since the material contains a plurality of electron-deficient groups, the HOMO-LUMO energy level structure of the material is appropriate, which is more conducive to the injection of holes from an anode into an adjacent organic layer, i.e., a hole transport layer, such that the performance of a device is improved.

    专利号:EP-3529230-B1
    优先权日:2016-10-19
    标 题 :Synthesis of bicyclo(2.2.2)octanes

    专利号:US-8912342-B2
    优先权日:2012-02-06
    标题:Pyrazole synthesis by coupling of carboxylic acid derivatives and enamines
    发明人:GLORIUS FRANK; SURI MAMTA
    权利人:UNIV MUENSTER WILHELMS; Westfälische Wilhelms Universität Münster
    摘要:A method of synthesizing Pyrazoles by means of the oxidative conversion of Enamines with suitable N-containing carboxylic acid derivatives in the presence of copper ions and 2-picolinic acid derivatives is provided.

    专利号:WO-2024044937-A1
    优先权日:2022-08-30
    标题:Organic hole injection material and use thereof
    发明人:MENG HONG; LU KE; CAI YU; YAN ZHAOYI; HU ZHAO; HE YAOWU; MENG ZHIMIN; LI TINGTING
    权利人:UNIV PEKING SHENZHEN GRADUATE SCHOOL
    摘要:The present invention relates to an organic hole injection material, which has a general chemical formula as below: The structure of the hole injection material of the present invention comprises two units of an azafluorene alkene derivative and a cyclic electron-deficient group, etc. Compared with a previous hole injection material, the material has the following advantages: the synthesis of the material is relatively simple, which is beneficial for large-scale production; the HOMO-LUMO energy level structure of the material is appropriate, which is conducive to the injection of carriers; an azafluorene alkene derivative and an electron-deficient group are used as a core of the material, which facilitates the transport of the carriers in an organic layer; and the material has a high LUMO/HOMO energy level, thereby facilitating the transport of holes from anode ITO to a hole transport layer.
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    主要参考文献

    [参考文献]: Youxiang Wang, Et Al. Preparation, Purification, And Characterization Of Binuclear Ruthenium(Ii) Complexes: Bridging Ligands Based On Diazafluorenes. Inorg Chem. 1998 May 4;37(9):2227-2234.

    合成参考文献


    摘要:Jie, X.; Su, W., Science of Synthesis, (2022) , 6.
    摘要:Kayaki, Y.; Ikariya, T., Science of Synthesis: Catalytic Oxidation in Organic Synthesis, (2017) 1, 106.
    摘要:Wang, P.-S.; Sayed, M.; Gong, L.-Z., Science of Synthesis: Knowledge Updates, (2023) 1, 211.
    摘要:Patil, N. T.; Bera, P.; Paroi, B., Science of Synthesis: Hypervalent Halogens in Organic Synthesis, (2025) .
    参考文献:10.1107/s1600536810035178
    摘要:Wang ZJ, Zhang F, Wan CQ. Bis[5-(2-pyrid-yl)pyrazine-2-carbonitrile]-silver(I) tetra-fluorido-borate. Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 08;66(Pt 10):m1232–3.
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