CAS: 56-55-3; Tetraphene

该化合物是一个多环芳烃(PAH),由四个有引信的苯环组成,形成一个复杂的结构,有助于化学特性,在室内温度下是一种固体,通常呈现出无色的黄色晶体物质,在水中具有高稳定性和低溶解性,但在苯,甲苯和氯仿等有机溶剂中可溶性.该化合物主要因其致癌作用而得到承认,在环境化学和毒理学中具有重大影响,因为它可以在有机材料不完全燃烧期间形成.Benzanthracene展示荧光并能够吸收紫外光,因此对各种科学研究,包括与摄影化学和环境监测有关的科学研究感兴趣.它在煤油和某些化石燃料中的存在引起了有关人类接触和环境影响的关切,因此需要在工业应用中谨慎处理和监管.

结构式图片

欧盟法规

[统一分类与标签ECHA物质工作场所安全标识要求ECHA物质化妆品禁用物质清单C&L通报食品接触材料-禁用CMR物质REACH预注册欧盟候选物质清单废弃物危险特性清单

上下游产品

CAS号68723-25-1 (2-methylphenyl... | CAS号67064-62-4 8,9,10,11-tetra... | CAS号4483-98-1 1,2,3,4-tetrahy... | CAS号1218996-93-0 2-((naphthalen-... | CAS号2498-66-0 1,2-苯并奎宁酮 | CAS号5018-87-1 2-(萘甲酰基)苯甲酸 | CAS号36914-99-5 5,6-Dihydrobenz... | CAS号32795-84-9 7-溴苯并[a]蒽 | CAS号20316-12-5 苯并[a]蒽-7-乙酸 | CAS号20268-52-4 7-chlorobenz(a)... | CAS号63021-10-3 7,12-dichlorobe... | CAS号23683-26-3 7-fluorobenzant... | CAS号2498-66-0 1,2-苯并奎宁酮 | CAS号77450-63-6 12-fluoro-Benz(... | CAS号77450-64-7 7,12-difluorobe... | CAS号2498-75-1 3-甲基苯并[a]蒽 | CAS号643-79-8 邻苯二甲醛

合成工艺路线路线简述

    📜2-甲基萘置于二硫化碳,三氯化铝,锌体系中,化学反应生成 苯并[a]蒽
    参考文献:Dziewonski; Ritt,Bulletin De L'Academie Polonaise Des Sciences,Serie Des Sciences Chimiques,1927,Vol.,P. 191
    标题:Dziewonski; Ritt,Bulletin De L'Academie Polonaise Des Sciences,Serie Des Sciences Chimiques,1927,Vol.,P. 191

    海关参考信息

    专利信息


    专利号:US-10711138-B2
    优先权日:2016-04-08
    标题:Intermediates and procedures for the synthesis of functional materials
    发明人:KIRSCH PEER; GUNST SUSANN
    权利人:MERCK PATENT GMBH
    摘要:The present invention relates to heteroaromatic compounds which have two different reactive groups, their use in the synthesis of asymmetrically substituted compounds, and synthesis processes in which the compounds according to the invention are reacted sequentially with two different compounds, whereby an asymmetrically substituted compound is formed.

    专利号:US-6512081-B1
    优先权日:1997-07-21
    标题:Synthesis of dithioester chain transfer agents and use of bis(thioacyl) disulfides or dithioesters as chain transfer agents
    发明人:RIZZARDO ENZIO; THANG SAN HOA; MOAD GRAEME
    权利人:E I DUPONT NEMOURS AND COMPANY; COMMW SCIENT IND RES ORG
    摘要:This invention relates to the synthesis of dithiocarboxylic acid esters by reaction of bis(thioacyl) disulphides, thioacetals or vinylidane bis(thioether) with free-radicals (optionally in the presence of monomers). The invention also relates to processes for the synthesis of polymers utilising these dithioesters as polymerisation regulators (chain transfer agents) or to the use of bis(thioacyl) disulphides to generate dithioester chain transfer agents in situ.

    专利号:US-2003162992-A1
    优先权日:2001-12-14
    标 题 :Preparation of intermediates useful in the synthesis of antiviral nucleosides
    发明人:WATANABE KYOICHI A; DU JINFA
    摘要:The present invention is an efficient process for the manufacture of α-acyloxyacetaldehyde, a key intermediate in the synthesis of 1,3-oxathiolane and 1,3-dioxolane nucleosides.

