CAS: 82-45-1; 1-Aminoanthracene-9,10-Dione

• 英文名称1-Aminoanthracene-9,10-Dione
• 中文名称1-氨基蒽醌
• IUPAC名称1-aminoanthracene-9,10-dione
• 其它别名1-氨基蒽并醌; Diazo Fast Red Al
• CAS编号82-45-1
• MFCD编号:MFCD00001213
• EINECS号:201-423-5
• 分子式:C14H9NO2
• 分子量:223.23
• 产品CID: 1815290
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• 产品信息参考;;;;
• InChIKey: KHUFHLFHOQVFGB-UHFFFAOYSA-N
• InChI=1S/C14H9NO2/c15-11-7-3-6-10-12(11)14(17)9-5-2-1-4-8(9)13(10)16/h1-7H,15H2…
• 计算化学: 氢键受体数3.0氢键供体数1.0可旋转键数0.0

物理性质

• 熔点253-255°C
• 沸点464.9°C at 760 mmHg
• 闪点235°C
• 密度1.4±0.1 g/cm3
• pKa:-0.51±0.20(预测)
• PSA:60.16
• LogP:2.0442
• 折射率1.708
• 蒸汽压0.0±1.1 mmHg at 25°C
• 溶解性Soluble In Alcohol, Benzene, Chlroform, Ether, Glacial Acetic Acid, Hcl
• 敏感性1.毒性和刺激性比蒽醌强。能造成皮肤过敏，引起湿疹。生产车间应通风良好，设备应密闭。操作时应穿戴防护用具。2.避免吸入本品的粉尘，避免与眼睛及皮肤接触。
• 外观形态橙色至棕色至深红色粉末至晶体
• 储存条件室温
• 产品应用用于制蒽醌染料,药物及测定亚硝酸盐等.
• 性质描述红色或橙红色针状结晶.熔点253-254°C.溶于乙醇,乙醚,氯仿,丙酮,苯,冰醋酸,热硝基苯及盐酸,硫酸中,不溶于水.

MSDS等安全信息

• GHS象形图
• GHS符号GHS07;
  注释: Exclamation mark
• 危险类别特定目标器官毒性 - 单次接触 类别3
  皮肤腐蚀/刺激 类别2
  严重眼刺激 类别2
  急性毒性 类别4(吸入)
  急性毒性 类别4(经皮)
  水生急性毒性 类别1
  水生慢性毒性 类别1
  严重眼刺激 类别2A
• 警示词Warning(警告)
• 危险描述H335 |可能引起呼吸道刺激.
  H315 |造成皮肤刺激.
  H319 |造成严重眼刺激.
  H332 |吸入有害.
  H312 |皮肤接触有害.
  H400 |对水生生物毒性极大.
  H410 |对水生生物毒性极大并具有长期持续影响.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P330-P362+P364-P403+P233-P405-P501
• 危险等级9
• UN编号3077
• 危险品标志Xn
• 包装等级III
• 安全声明24/25
• 危险类别码36/37/38
• WGK Germany1

欧盟法规

上下游产品

合成工艺路线路线简述

• 合成目标产物 1-Aminoanthraquinone 主要起始原料 1-Nitroanthraquinone
• 82-34-8 = 82-45-1 + 129-43-1 + 82-28-0
  反应条件:1.1 Solvents: Dimethylformamide
  标题:Reaction Of 1-Nitroanthraquinone With Hexamethylenetetramine
  作者:Galich,L. V.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1986 卷标:22(12) 页码:2619-20]
  
  5960-64-5 = 82-45-1
  反应条件:1.1 Reagents: Sulfuric Acid
  标题:C-Formylation Of α-Phenylaminoanthraquinones By Formaldehyde. Reaction Of α-Aminoanthraquinones With Formaldehyde In A Sulfuric Acid Medium
  作者:Kazankov,M. V.; Et Al
  参考文献:Zhurnal Organicheskoi Khimii 日期:1983 卷标:19(3) 页码:597-606]
  
  1147-43-9 = 82-45-1
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid
  标题:Manufacture Of 1-Aminoanthraquinones
  参考文献:Japan]
  
  110605-50-0 = 82-45-1
  反应条件:1.1 Reagents: Ethylenediamine Solvents: Ethanol; 6 H,Rt
  标题:2,2-Bis(Ethoxycarbonyl)Vinyl (Becv) As A Versatile Amine Protecting Group For Selective Functional-Group Transformations
  作者:Ilangovan,Andivelu; Et Al
  参考文献:Chemistry - A European Journal 日期:2010 卷标:16(9) 页码:2938-2943]
  
  = 82-45-1
  反应条件:1.1 Reagents: Potassium Hydroxide; 24 H,Reflux
  标题:Influence Of Substituents 5-Substituted 1,4-Naphthoquinones On Regioselectivity Of Diels-Alder Reaction
  作者:Dumanska,Yulia; Et Al
  参考文献:Journal Of Chemical And Pharmaceutical Research 日期:2015 卷标:7(8) 页码:697-702]
  
  82-44-0 = 82-45-1
  反应条件:1.1 Reagents: Potassium Amide
  标题:Reactions Of 1,5-Dichloroanthraquinone With Nucleophiles
  作者:Ruediger,Edward H.; Et Al
  参考文献:Journal Of Organic Chemistry 日期:1980 卷标:45(10) 页码:1974-8]
  
