CAS: 97148-39-5; Ammonium (Z)-2-(Furan-2-yl)-2-(Methoxyimino)Acetate

• 英文名称Ammonium (Z)-2-(Furan-2-yl)-2-(Methoxyimino)Acetate
• 中文名称甲氧亚胺基呋喃乙酸铵盐
• IUPAC名称ammonium (Z)-2-(furan-2-yl)-2-(methoxyimino)acetate
• 其它别名Methoxyiminofuranammoniumacetate; Syn-2-Methoxyimino-2-(2-Furyl)-Aceticacid-Ammoniasalt; Amf; Ammonium-2-Methoxyimino Furylacetate; Sym-2-Methoxyimino-2-(2-Furyl)-Acetic Acid Ammonium Salt; Syn-2-Methoxy-Imino-2-(2-Furyl)-Acetic Acid Ammonium Salt; Syn-2-Methoxyiminofuranglycolic Acid, Ammonium Salt; Syn-Methoxyimino-Alpha-Furanyl-Acetic Acid Ammonium Salt
• CAS编号97148-39-5
• MFCD编号:MFCD03791040
• EINECS号:619-259-1
• 分子式:C7H10N2O4
• 分子量:186.17
• 产品CID: 2020156
• 产品分类医药中间体

• 相似结构搜索
• InChIKey: ZWNSXPIVYODLLM-PHZXCRFESA-N
• InChI=1S/C7H7NO4.H3N/c1-11-8-6(7(9)10)5-3-2-4-12-5;/h2-4H,1H3,(H,9,10);1H3/b8-6-;…
• 计算化学: 氢键受体数5.0氢键供体数1.0可旋转键数2.0

物理性质

• 熔点182 °C
• 沸点284.7 °C at 760 mmHg
• 闪点126 °C
• 密度1.417g/ml
• PSA:74.86
• LogP:2
• 折射率1.5010 (估算)
• 溶解性Soluble In DMSO, Methanol
• 敏感性遵照规定使用和储存则不会分解。
• 外观形态棕色固体
• 储存条件惰性气氛,室温

MSDS等安全信息

• GHS象形图
• GHS符号GHS02;
  注释: Flame
• 危险类别易燃固体 类别2
  特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H228 |易燃固体.
  H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
• 防范说明P210-P240-P241-P280-P370+P378
• UN编号1325
• 危险品标志Xi,F
• 安全声明24/25-43-22-2-43A
• 危险类别码36/37/38-11

欧盟法规

合成工艺路线路线简述

• 合成目标产物 (Z)-2-Methoxyimino-2-(Furyl-2-yl) Acetic Acid Ammonium Salt 主要起始原料 L-Xylo-Hex-2-Ulosonic Acid
• 67-62-9 + 1467-70-5 = 97148-39-5
  反应条件:1.1 Catalysts: Copper Sulfate Solvents: Water; 0 °C1.2 Reagents: Sulfuric Acid Solvents: Water; Ph 3.5; 4.5 H,8 °C1.3 Reagents: Sulfuric Acid Solvents: Water; < Ph 1,20 °C1.4 Reagents: Ammonia; Ph 7.0,5 °C; 1 H,5 °C
  标题:Method For Synthesizing Ammonium (Z)-2-(Furan-2-Yl)-2-(Methoxyimino)Acetate As Drug Intermediate Of Cefuroxime Axetil
  参考文献:China]
  
  39684-61-2 = 97148-39-5
  反应条件:1.1 Reagents: Ammonia Solvents: Ethanol; Ph 8,-5 °C; 30 Min,0 °C
  标题:Method For Preparing Ammonium (Z)-2-Methoxylimino-2-Furanacetate With High Selectivity
  参考文献:China]
  
  67-62-9 + 1467-70-5 = 97148-39-5
  反应条件:1.1 Reagents: Sodium Hydroxide,Hydrochloric Acid Solvents: Water; Ph 3.5 - 4,15 - 20 °C; 4 H,Ph 3.5 - 4,20 - 25 °C; Ph 0.5,15 - 20 °C1.2 Reagents: Ammonia; 4 H,Ph 7,5 - 10 °C; 1 H,5 - 10 °C
  标题:Process For Preparation Of (Z)-2-(2-Furyl)-2-(Methoxyimino)Acetic Acid Ammonium Salt
  参考文献:China]
  