    专利号:US-6022963-A
    优先权日:1995-12-15
    标 题:Synthesis of oligonucleotide arrays using photocleavable protecting groups
    发明人:MCGALL GLENN H; NAM NGO QUOC
    权利人:AFFYMETRIX INC
    摘要:Novel compounds are provided which are useful as linking groups in chemical synthesis, preferably in the solid phase synthesis of oligonucleotides and polypeptides. These compounds are generally photolabile and comprise protecting groups which can be removed by photolysis to unmask a reactive group. The protecting group has the general formula Ar-C(R1)(R2)-O-C(O)- wherein: Ar is an optionally substituted fused polycyclic aryl or heteroaromatic group or a vinylogous derivative thereof; R1 and R2 are independently H, optionally substituted alkyl, alkenyl or alkynyl, optionally substituted aryl or optionally substituted heteroaromatic, or a vinylogous derivative of the foregoing; and X is a leaving group, a chemical fragment linked to Ar-C(R1)(R2)-O-C(O)- via a heteroatom, or a solid support; provided that when Ar is 1-pyrenyl and R1=R2=H, X is not linked to Ar-C(R1)(R2)-O-C(O)- via a nitrogen atom. Preferred embodiments are those in which Ar is a fused polycyclic aromatic hydrocarbon and in which the substituents on Ar, R1 and R2 are electron donating groups. A particularly preferred protecting group is the 'PYMOC' protecting group, pyrenylmethyloxycarbonyl, where Ar=pyrenyl and R1=R2=H. Also provided is a method of forming, from component molecules, a plurality of compounds on a support, each compound occupying a separate predefined region of the support, using the protected compounds described above.

    专利号:US-6951932-B2
    优先权日:2001-10-25
    标 题:Synthesis of 2-aralkoxyadenosines and 2-alkoxyadenosines
    发明人:MOORMAN ALLAN R
    权利人:KING PHARMACEUTICALS RES & DEV
    摘要:The invention provides new methods for synthesis of 2-aralkyloxyadenosines and 2-alkoxyadenosines. The invention is particularly useful for synthesis of 2-[2-(4-chlorophenyl)ethoxy]adenosine. Preferred methods of the invention include activating a guanosine compound followed by hydrolysis; alkylating the hydrolyzed compound with subsequent animation to provide a 2-aralkyloxyadenosine or a 2-alkoxyadenosine compound.

    专利号:US-10173993-B2
    优先权日:2015-12-09
    标题 :Process for the synthesis of sulfones and sulfonamides
    发明人:VON WOLFF NIKLAS; CHAR JOËLLE; CANTAT THIBAULT
    权利人:COMMISSARIAT ENERGIE ATOMIQUE
    摘要:A one pot single step process is described for the synthesis of a compound, including a labeled compound, containing a sulfonyl functional group comprising the step of mixing together a silane, an SO 2 source, an electrophilic compound, an activating compound and optionally a metal catalyst. A process for producing tracers from a labeled sulfonyl containing compound prepared by the described process is also included.

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    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1016/j.jhazmat.2011.06.055
    摘要:Dai Y, Niu J, Yin L, Xu J, Xi Y. Sorption of polycyclic aromatic hydrocarbons on electrospun nanofibrous membranes: sorption kinetics and mechanism. J Hazard Mater. 2011 Sep 15;192(3):1409–17. doi: 10.1016/j.jhazmat.2011.06.055.
    参考文献:10.1021/es201443z
    摘要:Wang W, Jariyasopit N, Schrlau J, Jia Y, Tao S, Yu T, Dashwood RH, Zhang W, Wang X, Simonich SLM. Concentration and Photochemistry of PAHs, NPAHs, and OPAHs and Toxicity of PM2.5 during the Beijing Olympic Games. Environ. Sci. Technol. 2011 Jul 18;45(16):6887–95. doi: 10.1021/es201443z.
    参考文献:10.1007/s10646-011-0737-7
    摘要:Serafim A, Lopes B, Company R, Cravo A, Gomes T, Sousa V, Bebianno MJ. A multi-biomarker approach in cross-transplanted mussels Mytilus galloprovincialis. Ecotoxicology. 2011 Nov;20(8):1959–74. doi: 10.1007/s10646-011-0737-7.
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