合成目标产物 Ethyl 3-Ethoxypropionate 主要起始原料 Ethanol And Ethyl Acrylate
(文献来源)合成步骤主要原料 Ethanol 和 Ethyl Acrylate
二乙氧基甲烷置于硫酸,乙酸酐体系中,用92%的收率获得产物3-乙氧基丙酸乙酯 参考文献:Process For The Preparation Of Alkyl 3-Alkoxypropionates 标题:Process For The Preparation Of Alkyl 3-Alkoxypropionates 摘要:本发明公开了一种改进的方法,通过在酰亚胺酸酐和浓缩或浓硫酸存在的催化剂作用下,将含有至少七个碳原子的烷基3-烷氧基丙酸酯与含有五个或更多碳原子的二烷氧基甲烷反应,制备烷基3-烷氧基丙酸酯.
专利号:US-2018171086-A1 优先权日:2016-12-16 标题 :Large area monolayer of perfluoro polymers 发明人:SUN HAORAN 权利人:SOUTH DAKOTA BOARD OF REGENTS 摘要:Synthesis and growth of large area free-standing ultra-thin two-dimensional (2D) polymeric films including 2D covalent organic frameworks (COF) are achieved by utilizing fluorocarbon-soluble fluorinated aldehyde derivatives and hydrocarbon-soluble amine derivatives at a liquid-liquid interface of respective fluorocarbon and hydrocarbon solvents.
专利号:US-8940925-B2 优先权日:2009-01-27 标题:Method for purifying the azeotropic fraction generated during the synthesis of N,N-dimethyl aminoethyl acrylate 发明人:PAUL JEAN-MICHEL; GRAIRE CORALIE; RIEHL AUDREY 权利人:PAUL JEAN-MICHEL; GRAIRE CORALIE; RIEHL AUDREY; ARKEMA FRANCE 摘要:The invention relates to a method for producing N,N-dimethylaminoethyl acrylate by the transesterification reaction of an alykl acrylate by N1N-dimethylaminoethanol, and more particularly relates to a method for purifying the azeotropic fraction generated during said reaction, thereby enabling the recycling thereof on the alkyl acrylate production unit. The aim of the method of the invention is in particular to remove the acetaldehyde and the dialkoxyethane contained in the azeotropic fraction, either by the direct distillation of the azeotropic fraction or by the distillation of the aqueous phase resulting from the water scrubbing of the azeotropic fraction.
专利号:US-8053161-B2 优先权日:2006-09-25 标 题 :Resist composition, resin for use in the resist composition, compound for use in the synthesis of the resin, and pattern-forming method using the resist composition 发明人:WADA KENJI; SAEGUSA HIROSHI 权利人:FUJIFILM CORP 摘要:A resist composition comprises: (A) a resin capable of increasing its solubility in an alkali developer by action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic ray or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent, wherein the resin (C) has a degree of molecular weight dispersion of 1.3 or less and a weight average molecular weight of 1.0×10 4 or less.
专利号:US-3579568-A 优先权日:1965-08-18 标题 :Synthesis of carboxylic acids from ethylene and carbon monoxide and noble metal compounds 发明人:HECK RICHARD F; HENRY PATRICK M 权利人:HERCULES POWDER CO 摘要:THE DISCLOSED PROCESS IS A METHOD FOR PRODUCING CARBOXYLIC ACIDS BY CARBNYLATION OF OLEFINIC HYDROCARBONS. AN OLEFIN SUCH AS ETHYLENE, AND WATER OR AN ACID SUCH AS ACETIC ACID, ARE BROUGHT INTO CONTACT WITH CARBON MONOXIDE IN THE PRESENCE OF A COMPOUND OF A GROUP VIII NOBLE METAL SUCH AS PALLADIUM AT A TEMPERATURE IN THE RANGE OF 25* TO 250*C. USING ETHYLENE AND ACETIC ACID AS REACTANTS, THE PRODUCT CONTAINS B-ACETOXYPROPIONIC ACID. A REDOX AGENT SUCH AS CUPRIC CHLORIDE MAY BE USED TO EFFECT REGENERATION OF THE NOBEL METAL COMPOUND.
专利号:US-10947189-B2 优先权日:2017-08-12 标 题:Online continuous flow process for the synthesis of organic peroxides using hydrogen peroxide as raw material 发明人:MA BING; PAN SHUAI; SHU XINLIN 权利人:SHANGHAI HYBRID CHEM TECH 摘要:An online continuous flow production process for directly preparing organic peroxides by using hydrogen peroxide as a raw material. This production process uses hydrogen peroxide, catalyst, and an oxidation substrate as a raw material. Substrate will be turned to designated peroxides sequentially through oxidation and workup. This process is performed in a plug-and-produce integrated continuous flow reactor, and the raw materials are continuously fed to the reactor. So, specified peroxide can be continuously obtained at the outlet of the plug-and-produce integrated continuous flow reactor.
专利号:US-9709891-B2 优先权日:2005-12-09 标 题:Positive resist composition, resin used for the positive resist composition, compound used for synthesis of the resin and pattern forming method using the positive resist composition 发明人:KANDA HIROMI; KANNA SHINICHI 权利人:FUJIFILM CORP 摘要:A positive resist composition comprises: (A) a resin of which solubility in an alkali developer increases under an action of an acid; (B) a compound capable of generating an acid upon irradiation with actinic rays or radiation; (C) a resin having at least one of a fluorine atom and a silicon atom; and (D) a solvent; and a pattern forming method using the positive resist composition.
[参考文献]: B Qi, Et Al. Biodegradation Of Volatile Organic Compounds By Five Fungal Species. Appl Microbiol Biotechnol. 2002 Apr;58(5):684-9.
合成参考文献
参考文献:10.1007/s00253-002-0938-3 摘要:Qi, W. Moe, K. Kinney B. Biodegradation of volatile organic compounds by five fungal species. Applied Microbiology and Biotechnology. 2002 Apr 01;58(5):684–9. doi: 10.1007/s00253-002-0938-3.