CAS: 38465-86-0; (1,5-Cyclooctadiene)Bis(Methyldiphenylphosphine)Iridium(I) Hexafluorophosphate

该化合物是协调的组合体,由环二烯离心和两甲基二苯基离心和两只甲基二苯基离心加以协调,由环二烯离心和两只甲基二苯基离心和两只亚苯基离心组成,其独特的结构包括环二烯环,为中心提供一个稳定的环境,增强它的再活性和催化特性;六氟磷对冲器的存在有助于化合物在极溶剂中的溶性及其在各种条件下的稳定性.一般情况下,由于金属-离心和相互作用,这些复合体在催化过程中具有有趣的电子特性,特别是在有机转化和聚合过程中,因此在催化过程中很有价值.磷离心可以影响中心的电子特性,影响其在催化应用中的再活性和选择性.

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    专利号:US-10336678-B2
    优先权日:2017-05-12
    标题:Compositions and methods for preparing β,γ-unsaturated acids
    发明人：SHOCKLEY SAMANTHA E; HETHCOX JOHN C; STOLTZ BRIAN M
    权利人:CALIFORNIA INST OF TECHN
    摘要:The present disclosure provides methods for enantioselective synthesis of acyclic α-quaternary carboxylic acid derivatives via iridium-catalyzed allylic alkylation.

    专利号:US-2014170151-A1
    优先权日:2010-04-23
    标 题:Synthetic Oligosaccharides for Staphylococcus Vaccine
    发明人：CAMPBELL A STEWART; PLANTE OBADIAH J
    权利人:CAMPBELL A STEWART; PLANTE OBADIAH J
    摘要:The present invention synthetic oligo-β-(1→6)-glucosamine structures and a methodology which essentially allows for the synthesis of any oligo-β-(1→6)-glucosamine species having a definite number of monosaccharide units, including a set pattern of acetylated and non-acetylated residues. The invention further provides antibodies to these synthetic oligo-β-(1→6)-glucosamines as well as compositions thereof and methods for treating and preventing infections caused by bacteria expressing poly-β-(1→6)-glucosamines, such as Staphylococcus aureus.

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    合成参考文献


    摘要:Demchenko, A. V.; De Meo, C., Science of Synthesis Knowledge Updates, (2010) 3, 253.
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