CAS: 12138-09-9; Tungsten (Iv) Sulfide

该化合物是具有六边形晶体结构的多层过渡性金属三卤化物, 由于其在范德华的相互作用力较弱, 呈现出特殊的润滑特性. 它具有化学惰性, 热稳定(高达~ 500°C 的空气中) , 在干载和高载条件下都具有低摩擦系数(微克~ 0.03-0. 07). WS2 显示在包括真空和高辐射在内的极端环境中的固态润滑性能, 使其适合航空航天, 汽车和工业应用. 其滑动结构也具有耐穿性, 并减少表面疲劳. 此外, WS2 具有半导力, 可用于电子和光电子学. 这些材料以粉状或薄膜形式提供多种功能涂料和合成材料.

结构式图片

相似化合物

12138-09-9

欧盟法规

REACH注册ECHA物质C&L通报REACH预注册

合成工艺路线路线简述

    专利信息


    专利号:US-8007756-B2
    优先权日:2007-03-30
    标题:Process for the synthesis of nanotubes and fullerene-like nanostructures of transition metal dichalcogenides, quasi one-dimensional structures of transition metals and oxides of transition metals
    发明人:MRZEL ALES; REMSKAR MAJA; JESIH ADOLF; VIRSEK MARKO
    权利人:INST & LDQUO JO HACEK OVER Z EF STEFAN & RDQUO
    摘要:The object of the invention is a process for the synthesis of nanotubes of transition metal dichalcogenides, of fullerene-like nanostructures of transition metal dichalcogenides, of nanotubes of transition metal dichalcogenides, filled with fullerene-like nanostructures of transition metal dichalcogenides, of quasi one-dimensional structures (nanowires, microwires and ribbons) of transition metal oxides and of quasi one-dimensional structures of transition metal dichalcogenides, consisting of fine crystallites of transition metal dichalcogenides. The process is characterized in that the synthesis occurs by the chemical transformation of quasi one-dimensional compounds with a sub-micron diameter, described by the formula M 6 C y H z , 8.2
    专利号:US-2024263349-A1
    优先权日:2023-02-02
    标 题 :Phase-controllable synthesis of transition metal dichalcogenide monolayer crystals
    发明人:ZHANG HUA; ZHAI WEI; WANG YONGJI
    权利人:UNIV CITY HONG KONG
    摘要:The present invention provides a general salt-assisted chemical vapour deposition method for phase-controllable synthesis of 1T′ and 2H-phase transition metal dichalcogenide (TMD) monolayer crystals. The method comprises: mixing a transition metal compound powder and a salt powder to form a precursor; placing a substrate on top of the precursor; placing the precursor and the substrate at a center position in a chemical vapour deposition (CVD) furnace; placing a chalcogen powder at an upstream position relative to the precursor along a gas-flow direction in the CVD furnace; heating up the CVD furnace to a growth temperature within the heat-up time; keeping the CVD furnace at the growth temperature for a growth time under a mixed gas flow of H2 and Ar. The optical and electrical characterizations reveal the phase-dependent in-plane isotropy and anisotropy of the as-synthesized 2H and 1T′-phase crystals. The 1T′-TMD monolayer crystals demonstrate much-improved phase transition temperatures.

    专利号:US-11548838-B2
    优先权日:2021-02-02
    标 题:Process for synthesis of polyhydrocarbons as heat transfer agents
    发明人:MANDAL TANMAY; VANKUDOTH KRISHNA; SARASWAT MANISHA; ARORA AJAY KUMAR; KAGDIYAL VIVEKANAND; SAXENA DEEPAK; RAMAKUMAR Sankara Sri Venkata
    权利人:INDIAN OIL CORP LTD
    摘要:The present invention provides a one-pot process of synthesis of phenyl naphthalene compounds that are employed as heat transfer agents. More particularly, the present invention provides a process of preparation of 1-phenylnaphthalene and 2-methyl-1-phenylnaphthalene using refinery spent catalyst. These molecules are known for application as synthetic heat transfer fluids that deliver outstanding performance and thermal stability at continuously high operating temperatures. The reaction is carried out in aqueous medium using a spent catalyst which is a palladium based charcoal catalyst as obtained from various refinery processes. Further, the present invention provides a heat resistant formulation using the synthesized polyhydrocarbons, wherein the formulation is optimized with a free radical scavenger.

