CAS: 1116-54-7; N,N-Bis(2-Hydroxyethyl)Nitrous Amide

该化合物是一种化学化合物,主要用作有机合成和工业应用的中间体,其结构结构包括两个氢氧乙基组,它们与氮原子中枢相连,该原子也是硝化的,在专门化学工艺中具有反作用,该化合物因其能够参与硝化和电温反应,使其与表面活性剂,腐蚀抑制剂和其他功能材料的生产相关,因此受到重视.由于它具有潜在的回活动性和稳定性考虑,需要谨慎处理.其双重功能组(氢氧乙基和硝基)在受控制的条件下在变化分子框架中提供了多功能性.

结构式图片

欧盟法规

统一分类与标签ECHA物质工作场所安全标识要求ECHA物质食品接触材料-禁用CMR物质C&L通报化妆品禁用物质清单REACH预注册废弃物危险特性清单

上下游产品

2,2'-iminobis[ethanol] bis(2-hydroxyethyl)(3',7'-dimethyl°Ctyl)amine bis(2-hydroxyethyl)geranylamine bromonitromethaneN-nitrosomorpholine N-Nitrosodimethylamine N-(2-hydroxyethyl)-N-methyl-N-nitrosamine methylvinylnitrosamine

合成工艺路线路线简述

  • 合成目标产物 N-Nitrosodiethanolamine 主要起始原料 Diethanolamine
  • (文献来源)合成步骤主要原料 Diethanolamine
📜二乙醇胺置于cross-Linked Polyvinylpyrrolidone*n2O4,Dinitrogen Tetraoxide体系中,用 二氯甲烷 用作溶剂,化学反应 0.13H,以90%的收率获得二乙醇亚硝胺
参考文献:Selective N-Nitrosation Of Amines,N-Alkylamides Andn-Alkylureasby N2O4Supported On Cross-Linked Polyvinylpyrrolidone(Pvp-N2O4)
标题:Selective N-Nitrosation Of Amines,N-Alkylamides Andn-Alkylureasby N2O4Supported On Cross-Linked Polyvinylpyrrolidone(Pvp-N2O4)
摘要:N2O4被负载在交联聚乙烯吡咯烷酮(pvp)上,形成一种固体,稳定且可回收的亚硝化剂.该试剂在温和的非均相条件下,室温下二氯甲烷中,对二烷基胺的n-亚硝化表现出优异的选择性,相比二芳基胺,芳基烷基胺及三烷基胺更具选择性.同时,在相似的反应条件下,该试剂也能在primary Amides和n-苯甲酰胺存在下,选择性制备n-亚硝基-N-烷基酰胺.此外,该试剂还能实现对三胺的选择性n-亚硝化和脱烷基化再n-亚硝化.
Doi:10.1055/s-2003-40518

海关参考信息

专利信息


专利号:EP-0572776-B1
优先权日:1992-05-29
标 题:Electrolyte thickenable detergent composition
发明人:BALZER DIETER DR
权利人:HUELS CHEMISCHE WERKE AG
摘要:The invention relates to surfactant combinations which can be thickened by means of electrolyte and are well tolerated by skin and mucous membranes as basis for shampoos, bath gels and shower gels as well as other cosmetic aqueous cleaning fluids for which an increased viscosity is necessary or desirable for application reasons. The individual components of the mixture are easily obtainable at low cost by synthesis. The surfactant combination contains alkyl polyglycoside and carboxymethylated alkanol ethoxylate alone or carboxymethylated alkanol ethoxylate and monoalkyl sulphosuccinate where appropriate with the addition of a small amount of other surfactant additives, the individual components in the mixture being in a narrow ratio of relative amounts and a highly synergistic increase in viscosity being achieved.

供应商参考报价(招募中)

品牌试剂参考报价(招募中)

📌 第三方产品分析报告

✅ COA系统入驻 | 共享模式

合成参考文献


摘要:40 CFR 721.3350 (USEPA); U.S. National Archives and Records Administration's Electronic Code of Federal Regulations. Available from, as of June 22, 2012:
摘要:Ong J TH et al; J Soc Cosmet Chem 32 (2): 75-86 (1981)
摘要:National Research Council. Prudent Practices for Handling Hazardous Chemicals in Laboratories. Washington, DC: National Academy Press, 1981., p. 55
摘要:Franz TJ et al; Toxicol Sci 21 (2): 213-221 (1993)
摘要:Bingham, E.; Cohrssen, B.; Powell, C.H.; Patty's Toxicology Volumes 1-9 5th ed. John Wiley & Sons. New York, N.Y. (2001)., p. V4: 656
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