CAS: 105-86-2; 3,7-Dimethylocta-2,6-Dien-1-Yl Formate

相似化合物

105-87-3 141-12-8 2345-26-8

上下游产品

formic acid Geraniol carbon monoxide (formyloxy)(acetoxy)phenylmethane dihydromyrcene [(E)-2-((E)-3,7-Dimethyl-°Cta-2,6-dienyloxy)-vinyl]-benzene (E/Z)-3,7-dimethyl-2,6-°Ctadienal

香叶醇,Formyloxyacetoxyphenylmethane置于碳酸氢钠体系中,用 Neat (No Solvent) 用作溶剂,化学反应 16.0H,以85%的收率获得甲酸香叶酯
参考文献:甲酰氧基乙酰氧基苯甲烷和1,1-二醛作为醇类通用的o-甲酰化和o-酰化试剂
标题:甲酰氧基乙酰氧基苯甲烷和1,1-二醛作为醇类通用的o-甲酰化和o-酰化试剂
摘要:在无溶剂/催化剂的情况下,甲氧基乙氧基苯基甲烷,对称的1,1-二醛和混合的1-新戊氧基-1-酰氧基-1-苯基甲烷已被用作伯,仲醇,烯丙基醇和苯酚的湿气稳定的o-甲酰化和o-酰化试剂.条件以高收率得到其相应的酯.
Doi:10.1016/j.Tet.2018.09.014

专利信息

专利号:US-4665221-A
优先权日:1978-04-26
标 题 :Preparation of terpenoid formates
发明人：THOEMEL FRANK; HOFFMANN WERNER
权利人:BASF AG
摘要:An improved process for the preparation of primary terpenoid alcohols, e.g. 6,7-dihydrogeraniol and phytol, and of their esters with formic acid. The terpenoid formates are obtained very advantageously by reacting the corresponding tert.-vinylcarbinols with more than 2 moles, per mole of vinylcarbinol, of aqueous formic acid of more than 70 percent strength by weight, or with anhydrous formic acid, at from 5 DEG to 100 DEG C. The primary terpenoid alcohols themselves are obtained from their formates by trans-esterification with a low-boiling alcohol in the presence of a catalytic amount of a strong base. The products are valuable compounds. For example, 6,7-dihydrogeraniol is used as a scent and phytol is used as a perfume fixative and as a starting material for the synthesis of naturally occurring materials.

专利号:WO-2006045963-A3
优先权日:2004-10-28
标 题:Composition of cosmetic or pharmacological application for stimulation of synthesis of collagen

专利号:US-2025121362-A1
优先权日:2022-01-25
标题 :Novel compositions for the sustainable catalysis of organic synthesis reactions
发明人：GRISON CLAUDE; LOCK TOY KI YVETTE
权利人:CENTRE NAT RECH SCIENT; UNIV MONTPELLIER
摘要:A composition comprising K2CO3, KCl, and optionally K2SO4 and/or KHCO3, having a weight content of potassium between 9.0 and 60.0% relative to the total weight of the composition, preferably between 10.0 and 50.0%, more preferably between 10.0 and 40.0%, advantageously between 20.0 and 40.0%.

专利号:WO-2006045963-A2
优先权日:2004-10-28
标题:Composition of cosmetic or pharmacological application for stimulation of synthesis of collagen

专利号:WO-2023144167-A1
优先权日:2022-01-25
标 题:Novel compositions for the sustainable catalysis of organic synthesis reactions

专利号:EP-4215267-A1
优先权日:2022-01-25
标 题 :Novel compositions for the sustainable catalysis of organic synthesis reactions