CAS: 846-63-9; 2-(Naphthalen-1-yl)-5-Phenyloxazole

该化合物是属于牛的有机化合物,其特点是五人组成的含有氮和氧气的环环环,其特征是环球和苯基组,其芳香特性和潜在用途在各个领域,包括有机电子和光子,通常具有很强的荧光性,在荧光探针和染料等应用中十分有用,多种芳香环的存在增强了其在有机溶剂中的稳定性和溶性.此外,该化合物可能具有有趣的光物理特性,包括吸收和排放光谱,可通过改变其结构加以调控.其合成通常涉及循环反应,并可能研究其在生物系统或作为材料科学组成部分的相互作用.总体而言,2-(1-Nathyl)-5-苯氧基及其独特的结构特征和在先进化学应用中的潜在用途值得注意.

结构式图片

相似化合物

92-71-7 1806-34-4 16155-60-5

物理性质

MSDS等安全信息

上下游产品

CAS号118-31-0 1-萘甲胺 | CAS号122-78-1 2-苯基乙醛 | CAS号13504-46-6 1-苯基醛肟 | CAS号536-74-3 苯乙炔 | CAS号879-18-5 1-萘甲酰氯

合成工艺路线路线简述

  • 42299-49-0 = 846-63-9
    反应条件:1.1 Reagents: Tert-Butyl Hydroperoxide,Cesium Carbonate,Ammonium Oxalate Monohydrate Catalysts: Iodine Solvents: Dimethyl Sulfoxide; 10 H,100 °C
    标题:I2/tbhp-Mediated Tandem Cyclization And Oxidation Reaction: Facile Access To 2,5-Disubstituted Oxazoles
    作者:Guo,Xin; Liu,Xianyan; Li,Chonglong; Jiang,Zhibo; Nan,Zedong; Et Al
    参考文献:Tetrahedron Letters 日期:2022 卷标:112]

    118-31-0 + 122-78-1 = 846-63-9
    反应条件:1.1 Reagents: Potassium Carbonate,Oxygen,Copper Bromide (Cubr2) Catalysts: Pyridine Solvents: Toluene; 10 Min,1 Atm,Rt; 16 H,80 °C
    标题:Synthesis Of Oxazoles Through Copper-Mediated Aerobic Oxidative Dehydrogenative Annulation And Oxygenation Of Aldehydes And Amines
    作者:Xu,Zejun; Zhang,Chun; Jiao,Ning
    参考文献:Angewandte Chemie 日期:2012 卷标:51(45) 页码:11367-11370]

    13504-46-6 = 846-63-9
    反应条件:1.1 Catalysts: Trifluoromethanesulfonic Acid,Silica Solvents: Toluene; 0.5 H,50 °C1.2 50 °C; 3.5 H,70 °C1.3 Reagents: 2,3-Dichloro-5,6-Dicyano-1,4-Benzoquinone,Cupric Chloride,Lithium Chloride,Oxygen Solvents: 1-Propanol,1,4-Dioxane; 4 H,1.3 Mpa,60 °C
    标题:Convenient One-Pot Synthesis Of 2,5-Disubstituted Oxazoles Via A Catalytic Oxidative Dehydrogenation Of F3Cso3H.Sio2-Ddq/cucl2/licl
    作者:Yuan,Shizhen; Li,Zhen; Xu,Ling
    参考文献:Journal Of Heterocyclic Chemistry 日期:2013 卷标:50(6) 页码:1405-1409]

    1006-68-4 + 37181-39-8 = 846-63-9
    反应条件:1.1 Reagents: Sodium Tert-Butoxide Catalysts: Di-μ-Chlorobis(η3-2-Propenyl)Dipalladium,1H-Imidazolium,1,3-Bis[2,6-Bis(1-Methylethyl)Phenyl]-,Chloride (1:1) Solvents: Dimethylformamide; 12 H,120 °C
    标题:Palladium-Catalyzed C-H Arylation Of (Benzo)Oxazoles Or (Benzo)Thiazoles With Aryltrimethylammonium Triflates
    作者:Zhu,Feng; Tao,Jian-Long; Wang,Zhong-Xia
    参考文献:Organic Letters 日期:2015 卷标:17(19) 页码:4926-4929]