  593-56-6 + 5781-53-3 = 97148-39-5
  反应条件:1.1 Reagents: Aluminum Chloride Solvents: 1,2-Dichloroethane; 10 °C; 6 H,10 °C1.2 Reagents: Water1.3 Reagents: Sodium Acetate; 1 H,0 °C; 8 H,0 °C1.4 Reagents: Hydrochloric Acid Solvents: Water; 6 H,Ph 10,Rt1.5 Reagents: Ammonia; Rt
  标题:Method For Preparing Ammonium 2-Methoxyimino-2-Furyl Acetate
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Cost-Effective And Environmentally-Friendly Method For Recycling (Z)-2-Methoxyimino-2-Furanacetic Acid
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Method For Catalyzing Conversion Of (E)-2-Methoxyimino-2-(Furyl-2-Yl)Acetic Acid Ammonium Salt Into (Z)-2-Methoxyimino-2-(Furyl-2-Yl) Acetic Acid Ammonium Salt With Graphene/cobalt Composite Catalyst
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Process For The Preparation Of (Z)-α-(Methoxyimino)-2-Furanacetic Acid Ammonium Salt With Capability Of Recycling 2-Furanyloxoacetic Acid
  参考文献:China]
  
  593-56-6 + 1467-70-5 = 97148-39-5 + 97148-40-8
  反应条件:1.1 Reagents: Triethylamine Solvents: Water; Ph 2.0,10 °C1.2 Reagents: Triethylamine Solvents: Water; 2 H,Ph 4.5,10 °C1.3 Reagents: Hydrochloric Acid Solvents: Water; Ph 2.01.4 Reagents: Ammonia Solvents: Methanol; 15 Min,Ph 8,Rt
  标题:Preparation Method Of Cis-(Z)-2-Methoxyimino-2-(Furyl-2-Yl)Acetic Acid Ammonium Salt
  参考文献:China]
  
  67-62-9 + 1467-70-5 = 97148-39-5
  反应条件:1.1 Reagents: Sodium,Hydrochloric Acid Solvents: Water; < Ph 1,Rt; 30 Min,Rt -> 11 °C1.2 Solvents: Water; Rt -> 20 °C; 4.5 H,Ph 4.0,20 °C1.3 Reagents: Ammonia Solvents: Methanol,Dichloromethane; Ph 8.0,10 °C
  标题:Preparation Of Furan Ammonium Salt
  参考文献:China]
  
  67-62-9 + 1467-70-5 = 97148-39-5
  反应条件:1.1 Solvents: Water; 4 H,Rt1.2 < Ph 11.3 Reagents: Ammonia Solvents: Methanol; Ph 7.0,Rt
  标题:Process For Preparation Of 2-Furanglyoxylic Acid
  参考文献:China]
  
  593-56-6 + 1192-62-7 = 97148-39-5
  反应条件:1.1 Reagents: Sodium Nitrite Solvents: Water; 70 °C; 12 H,70 °C1.2 Reagents: Butyric Acid; 1 H,70 °C1.3 Solvents: Water; Neutralized,Rt; Rt -> 10 °C1.4 Reagents: Butyl Acetate,Sodium Chloride; Acidified1.5 Reagents: Ammonia; 10 °C
  标题:Preparation Of Furan Intermediate For Antibiotic Synthesis
  参考文献:India]
  
  65866-86-6 = 97148-39-5
  反应条件:1.1 Reagents: Ammonia Solvents: Methanol; 4 °C; 3.5 H,Heated
  标题:Preparation Method Of Ammonium Furan Salt With High Selectivity
  参考文献:China]
  
  97148-40-8 = 97148-39-5
  反应条件:1.1 Reagents: Formaldehyde,Hydrochloric Acid,Phosphonic Acid Solvents: Water; Ph 3 - 3.5; 60 °C; 4 H
  标题:Inverting Method Of α-(Methoxyimino)-(2-Furyl)Acetic Acid Ammonium Salt From E-Type To Z-Type
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Production Process Of O-Methylhydroxylamine For Furan Ammonium Salt
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Process For Synthesizing (Z)-2-Methoxyimino-2-(Furyl-2-Yl)Acetic Acid Ammonium Salt
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Method For Recovering Furan Keto Acid From Furan Ammonium Salt Waste Residue
  参考文献:China]
  
  = 97148-39-5 [标题:Reaction Conditions
  标题:Stereoselective Precipitation Process For The Recovery Of The Syn Isomer Of 2-(Methoxyimino)-2-(2-Furyl)Acetic Acid As The Ammonium Salt
  参考文献:Italy

海关参考信息

• 2912110000-甲醛
  2912120000-乙醛
  2915110000-甲酸
  2915211900-乙酸
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