  82-44-0 = 82-45-1
  反应条件:1.1 Reagents: Sulfuric Acid2.1 Reagents: Sodium Azide3.1 Reagents: Iodobenzene Diacetate
  标题:Pyrolysis Of Aryl Azides. Xi. Enhanced Neighboring Group Effects Of Carbonyl In A Locked Conformation
  作者:Dyall,Leonard K.; Et Al
  参考文献:Australian Journal Of Chemistry 日期:1992 卷标:45(12) 页码:1991-2002]
  
  1715-82-8 = 82-45-1
  反应条件:1.1 Reagents: Iodobenzene Diacetate
  标题:Pyrolysis Of Aryl Azides. Xi. Enhanced Neighboring Group Effects Of Carbonyl In A Locked Conformation
  作者:Dyall,Leonard K.; Et Al
  参考文献:Australian Journal Of Chemistry 日期:1992 卷标:45(12) 页码:1991-2002]
  
  82-34-8 = 82-45-1
  反应条件:1.1 Reagents: Hydrogen Catalysts: Nickel Alloy,Base,Ni 73,Cu 27 Solvents: Dimethylformamide; 4 H,0.5 Mpa,120 °C
  标题:Synthesis Of Bimetallic Cuxniy Nanoparticles For Selective Hydrogenation Of 1-Nitroanthraquinone With Gaseous H2 To 1-Aminoanthraquinone
  作者:Wang,Aili; Et Al
  参考文献:Colloids And Surfaces 日期:2020 卷标:601]
  
  82-34-8 = 82-45-1
  反应条件:1.1 Reagents: Carbon Monoxide,Sodium Hydroxide,Water Catalysts: Rhodium,Tri-μ-Carbonylnonacarbonyltetra-,Tetrahedro,9,10-Diaminophenanthrene Solvents: 2-Methoxyethanol
  标题:Efficient Selective Reduction Of Aromatic Nitro Compounds Affording Aromatic Amines Under Carbon Monoxide/water Conditions Catalyzed By Amine-Added Rhodium-Carbonyl Complexes
  作者:Nomura,Kotohiro; Et Al
  参考文献:Bulletin Of The Chemical Society Of Japan 日期:1991 卷标:64(9) 页码:2624-8]
  
  5960-64-5 = 82-45-1 [标题:Reaction Conditions
  标题:Elimination Of N-Substituents From Derivatives Of 1-Aminoanthraquinone
  作者:Bradley,William; Et Al
  参考文献:Journal Of The Chemical Society 日期:1954 卷标:247 页码:247-52]
  
  65270-01-1 = 82-45-1
  反应条件:1.1 Reagents: Sulfuric Acid
  标题:Serum Phosphorus And Potassium Levels After Intravenous Administration Of Glucose. Their Use As Diagnostic Aids In Diabetic And Nondiabetic Subjects With And Without Liver Disease
  作者:Gundersen,Kare; Et Al
  参考文献:New England Journal Of Medicine 日期:1954 卷标:250 页码:547-54]
  
  = 82-45-1
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol; 10 Min,Reflux
  标题:Pd-Catalyzed α-Selective C(Sp3)-H Acetoxylation Of Amides Through An Unusual Cyclopalladation Mechanism
  作者:Wang,Meining; Et Al
  参考文献:Chemical Communications (Cambridge 日期:2015 卷标:51(15) 页码:3219-3222]
  
  1143-50-6 = 82-45-1
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid
  标题:Manufacture Of 1-Aminoanthraquinones
  参考文献:Japan]
  
  42013-62-7 = 82-45-1
  反应条件:1.1 Reagents: Sodium Sulfide Hydrate Catalysts: Methanol; 1 Min,Rt
  标题:Chemoselective Reduction Of Azides With Sodium Sulfide Hydrate Under Solvent Free Conditions
  作者:Kazemi,Foad; Et Al
  参考文献:Phosphorus 日期:2004 卷标:179(9) 页码:1813-1817]
  
  = 82-45-1 [标题:Reaction Conditions
  标题:Photolysis Of (Nitrosomethylamino)Anthraquinones
  作者:Klimenko,L. S.; Et Al
  参考文献:Izvestiya Akademii Nauk Sssr 日期:1991 卷标:(9) 页码:2098-102]
  
  520-03-6 = 82-45-1
  反应条件:1.1 Reagents: Trifluoromethanesulfonic Acid
  标题:Preparation Of 1-Aminoanthraquinones
  参考文献:Japan]
  
  569-06-2 = 82-45-1
  反应条件:1.1 Reagents: Ammonia
  标题:Photoamination Of 1- And 2-Substituted 9,10-Anthraquinone
  作者:Lukonina,S. M.; Et Al
  参考文献:Izvestiya Sibirskogo Otdeleniya Akademii Nauk Sssr 日期:1979 卷标:(2) 页码:90-5]
  
  = 82-45-1 [标题:Reaction Conditions
  标题:Preparation Of 1-Aminoanthraquinone From 4-Amino-9-Anthrone
  作者:Gronowska,Janina; Et Al
  参考文献:Prace Wydzialu Nauk Technicznych 日期:1985 卷标:15 页码:61-4

海关参考信息

• 2912110000-甲醛
  2912210000-苯甲醛
  2914610000-蒽醌
  2914190090-其他无环酮
• 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
• 详情请参考：📖 海关编码查询和海关进出口税则

其他信息查阅

• ➥ 象形图和危险代码
• ➥ 防范代码详解
• ➥ 危险代码说明
• ➥ Globally Harmonized System
• ➥ REACH监管