    66-77-3 + 884866-01-7 = 846-63-9
    反应条件:1.1 Catalysts: Dirhodium Tetraacetate Solvents: Chloroform; 12 H,120 °C
    标题:Synthesis Of 2,5-Diaryloxazoles Through Rhodium-Catalyzed Annulation Of Triazoles And Aldehydes
    作者:Li,Jian; Zhu,Shang-Rong; Xu,Yue; Lu,Xue-Chen; Wang,Zheng-Bing; Et Al
    参考文献:Rsc Advances 日期:2020 卷标:10(42) 页码:24795-24799]

    90-14-2 + 1006-68-4 = 846-63-9
    反应条件:1.1 Reagents: Silver Carbonate,Triphenylphosphine Catalysts: [1,1′-Bis(Diphenylphosphino)Ferrocene]Dichloropalladium Solvents: Dichloromethane
    标题:Palladium Cross-Couplings Of Oxazoles
    作者:Flegeau,Emmanuel Ferrer
    参考文献:2008]

    90-14-2 + 1006-68-4 = 846-63-9
    反应条件:1.1 Reagents: Silver Carbonate Catalysts: Triphenylphosphine,Dichloro[1,1′-Bis(Diphenylphosphino)Ferrocene]Palladium(Ii) Dichloromethane Addu... Solvents: Water; 16 H,70 °C
    标题:Direct Arylation Of Oxazoles At C2. A Concise Approach To Consecutively Linked Oxazoles
    作者:Flegeau,Emmanuel Ferrer; Popkin,Matthew E.; Greaney,Michael F.
    参考文献:Organic Letters 日期:2008 卷标:10(13) 页码:2717-2720]

    99747-74-7 + 1006-68-4 = 846-63-9
    反应条件:1.1 Reagents: Butyllithium Solvents: Tetrahydrofuran,Hexane1.2 Reagents: Zinc Chloride Solvents: Diethyl Ether1.3 Solvents: Tetrahydrofuran1.4 Reagents: Butyllithium Catalysts: Dichlorobis(Triphenylphosphine)Palladium
    标题:Palladium-Catalyzed Cross Coupling Reactions Of Oxazol-2-Ylzinc Chloride Derivatives
    作者:Anderson,Benjamin A.; Harn,Nancy K.
    参考文献:Synthesis 日期:1996 卷标:(5) 页码:583-585]

    1006-68-4 + 90-11-9 = 846-63-9
    反应条件:1.1 Reagents: Lithium Tert-Butoxide Catalysts: Tetrakis(Triphenylphosphine)Palladium Solvents: 1,4-Dioxane; 2 - 5 H,120 °C
    标题:C-H Bond Activation: A Versatile Protocol For The Direct Arylation And Alkenylation Of Oxazoles
    作者:Besselievre,Francois; Lebrequier,Sabrina; Mahuteau-Betzer,Florence; Piguel,Sandrine
    参考文献:Synthesis 日期:2009 卷标:(20) 页码:3511-3518
📜N,N-二甲基-1-萘胺置于bis(η3-Allyl-μ-Chloropalladium(II)),Sodium T-Butanolate,三环己基膦体系中,用 二氯甲烷,N,N-二甲基甲酰胺 作为反应溶剂,化学反应 17.0H,反应生成 2-(1-萘基)-5-苯基噁唑
参考文献:Palladium-Catalyzed C-h Arylation Of (Benzo)Oxazoles Or (Benzo)Thiazoles With Aryltrimethylammonium Triflates
标题:Palladium-Catalyzed C-h Arylation Of (Benzo)Oxazoles Or (Benzo)Thiazoles With Aryltrimethylammonium Triflates
摘要:The C-H Arylation Of (Benzo)Oxazoles Or (Benzo)Thiazoles With Aryltrimethylammonium Triflates Was Carried Out Via Pd-Catalyzed C-H/c-N Cleavage. Oxazoles,Thiazoles,Benzoxazole,And Benzothiazole Were Arylated Using Activated And Deactivated Aryltrimethylamrnonium Triflates To Give 2-Aryl(Benzo)Oxazoles Or 2-Aryl(Benzo)Thiazoles In Reasonable To Excellent Yields.
DOI:10.1021/acs.Orglett.5B02458

海关参考信息

专利信息


专利号:US-9827555-B2
优先权日:2013-07-31
标 题:Catalyst for conversion of synthesis gas
发明人：KARIM KHALID; RAKIB MOHAMMAD ABDUR; KHAN ASAD AHMAD; AL-SEMAHI MOHAMMED
权利人:SAUDI BASIC IND CORP
摘要:The disclosed subject matter presents a catalyst or catalyst composition as well as the methods of making and using the catalyst or catalyst composition. In one aspect, the disclosed subject matter relates to a catalyst comprising CoMn a Si b X c Y d O x wherein in X comprises an element from Group 11; Y comprises an element from Group 12; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; c ranges from 0.01 to 0.05; d ranges from 0.01 to 0.05; x is a number determined by the valency requirements of the other elements present; and wherein the catalyst converts synthesis gas to at least one olefin.

