N-烯丙基咪唑置于叔丁基过氧化氢,Mn(Dpm)3,苯硅烷体系中,用 癸烷,异丙醇 用作溶剂,以69%的收率获得1-丙基咪唑
参考文献:Simple,Chemoselective Hydrogenation With Thermodynamic Stereocontrol
标题:Simple,Chemoselective Hydrogenation With Thermodynamic Stereocontrol
摘要:Few Methods Permit The Hydrogenation Of Alkenes To A Thermodynamically Favored Configuration When Steric Effects Dictate The Alternative Trajectory Of Hydrogen Delivery. Dissolving Metal Reduction Achieves This Control,But With Extremely Low Functional Group Tolerance. Here We Demonstrate A Catalytic Hydrogenation Of Alkenes That Affords The Thermodynamic Alkane Products With Remarkably Broad Functional Group Compatibility And Rapid Reaction Rates At Standard Temperature And Pressure.
Doi:10.1021/ja412342G