专利号:US-4666945-A 优先权日:1983-11-14 标 题:Catalyst composition suitable for synthesis of methanol 发明人:OSUGI MINORU; TAKAGAWA MAKOTO; NAKAMURA TADASI; KOJIMA TAKASHI; TSUJI KINYA 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:A catalyst composition comprising copper oxide, zinc oxide and zirconium oxide, the content of zirconium oxide being 30 to 70% by weight. This catalyst composition is useful for synthesis of methanol from carbon monoxide and/or carbon dioxide and hydrogen by a gas-liquid-solid phase fluidized bed method or a gas-solid phase fluidized bed method.
专利号:US-4436835-A 优先权日:1982-03-24 标 题:Process for preparation of catalysts 发明人:HORIE SHIGERU; YAMAMOTO YASUO; IKARASHI TAKEO 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:Disclosed is a process for the preparation of a catalyst for the synthesis of methyl formate by dehydrogenating methanol in the gaseous phase, said process being characterized in that (A) at least one phosphate selected from the group consisting of copper phosphates, zinc phosphates and aluminum phosphates, and (B) at least one chloride selected from the group consisting of copper chlorides, zinc chloride, aluminum chloride, alkali metal chlorides and alkaline earth metal chlorides and/or (C) at least one compound selected from the group consisting of alkali metal compounds (exclusive of halides) and alkaline earth metal compounds (exclusive of halides) are added to copper oxide, zinc oxide and aluminum oxide. The catalyst obtained according to this process has a high activity for preparing methyl formate by dehydrogenating methanol in the gaseous phase, and this catalyst is excellent in the heat resistance and durability and has a high mechanical strength.
专利号:US-4547482-A 优先权日:1982-07-21 标题:Catalyst composition suited for synthesis of methanol 发明人:OSUGI MINORU; NAKAMURA TADASI; EBATA SHUJI 权利人:MITSUBISHI GAS CHEMICAL CO 摘要:A catalyst composition comprising copper oxide, zinc oxide and an oxyacid of phosphorus or its salt; and a method for producing methanol by reacting carbon monoxide and/or carbon dioxide with hydrogen in the vapor phase in the presence of a catalyst, wherein the catalyst is the aforesaid catalyst composition which has been activated by reduction with a hydrogen-containing gas.
专利号:CN-108727462-B 优先权日:2018-07-11 标题 :A kind of preparation method of four-step synthesis of 28-homobrassinolide
专利号:CN-110551153-A 优先权日:2019-10-07 标 题 :A kind of preparation method of three-step synthesis of tenofovir alafenamide
专利号:CA-1202947-A 优先权日:1982-07-21 标 题 :Catalyst composition suited for synthesis of methanol
参考文献:10.1007/bf00296291 摘要:Hirsch D, Landis WJ, Azoury R, Sarig S. Liposome interactions with hydroxyapatite crystals: a possible mechanism in the calcification of atherosclerotic plaques. Calcif Tissue Int. 1992 Mar;50(3):261–5. doi: 10.1007/bf00296291. 参考文献:10.1007/978-3-031-27062-8_17 摘要:Kopac T. Metal Phosphates for Environmental Remediation: Adsorptive Removal of Dyes from Wastewater. 2023. In: Engineering Materials.