CAS: 88485-37-4; Fluxofenim

该化合物是一种化学化合物,主要用于农业用途中的除草剂,属于被称为苯尿素的化学品类别,其特点是它们有能力通过干扰特定的生化途径抑制植物生长,对一系列大叶杂草和草特别有效,使其对作物管理有价值,该化合物通常在出现前或出现后应用,取决于目标的杂草和作物类型,其行动方式涉及破坏植物的光合作用和其他关键过程,它通常被认为对哺乳动物具有低毒性,但与许多农用化学品一样,它需要谨慎地处理和应用,以尽量减少环境影响,此外,它在土壤中的持久性及其对非目标生物的潜在影响是其使用中的重要考虑因素,与任何化学物质一样,遵守安全准则和条例对于确保有效和负责任地在农业做法中使用至关重要.

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欧盟法规

ECHA物质C&L通报REACH预注册

上下游产品

2-bromomethyl-1,3-dioxolane 1-(4-chlorophenyl)-1-hydroximino-2,2,2-trifluoroethane

合成工艺路线路线简述

    📜2-溴甲基-1,3-二氧戊烷,(4-Chlorophenyl) Trifluoromethyl Ketoxime 以 乙醇,二甲基亚砜 作为反应溶剂,化学反应生成 1-(4-Chlorophenyl)-1-(1,3-Dioxolan-2-Ylmethoxyimino)-2,2,2-Trifluoroethane,氟草肟
    参考文献:Oxime Ethers,Compositions Containing Them And The Use Thereof
    标题:Oxime Ethers,Compositions Containing Them And The Use Thereof
    摘要:化学式i所示的肟醚能够作为解毒剂或安全剂,保护栽培植物免受除草剂的植物毒性影响.这种栽培植物主要是高粱,谷物,玉米和稻米,而除草剂主要是氯乙酰苯胺和硫代氨基甲酸酯.肟醚的化学式如下:其中n为1或2,R.Sub.1和r.Sub.2分别为氢或c.Sub.1-C.Sub.4烷基,R.Sub.3和r.Sub.4分别为氢,卤素,C.Sub.1-C.Sub.4烷基,C.Sub.1-C.Sub.4卤代烷基,C.Sub.1-C.Sub.4烷氧基,C.Sub.1-C.Sub.4卤代烷氧基,C.Sub.1-C.Sub.4烷硫基,C.Sub.1-C.Sub.4卤代烷硫基,C.Sub.1-C.Sub.4烷基亚砜,C.Sub.1-C.Sub.4烷基砜,C.Sub.1-C.Sub.4卤代烷基亚砜,C.Sub.1-C.Sub.4卤代烷基砜或硝基;r.Sub.5和r.Sub.6中的每一个独立地为c.Sub.1-C.Sub.4烷基,C.Sub.1-C.Sub.4卤代烷基,C.Sub.2-C.Sub.8烷氧基烷基,C.Sub.3-C.Sub.4烯基,C.Sub.3-C.Sub.4炔基,或者一起形成一个2-到6-成员的烷基或烯基桥,该桥可能被1至4个c.Sub.1-C.Sub.4烷基,C.Sub.1-C.Sub.4卤代烷基,C.Sub.1-C.Sub.4烷氧基,C.Sub.2-C.Sub.4烯氧基,C.Sub.2-C.Sub.8烷氧基烷基或c.Sub.3-C.Sub.8烯氧基烷基基团取代;a和b中的每一个独立地为氧或硫,或者a和b中的一个是亚甲基基团,X是氟化的c.Sub.1-C.Sub.3烷基基团,也可能额外含有氯,Y为氢,C.Sub.1-C.Sub.4烷基,C.Sub.1-C.Sub.4卤代烷基,C.Sub.1-C.Sub.4烷氧基,C.Sub.1-C.Sub.4卤代烷氧基或苯基.

    海关参考信息

    专利信息


    专利号:US-2021386068-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and very long chain fatty acid (vlcfa) synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a VLCFA synthesis inhibitor herbicide. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof, and (b) a VLCFA synthesis inhibitor herbicide.

