CAS: 42278-67-1; Potassium Triisopropoxyhydroborate
该化合物是一种有机合成中常用的选择性减少剂,与传统氢化物试剂(如锂铝氢化物(LiAlH4)或氢酸钠(NaBH4))相比,具有较轻的再活性,使其适合减少敏感基质,如氯酮,甲酰胺和高化学选择性的离子体.其受窒息的异丙氧基组加强对反应结果的控制,减少过度减少或粘合等侧面反应.在非对称合成和药物应用中,该试剂特别有用,因为精确的选择性至关重要.由于对水的敏感度,它通常在惰性条件下处理,但与更具侵略性的氢化物捐献者相比,它的安全性和处理得到改善.
- 英文名称Potassium Triisopropoxyhydroborate
- 中文名称三异丙氧基硼氢化钾
- IUPAC名称potassium triisopropoxyhydroborate
- 其它别名Potassium Triisopropoxyborohydride; Potassium Hydro(Triisopropoxy)Borate; Potassium Triisopropoxyborohydride, In Tetrahydrofuran, 1M Solution; Potassium Triisopropoxyborohydride, 1M Solution In Thf; Potassium Triisopropoxyborohydride, 1M Solution In Thf, Acroseal§3; Potassium Triisopropoxyborohydride, 1M Solution In Thf, Acroseal; Potassium Hydrotriisopropoxyborate(1-)
- CAS编号42278-67-1
- MFCD编号:MFCD00044439
- EINECS号:255-747-7
- 分子式:C9H22BKO3分子量:228.18
- 产品CID: 1436010
- 产品分类有机原料→分子砌块→芳杂环类化合物→其它芳杂环类化合物
MSDS等安全信息
欧盟法规
ECHA物质C&L通报REACH预注册合成工艺路线路线简述
📜硼酸三异丙酯,氢化钾 反应生成 三异丙氧基硼氢化钾
参考文献:Brown,H. C.;Cha,J. Soon;Nazer,Behrooz;Kim,Suk-Choong;Krishnamurthy,S+,J. Org. Chem.,1984,49,N 5,885-892
标题:Brown,H. C.;Cha,J. Soon;Nazer,Behrooz;Kim,Suk-Choong;Krishnamurthy,S+,J. Org. Chem.,1984,49,N 5,885-892
海关参考信息
- 2905122000-异丙醇
2931900090-硼酸酯类 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-5886229-A
优先权日:1998-05-29
标 题:Method of synthesis of alkali metal trisubstituted borohydride reagents
发明人：CORELLA II JOSEPH A; ELLENBERGER DAVID H; BRUENING JOERG
权利人:MINE SAFETY APPLIANCES CO
摘要:Synthetic routes for forming alkali metal substituted borohydride compounds include the step of reacting an alkali metal reagent, a hydrogen donor, and a substituted borane. The reactions proceed without the requirement of specialized handling of alkali metal hydrides associated with prior synthetic processes for the production of alkali metal trisubstituted borohydride compounds. A chemical composition comprises solid potassium tri-sec-butyl borohydride.
专利号:WO-0043400-A1
优先权日:1999-01-19
标 题:Synthesis of alkali metal substituted borohydride reagents
专利号:CN-117756720-B
优先权日:2023-12-18
标 题:Polymerizable quaternary ammonium salt antibacterial agent and its preparation and application in the synthesis of antibacterial polyester
专利号:EP-1144419-A1
优先权日:1999-01-19
标 题:Synthesis of alkali metal substitiuted borohydride reagents
专利号:CN-1303386-A
优先权日:1999-01-19
标 题:Synthesis method of alkali metal substituted borohydride reagent
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Ramón, D. J.; Yus, M., Science of Synthesis, (2009) 46, 544.
📝 需求与反馈
尽可能描述清楚需求与问题信息