专利号:US-10024983-B1
优先权日:2015-12-01
标 题 :Metal-loaded plastic scintillators for gamma-ray spectroscopy
发明人：FENG PATRICK L; CORDARO JOSEPH GABRIEL; MENGESHA WONDWOSEN; MYLLENBECK NICOLAS RICHARD
权利人:NAT TECH & ENG SOLUTIONS SANDIA LLC
摘要:Exemplary embodiments of several new metal-loaded plastic scintillators are reported herein, comprising sterically and electronically isolated organotin additive complexes. Distance-dependent quenching relationships have been used as design criteria for the selection and synthesis of these organometallic additives, resulting in increased light yields and improved gamma-ray energy resolution values relative to previously reported PS/PVT examples. Fast scintillation decay properties have also been characterized in the prepared scintillators, rivaling the kinetics of stilbene-doped bibenzyl and BC-422Q-1% while providing higher light yields than these reference materials.

专利号:US-9486785-B2
优先权日:2013-07-31
标题 :Catalyst and process for the production of olefins from syngas
发明人：KARIM KHALID; KHAN ASAD AHMAD; RAKIB MOHAMMAD ABDUR; AL-SEMAHI MOHAMMED; BAROCHIA JAYEN
权利人:SAUDI BASIC IND CORP
摘要:The present disclosures and inventions relate to a catalyst or catalyst composition and the methods of making and using the catalyst or catalyst composition. In one aspect, the present disclosure relates to a catalyst composition that includes a catalyst having the formula C A C B O x and a catalyst support; a) C A is Co a Mn b X d , wherein X comprises Si, Ti, Cu, Zns Pd, or La or a combination thereof; a ranges from 0.8 to 1.2; b ranges from 0.1 to 1; and d ranges from 0 to 0.5; and b) C B is Ni e Cu f Mg h Si m , wherein e ranges from about 0.8 to 1.2; f ranges from 0 to 1; h ranges from 0 to 0.5; and m ranges from 0 to 0.5; wherein O x is determined by the valence requirements of the other elements present, wherein in the catalyst support consists essentially of magnesia, alumina, silica, titanic, carbon, or zeolite, or a combination thereof; and wherein the catalyst composition converts synthesis gas to at least one olefin.

专利号:US-2016167025-A1
优先权日:2013-07-31
标 题:Catalyst for conversion of synthesis gas

专利号:EP-3027314-A2
优先权日:2013-07-31
标 题 :Catalyst for conversion of synthesis gas

专利号:WO-2015015316-A2
优先权日:2013-07-31
标 题 :Catalyst for conversion of synthesis gas

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主要参考文献

参考标题:Convenient One-Pot Synthesis Of 2,5-Disubstituted Oxazoles Via A Catalytic Oxidative Dehydrogenation Of F3Cso3H.Sio2-Ddq/cucl2/licl
作者:Shizhen Yuan,Zhen Li,Ling Xu |发布日期:2013.11
摘要:A Facile One‐pot Synthesis Of 2,5‐disubstituted Oxazoles Was Developed Via Cyclization Of Aldoximes And Phenylacetylene Then Dehydrogenation Oxidation. 2,3‐dichloro‐5,6‐dicyano‐1,4‐benzoquinone Was Studied For The Selective Oxidation Of Oxazolines Using Cu2+/li+ As Catalyst And O2 As Indirect Oxidant. The Reaction Results Showed That This Catalyst System Can Effectively Catalyze The Oxidation Of Oxazolines

合成参考文献


参考文献:10.1021/ac103311p
摘要:Seliman AF, Samadi A, Husson SM, Borai EH, DeVol TA. Preparation of polymer-coated, scintillating ion-exchange resins for monitoring of 99Tc in groundwater. Anal Chem. 2011 Jun 15;83(12):4759–66. doi: 10.1021/ac103311p.
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