专利号:WO-2022196043-A1 优先权日:2021-03-17 标 题:Method for producing zeolite 发明人:IKEHARA YUYA; TANAKA KEISUKE; MURAKAMI MASAYOSHI; SEKI KOHEI 权利人:SUMITOMO CHEMICAL CO 摘要:The present invention further improves the selectivity of ε-caprolactam. This method is for producing zeolite and comprises steps (1)-(5). Step (1): A step for mixing tetraalkyl orthosilicate, water, and a hydroxylated quaternary ammonium to obtain a mixture. Step (2): A step for, while causing the mixture obtained in step (1) to undergo a hydrothermal synthesis reaction, supplying, to the mixture, at least one compound (A) selected from the group consisting of boron compounds, germanium compounds, magnesium compounds, aluminum compounds, tin compounds, and iron compounds to obtain a reaction mixture containing zeolite crystals. Step (3): A step for performing solid-liquid separation on the reaction mixture containing zeolite crystals obtained in step (2), to obtain zeolite crystals. Step (4): A step for sintering the zeolite crystals obtained in step (3). Step (5): A step for bringing the zeolite crystals sintered in step (4) into contact with an aqueous solution containing at least one acid selected from the group consisting of inorganic acids and organic acids to obtain zeolite.
参考文献:10.1007/s10646-011-0739-5 摘要:Antizar-Ladislao B, Sarkar SK, Anderson P, Peshkur T, Bhattacharya BD, Chatterjee M, Satpathy KK. Baseline of butyltin contamination in sediments of Sundarban mangrove wetland and adjacent coastal regions, India. Ecotoxicology. 2011 Nov;20(8):1975–83. doi: 10.1007/s10646-011-0739-5.