    专利号:US-2023279562-A1
    优先权日:2021-12-30
    标题 :Process for the Electrochemical Synthesis of Ammonia (NH3) and the Ammonia Produced Thereby
    发明人:GHORAI UTTAM KUMAR; PAUL SOURAV; ADALDER ASHADUL; SARKAR SOUGATA
    权利人:GHORAI UTTAM KUMAR; RAMAKRISHNA MISSION VIDYAMANDIRA
    摘要:This invention relates to a process for the electrochemical synthesis of ammonia (NH3) and the ammonia produced thereby. Ammonia is synthesized by the electrochemical reduction of nitrogenous materials such as nitrogen or nitrates (NO3-) using metal phthalocyanine such as iron phthalocyanine (FePc) or β-cobalt phthalocyanine (CoPc) or iron phthalocyanine-molybdenum disulfide (FePc-MoS2) or cobalt phthalocyanine- carbon nitride (CoPc-C3N4) catalyst at very low pressure and room temperature by applying low potential.

    专利号:US-11548793-B2
    优先权日:2016-10-19
    标题:Synthesis of aerosol gels comprising macro-aggregates in a buoyancy-opposed flame reactor by a diffusion-limiting cluster aggregating process
    发明人:CHAKRABARTY RAJAN K; LIU PAI
    权利人:WASHINGTON UNIVERSITY ST LOUIS
    摘要:A process for gas-phase synthesis of titanium dioxide aerosol gels with controlled monomer size and crystalline phase using a diffusion flame aerosol reactor operated in a buoyancy-opposed configuration is disclosed. The process includes introducing a precursor stream into a diffusion flame aerosol reactor, introducing a fuel stream into the reactor, combusting the precursor stream and the fuel stream in a flame to form at least one nanoparticle, and operating the reactor in a down-fired buoyancy-opposed configuration to produce the aerosol gel.

    专利号:US-10593928-B2
    优先权日:2014-08-20
    标 题 :Single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition process
    发明人:CHADHA TANDEEP SINGH; BISWAS PRATIM; AN WOO-JIN
    权利人:UNIV WASHINGTON
    摘要:The present disclosure is generally directed to a single-step synthesis of nanostructured thin films by a chemical vapor and aerosol deposition (CVAD) process. The present disclosure is also directed to methods for controlling the morphology of the nanostructured thin films. The films can be used, for example, in lithium ion and/or sodium ion battery electrodes, solar cells and gas sensors.
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    主要参考文献

    [参考文献]: Elizabeth Gibney, Et Al. The Super Materials That Could Trump Graphene. Nature. 2015 Jun 18;522(7556):274-6.
    [参考文献]: Jingjin Zhao, Et Al. Tungsten Disulfide Nanosheet And Exonuclease Iii Co-Assisted Amplification Strategy For Highly Sensitive Fluorescence Polarization Detection Of Dna Glycosylase Activity. Anal Chim Acta. 2015 Aug 5:887:216-223.
    [参考文献]: Xinyi Chia, Et Al. Catalytic And Charge Transfer Properties Of Transition Metal Dichalcogenides Arising From Electrochemical Pretreatment. Acs Nano. 2015 May 26;9(5):5164-79.
    [参考文献]: Yingfeng Qin, Et Al. A Sensitive Fluorescence Turn-On Assay Of Bleomycin And Nuclease Using Ws2 Nanosheet As An Effective Sensing Platform. Anal Chim Acta. 2015 Mar 25:866:84-89.

    合成参考文献


    参考文献:10.1186/s11671-019-3062-3
    摘要:Zhukova MO, Hogan BT, Oparin EN, Shaban PS, Grachev YV, Kovalska E, Walsh KK, Craciun MF, Baldycheva A, Tcypkin AN. Transmission Properties of FeCl3-Intercalated Graphene and WS2 Thin Films for Terahertz Time-Domain Spectroscopy Applications. Nanoscale Research Letters. 2019 Jul 09;14(1):225. doi: 10.1186/s11671-019-3062-3.
    摘要:Hawley - Lewis RJ. _Hawley's Condensed Chemical Dictionary, _15th Ed. New York: John Wiley & Sons, 2007.
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