CAS: 126-68-1; O,O,O-Triethyl Phosphorothioate

该化合物是一种有机磷化合物,主要用作杀虫剂和杀螨剂,其特征是磷酸盐结构,包括磷原子结为三乙基组和硫原子,取代磷酸盐中常见的氧原子之一,该化合物因其能够抑制乙酰胆碱酯酶,一种对昆虫...

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298-03-3 152-18-1

物理性质

MSDS等安全信息

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ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

1,2-epithio-3-methoxypropane triethyl phosphite cyclohexene sulfide diethyl etherO,O,S-triethyl phosphorothioate Diethyl phosphoramidate triethyl phosphate sulfotep

合成工艺路线路线简述

    📜Sodium Ethanolate置于三氯氧磷体系中,化学反应生成O,O,O-三乙基硫代磷酸酯
    参考文献:Mastin; Norman; Weilmuenster,Journal Of The American Chemical Society,1945,Vol. 67,P. 1663
    标题:Mastin; Norman; Weilmuenster,Journal Of The American Chemical Society,1945,Vol. 67,P. 1663

    海关参考信息

    专利信息


    专利号:US-6809195-B1
    优先权日:2000-08-16
    标 题:Process for the preparation of oligonucleotides
    发明人：SANGHVI YOGESH S; SONG QUANLAI
    权利人:ISIS PHARMACEUTICALS INC
    摘要:The present invention discloses methods for synthesizing oligomeric compounds. The methods include a modified phosphoramidite protocol wherein the oxidation and capping steps are combined into a single step. The methods result in increased efficiency and are especially amenable to the large scale synthesis of oligomeric compounds.

    专利号:CN-110016050-A
    优先权日:2019-04-08
    标 题:A kind of stable isotope labeling chlopyrifos and its derivative and synthesis preparation method

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    主要参考文献

    参考标题:Preparation And Toxicity Of Some Alkyl Thiopyrophosphates
    作者:R. A. Mcivor,G. D. Mccarthy,G. A. Grant |发布日期:1956.12.1
    摘要:Several Methods Have Been Investigated For The Synthesis Of Tetraalkyl Thiopyrophosphates, Including One That Can Be Carried Out Very Rapidly With High Yield. Purification Of These Compounds Proved Exceedingly Difficult, Because They Were Sensitive To Traces Of Acids Or Bases, And Probably To Inorganic Salts At Temperatures Above 70 °C. All Methods Investigated Yield Only The Thiono Isomer, There Being

    合成参考文献


    参考文献:10.1007/bf02072039
    摘要:Hamade N, Jin Y, Tsukada M, Wada Y, Koizumi A. O,O,S-Trimethyl phosphorothioate induces hypothermia in Fischer 344 rats in a manner dependent on both doses and housing temperatures. Arch Toxicol. 1993;67(1):72–5. doi: 10.1007/bf02072039.
    摘要:Journal of Agricultural and Food Chemistry., 6(900), 1958
    摘要:Prehled Prumyslove Toxikologie; Organicke Latky, Marhold, J., Prague, Czechoslovakia, Avicenum, 1986, -(1149), 1986
    摘要:Nature., 179(154), 1957
    摘要:McKenna, C. E.; Kashemirov, B. A.; Błażewska, K. M., Science of Synthesis, (2009) 42, 899.
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