CAS: 13536-73-7; Erbium(Iii) Bromide

上下游产品

hydrogen bromide bromine aluminium bromide N,N-dimethyl acetamide

📜[er(Water)8](Br)3 以 Neat (No Solvent,Solid Phase) 用作溶剂,以99%的收率获得溴化铒
参考文献:甲醇取代的卤化镧的结构表征
标题:甲醇取代的卤化镧的结构表征
摘要:使用甲醇(meoh)进行了卤化镧[lax(3)]衍生物的醇溶化作为降低labr(3)闪烁体生产温度的一种手段的首次研究.最初,通过在室温下简单地将1溶解在meoh中,研究了{[la(micro-Br)(h(2)o)(7)](br)(2)}(2)(1)的脱水.分离出混合的溶剂化物单体[la(h(2)o)(7)(meoh)(2)](br)(3)(2)化合物,其中la金属中心通过与两种其他的meoh溶剂,但必须将内球br转移到外球.为了尝试将1的甲醇中的反应混合物在cah(2)上干燥,分离了[ca(meoh)(6)](br)(2)(3)的晶体.在回流温度下将化合物1溶解在meoh中,导致分离出异常结构,该结构被确定为盐衍生物{[labr(2.75)* 5.25(meoh)](+ 0.25)[labr(3.25)* 4.75(meoh)](-0.25)}(4).最终,通过将干燥的labr(3)溶
Doi:10.1016/j.Poly.2010.02.027

专利信息

专利号:US-7485741-B2
优先权日:2002-12-02
标 题:Method of producing nitrile compounds from ethylenically-unsaturated compounds
发明人：BOURGEOIS DAMIEN; GALLAND JEAN-CHRISTOPHE; DIDILLON BLAISE; MARION PHILIPPE
权利人:RHODIA POLYAMIDE INTERMEDIATES
摘要:The present invention relates to a process for hydrocyanating a hydrocarbon-based compound containing at least one ethylenic unsaturation by reaction in liquid medium with hydrogen cyanide in the presence of a catalyst comprising a metal element chosen from transition metals and an organophosphorus ligand, characterized in that the organophosphorus ligand is a monodentate organophosphorus compound. The present invention is in particular useful for the synthesis of adiponitrile from butadiene.

专利号:US-12209104-B1
优先权日:2018-07-11
标 题:Metal complexes and methods of making the same
发明人：KIPLINGER JAQUELINE; BEATTIE ROSS; PAGANO JUSTIN; ERICKSON KARLA
权利人:TRIAD NAT SECURITY LLC
摘要:Disclosed herein are embodiments of metal complexes and methods of making the same. The disclosed method embodiments provide a one-step approach to making metal complexes, such as complexes comprising lanthanide metals, rare earth metals, transition metals, main group metals, and/or actinide metals that can be used various applications, such as in separations technology, catalysis (e.g., catalysts for pharmaceutical synthesis and/or catalysts for biomass conversion), nuclear chemistry, LED phosphors, scintillator materials, magnetic materials, and nuclear fuels.

专利号:US-2023212024-A1
优先权日:2020-04-14
标 题:New lithium rare-earth halides
发明人：BRAIDA MARC-DAVID
权利人:SOLVAY
摘要:The present invention concerns new lithium rare earth halides that may be used as solid electrolytes or in electrochemical devices. The invention also refers to wet and dry processes for the synthesis of such lithium rare earth halides and lithium rare earth halides susceptible to be obtained by these processes.