CAS: 130783-02-7; 3,5-Bis(Trifluoromethyl)Benzenethiol

上下游产品

3,5-bis(trifluoromethyl)benzenesulfonyl chloride isopropyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate benzyl {[3,5-bis(trifluoromethyl)phenyl]thio}acetate 2-[3,5-di(trifluoromethyl)phenylsulfanyl]-1-ethanol 2-(3,5-bis-trifluoromethyl-phenylsulfanyl)-benzaldehyde

3,5-二三氟甲基苯磺酰氯置于potassium Formate体系中,化学反应 7.0H,以51%的收率获得3,5-双(三氟甲基)苯硫酚
参考文献:Solvent-Free Synthesis Of Thiophenol Using Uncatalyzed Transfer Hydrogenation
标题:Solvent-Free Synthesis Of Thiophenol Using Uncatalyzed Transfer Hydrogenation
摘要:Clean And Sustainable Transfer Hydrogenation For Aryl Sulfonamides And Sulfonyl Chlorides Is Described. The Protocol Is Chemoselective And Uses Neither Catalyst Nor Solvent.
Doi:10.1080/00397911.2011.559317

专利信息

专利号:US-10150160-B2
优先权日:2014-12-04
标题 :Universal one-pot and up-scalable synthesis of SERS encoded nanoparticles
发明人：PAZOS PÉREZ NICOLÃ?S; MIR DE SIMÓN BERNAT
权利人:MEDCOM ADVANCE S A; MEDCOM ADVANCE S A
摘要:The universal one-pot and up-scalable synthesis of SERS encoded nanoparticles relies on the controlled co-absorption of mercaptoundecanoic acid (MUA) and the Raman code on the metallic surfaces of the nanoparticles. In contrast to most of the reported procedures which typically involve complex steps, the present method has demonstrated to be an easy and fast one-pot approach for the production of SERS-encoded nanoparticles. This versatile strategy allows for the SERS codification of particles with every molecule with affinity toward the metal surface, independently of its chemical nature, as exemplified here in the fabrication of 31 different encoded particles using the same standard procedure. In addition to the easiness of preparation, scalability to the liter regime, stability in aqueous solutions including PBS and chemical diversity, our SERS-encoded particles show considerably higher optical efficiency than those fabricated by using PEG or PVP polymers.

专利号:US-9260423-B2
优先权日:2011-12-09
标 题:Process for the preparation of a thioprecursor for statins
发明人：DE LANGE BEN; HEEMSKERK DENNIS; BESSEMBINDER KARIN HENDERIKA MARIA
权利人:DSM SINOCHEM PHARM NL BV
摘要:The present invention relates to a process for the preparation of a precursor for the synthesis of hexanoic acid derived statins and to the use of said precursor in the manufacture of a medicament.

专利号:US-2017326638-A1
优先权日:2014-12-04
标 题:Universal one-pot and up-scalable synthesis of sers encoded nanoparticles

专利号:EP-3227037-A1
优先权日:2014-12-04
标 题:Universal one-pot and up-scalable synthesis of sers encoded nanoparticles

专利号:EP-3227037-B1
优先权日:2014-12-04
标题 :Universal one-pot and up-scalable synthesis of sers encoded nanoparticles

专利号:ES-2673013-T3
优先权日:2014-12-04
标题:Universal synthesis of a single, large-scale, realizable reaction of nanoparticles encoded with SERS