    专利号:US-2021352899-A1
    优先权日:2018-11-07
    标题 :Compositions comprising pyridine carboxylate herbicides and fatty acid and lipid synthesis inhibitor herbicides
    发明人:KISTER JEREMY; SATCHIVI NORBERT M
    权利人:CORTEVA AGRISCIENCE LLC
    摘要:Disclosed herein are compositions comprising (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof. Also disclosed herein are methods of controlling undesirable vegetation, comprising applying to vegetation or an area adjacent the vegetation or applying in soil or water to control the emergence or growth of vegetation (a) a pyridine carboxylate herbicide or an agriculturally acceptable N-oxide, salt, or ester thereof and (b) a fatty acid and lipid synthesis inhibitor (FA/LSI) herbicide, an agriculturally acceptable salt or ester thereof, or mixtures thereof.

    专利号:ES-2717283-T3
    优先权日:2012-07-24
    标 题:Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6- (4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and herbicides inhibitors of VLCFA synthesis and synthesis of fatty acids / lipids

    专利号:BR-102013018473-B1
    优先权日:2012-07-24
    标题 :HERBICIDAL COMPOSITIONS COMPENDIENT 4-AMINO-3-CHLORO-5-FLUORO-6- (4-CHLORO-2-FLUORO-3-ETOXYPHENYL) PYRIDINE-2-CARBOXYLIC ACID OR A DERIVATIVE OF THE SAME AND HERBICIDES INHIBITING THE SYNTHESIS OF VLCFA AND SYNTHESIS OF GRAIN ACID / LIPID, AND METHOD FOR UNDESIRABLE VEGETATION CONTROL

    专利号:TW-I655905-B
    优先权日:2012-07-24
    标题 :Contains 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl)pyridine-2-carboxylic acid or a derivative thereof and very long chain fatty acid (VLCFA) Synthesis of herbicidal compositions with fatty acid/fat synthesis inhibiting herbicides

    专利号:US-9644469-B2
    优先权日:2012-07-24
    标题 :Herbicidal compositions comprising 4-amino-3-chloro-5-fluoro-6-(4-chloro-2-fluoro-3-methoxyphenyl) pyridine-2-carboxylic acid or a derivative thereof and VLCFA and lipid synthesis inhibiting herbicides
    发明人:YERKES CARLA N; MANN RICHARD K; SHIRAISHI IKUO; YANAGIYAMA SHINGO; SATCHIVI NORBERT M
    权利人:DOW AGROSCIENCES LLC
    摘要:A synergistic herbicidal composition containing (a) a compound of formula (I): n nor an agriculturally acceptable salt or ester thereof and (b) VLCFA and fatty acid/lipid synthesis inhibiting herbicides, including but not limited to, acetochlor, alachlor, anilofos, benfuresate, cafenstrole, dimethenamid-P, fentrazamide, indanofan, flufenacet, mefenacet, s-metolachlor, molinate, pethoxamid, pretilachlor, prosulfocarb, pyroxasulfone, thenylchlor and thiobencarb, or a salt or ester thereof, provide synergistic weed control of undesirable vegetation in direct-seeded, water-seeded and transplanted rice, cereals, wheat, barley, oats, rye, sorghum, corn or maize, sugarcane, sunflower, oilseed rape, canola, sugar beet, soybean, cotton, pineapple, pastures, grasslands, rangelands, fallowland, turf, tree and vine orchards, aquatics, plantation crops, vegetables, industrial vegetation management (IVM) or rights-of-way (ROW).

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

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    ✅ COA系统入驻 | 共享模式

    主要参考文献


    1: Shi Y, Wang J, Wang Z, Jiao Z, Du Q, Jia X, Niu J, Du R, Ji G, Duan P, Lv P, Cao J. Integrating transcriptome and physiological analyses to elucidate the molecular responses of sorghum to fluxofenim and metolachlor herbicide. Pestic Biochem Physiol. 2023 Dec;197:105692. doi: 10.1016/j.pestbp.2023.105692. Epub 2023 Nov 14. 62(10):927-32. doi: 10.1002/ps.1258.
    10:192. doi: 10.3389/fpls.2019.00192.
    4: Scarponi L, Del Buono D. Festuca arundinacea, glutathione S-transferase and herbicide safeners: a preliminary case study to reduce herbicidal pollution. J Environ Sci Health B. 2009 Nov;44(8):805-9. doi: 10.1080/03601230903238400. 130(3):1497-505. doi: 10.1104/pp.010066.

    合成参考文献


    摘要:Pesticide Manual., 9(430), 1991
    摘要:National Technical Information Service., OTS0535321
    摘要:Farm Chemicals Handbook., -(C79), 1991
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