CAS: 2169-87-1; Naphthalene-2,3-Dicarboxylic Acid

该化合物其结构特征为结构,在2和3个位置上附于一个氯化萘环上的两个箱状酸组(COOH),该化合物看起来像白色的脱白晶状固体,在水和酒精等极地溶剂中溶解,但在非极地溶剂中不易溶解;由于碳箱酸组的存在,其酸性具有酸性,允许其参与各种化学反应,包括酯化和恐吓;2,3-Naphtha-nedicaboxylic 酸用于各种衍生物和聚合物的合成,作为有机合成的中间体;此外,该化合物在材料科学和药物领域具有潜在用途;在标准条件下,其稳定性使它成为进一步化学修改和研究应用的合适选择.

结构式图片

相似化合物

7149-49-7 22856-30-0 39110-32-2

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合成工艺路线路线简述

  • 合成目标产物 2,3-Naphthalenedicarboxylic Acid 主要起始原料 2,3-Naphthalenedicarboxylic Anhydride
  • (文献来源)合成步骤主要原料 2,3-Naphthalenedicarboxylic Anhydride
苯并[c]碲置于sodium Hydroxide体系中,用 苯 用作溶剂,化学反应生成2,3-萘二羧酸
参考文献:O-Quinonoid Heterocycles: Benzo[c]Tellurophene
标题:O-Quinonoid Heterocycles: Benzo[c]Tellurophene
摘要:
Doi:10.1016/s0040-4039(96)02164-8

海关参考信息

专利信息


专利号:US-12263464-B2
优先权日:2018-03-14
标题 :Method for in-situ synthesis of metal organic frameworks (MOFs), covalent organic frameworks (COFs) and zeolite imidazolate frameworks (ZIFs), and applications thereof
发明人:PAHWA DEEPAK; PAHWA VARUN; CHOUDHARY ANIL KUMAR; SONIA; JHA VIVEK KUMAR; CHAUHAN ANJALI; YADAV ANNU
权利人:DESICCANT ROTORS INTERNATIONAL PRIVATE LTD
摘要:The present invention relates to a method for the in situ synthesis of of MOFs (metal organic frameworks), COFs (covalent organic frameworks), and ZIFs (Zeolitic imidazolate framework), onto and within different types of porous substrates, and their applications. The present invention provides a unique and easy to utilize method by which a number of MOFs, COFs and ZIFs can be synthesized directly onto and within a porous substrate with high performance efficiency ensuring higher grammage in formation of adsorbent product onto and within the substrate.

专利号:US-2022089618-A1
优先权日:2019-01-29
标题:Solid-State Synthesis Of Precursors Of Metal-Organic Frameworks
发明人:MAJANO GERARDO J; FALKOWSKI JOSEPH M
权利人:EXXONMOBIL RES & ENG CO
摘要:Metal-organic frameworks (MOFs) are highly porous entities comprising a multidentate ligand coordinated to multiple metal atoms, typically as a coordination polymer. MOFs are usually produced from a solvent in powder form under hydrothermal or solvothermal synthesis conditions. Alternately, powder-form precursors of MOFs may be formed by milling or mulling a substantially solid mixture of a metal salt and a multidentate organic ligand, optionally in the presence of a small amount of a solvent. The powder-form precursors may then undergo heating, typically in the absence of applied shear, to produce the corresponding MOF. Mulling may be differentiated from milling at least in that mulling applies to the substantially solid mixture at a non-constant pressure and milling applies a constant pressure while forming the powder-form precursor. In some cases, mulling may promote more effective formation of the powder-form precursor compared to milling.

专利号:US-4201869-A
优先权日:1970-12-21
标 题:Intermediates for steroid total synthesis process utilizing asymmetric induction
发明人:COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A multi-step, stereospecific total synthesis of steroids is disclosed. The starting materials for this process are the relatively inexpensive and readily available m-alkoxy acetophenones. The process is suitable for the preparation of racemic or optically active, medicinally valuable steroids, particularly A-ring aromatic steroids. This process features an early optical resolution and a unique asymmetric induction which insures the correct stereochemistry of the final steroidal product.

专利号:US-4092483-A
优先权日:1973-10-16
标题 :Intermediates for steroid total synthesis process utilizing asymmetric induction
发明人:COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A multi-step, stereospecific total synthesis of steroids is disclosed. The starting materials for this process are the relatively inexpensive and readily available m-alkoxy acetophenones. The process is suitable for the preparation of racemic or optically active, medicinally valuable steroids, particularly A-ring aromatic steroids. This process features an early optical resolution and a unique asymmetric induction which insures the correct stereochemistry of the final steroidal product.

专利号:US-4102925-A
优先权日:1970-12-21
标题:Steroid total synthesis process utilizing asymmetric induction
发明人:COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A multi-step, stereospecific total synthesis of steroids is disclosed. The starting materials for this process are the relatively inexpensive and readily available m-alkoxy acetophenones. The process is suitable for the preparation of racemic or optically active, medicinally valuable steroids, particularly A-ring aromatic steroids. This process features an early optical resolution and a unique asymmetric induction which insures the correct stereochemistry of the final steroidal product.

专利号:US-4011211-A
优先权日:1973-10-16
标题:Steroid total synthesis process utilizing asymmetric induction
发明人:COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A multi-step, stereospecific total synthesis of steroids is disclosed. The starting materials for this process are the relatively inexpensive and readily available m-alkoxy aceto-phenones. The process is suitable for the preparation of racemic or optically active, medicinally valuable steroids, particularly A-ring aromatic steroids. This process features an early optical resolution and a unique asymmetric induction which insures the correct stereochemistry of the final steroidal product.
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✅ COA系统入驻 | 共享模式

主要参考文献

[参考文献]: L J Fitzgerald, Et Al. Structure Of 2,3-Naphthalenedicarboxylic Acid. Acta Crystallogr C. 1992 Nov 15:48 ( Pt 11):1971-5.

合成参考文献


参考文献:10.2116/analsci.22.807
摘要:Yokoyama T, Tsuchiya Y, Murakami G, Zenki M. Capillary electrophoretic determination of self-dimerization constants of aromatic carboxylate and sulfonate ions. Anal Sci. 2006 Jun;22(6):807–10. doi: 10.2116/analsci.22.807.
参考文献:10.1007/s00253-005-0219-z
摘要:Keum YS, Seo JS, Hu Y, Li QX. Degradation pathways of phenanthrene by Sinorhizobium sp. C4. Appl Microbiol Biotechnol. 2006 Aug;71(6):935–41. doi: 10.1007/s00253-005-0219-z.
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