CAS: 3091-32-5; Tricyclohexyltin Chloride
该化合物是一种有机锡化合物,其特点是分子式(C6H11)3SnCl.该化合物主要用作有机合成的催化剂或中间体,特别是在涉及酯化,转入和聚合过程的反应中;在中度条件下其稳定性和选择性再活性使其适合用于细化学生产的专门应用;环球氯环十二烷组增强了有机溶剂中的溶性,促进了同质反应条件;三环氯环十二烷也因其在稳定某些聚合系统方面的作用而得到注意;妥善处理由于其对水分和潜在毒性的敏感性,在惰性条件下需要储存,因此必不可少;其受控制的再活性和结构稳健性有助于其在先进的合成化学中的用途.
相似化合物
1449-55-4 6056-50-4 2587-76-0物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS07 & GHS09;
注释: Exclamation mark & Environment - 危险类别急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
水生急性毒性 类别1
水生慢性毒性 类别1 - 警示词Warning(警告)
- 危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H400 |对水生生物毒性极大.
H410 |对水生生物毒性极大并具有长期持续影响. - 防范说明P260-P262-P264-P270-P271-P273-P280-P284-P302+P352-P304+P340-P330-P361+P364-P391-P405-P501
- 危险等级6.1
- UN编号3146.0
- 危险品标志Xn,N
- 包装等级Ⅲ
- 安全声明26-28-61-60
- 危险类别码20/21/22-50/53
- WGK Germany3
欧盟法规
《欧盟PIC法规》统一分类与标签ECHA物质ECHA物质工作场所安全标识要求OtherC&L通报REACH预注册废弃物危险特性清单上下游产品
四环己基锡 Tetracyclohexyl-Stannan 1449-55-4三环己基(丙-2-烯基)锡烷 Cy3Snch2Chch2 13121-83-0
三环己基溴化锡 Tris(Cyclohexyl)Tin Bromide 3023-92-5
丁基(三环己基)锡烷 (Cyclo-C6H11)3Snc4H9 7067-44-9
合成工艺路线路线简述
📜氯代环己烷置于na体系中,用 苯 作为反应溶剂,化学反应生成 三环己基氯化锡
参考文献:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.1,1.1.1.12,Page 121-122
标题:Gmelin Handbuch Der Anorganischen Chemie,Gmelin Handbook: Sn: Org.Verb.1,1.1.1.12,Page 121-122
专利信息
专利号:US-8329923-B2
优先权日:2010-06-17
标 题:4, 4′ disubstituted 4H-cyclopentadithiophene and new methods for synthesizing the same
发明人：VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH
权利人:VANDERZANDE DIRK; LUTSEN LAURENCE; VAN MIERLOO SARAH; IMEC; UNIV HASSELT
摘要:The present preferred embodiments relate to a method for the synthesis of a compound having the following general formula: n nthe method comprising the step of reacting, in presence of a diprotic acid having a negative pKa, a compound having the general formula:n n nwherein R 1 and R 2 are organic groups and wherein X and Y are independently selected from the group consisting of hydrogen, chloro, bromo, iodo, boronic acid, boronate esters, borane, pseudohalogen and organotin. It further relates to compounds so obtained and to compounds resulting from the ring closure of compound (II).
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 155.
摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 2004. Toxicity, Repellency of Phytotoxicity of 979 Chemicals to Birds, Mammals and Plants. Research Report No. 04-01. National Wildlife Research Center, Fort Collins, Colorado. 118 pp.
摘要:Ielo, L.; Pace, V., Science of Synthesis: Knowledge Updates, (2025) 2.
参考文献:10.1007/s00216-004-2735-6
摘要:Capitán-Vallvey LF, Guerrero EA, Merelo CB, Ramos MDF. A test strip for chloride analysis in environmental water. Analytical and Bioanalytical Chemistry. 2004 Aug 21;380(3):563–9. doi: 10.1007/s00216-004-2735-6.
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