CAS: 66521-54-8; 3-(Dimethylamino)-1-(Pyridin-2-yl)Prop-2-En-1-One

相似化合物

123367-25-9 63285-43-8 112677-15-3

上下游产品

2-acetylpyridine N,N-dimethyl-formamide dimethyl acetalN,N-dimethyl-formamide dimethyl acetal N,N-dimethylformamide diethyl diacetal N,N-dimethyl-formamide 2-(1H-pyrazol-3-yl)pyridine pyridin(+)-2-1-(1-Phenylethyl)-5-pyrazolylpyridin 4-(pyridin-2-yl)pyrimidine 2,2':6,2''-terpyridine

📜2-乙酰基吡啶,N,N-二甲基甲酰胺二甲基缩醛 以 甲苯 作为反应溶剂,化学反应 12.0H,以98%的收率获得产物3-(二甲氨基)-1-(2-吡啶基)-2-丙烯-1-酮
参考文献:铱(iii)光催化还原剂的合成,表征及应用
标题:铱(iii)光催化还原剂的合成,表征及应用
摘要:通式为[ir Iii(c ^ N)2(n ^ N)] +(c ^ N:环金属化苯基吡啶配体,N ^ N:中性的新型单阳离子铱(iii)光敏剂(ir-Pss)的合成描述了二齿配体.通过循环伏安法,Uv / Vis和光致发光光谱法和x射线分析检查获得的结构.测试了所有铱配合物作为光敏剂的能力,以促进从水中均匀催化的氢气反应生成.在[hnet 3] [hfe 3(co)11]作为减水催化剂(wrc)和三乙胺作为牺牲性还原剂(sr)的存在下,七个新的铱络合物表现出活性.[ir(6‐ Ipr-Bpy)(ppy)2] Pf 6(bpy:2,2'-联吡啶,Ppy:2-苯基吡啶)被证明是最有效的光敏剂.还对该复合物与其他基于铑,铂,钴和锰的wrc进行了测试.在所有情况下,都会发生大量的氢气逸出.从[hnet 3] [hfe 3(co)11]和三[3,5-双(三氟甲基)苯基]膦现场反应生成的ir-Ps的最大周转数为4550,Fe
DOI:10.1002/chem.201100235

专利信息

专利号:US-5064963-A
优先权日:1990-04-25
标 题 :Process for the synthesis of n-(3-(1h-imidazol-1-yl)phenyl-4-(substituted)-2-pyrimidinamines
发明人：DEAN WILLIAM D
权利人:AMERICAN CYANAMID CO
摘要:The invention provides a novel process for producing N-[3-(1H-imidazol-1-yl)phenyl]-4-(substituted)-2 pyrimidinamine compounds in which the substituent is a 2-pyridinyl, 3-pyrindinyl, 4-pyridinyl, 2-furanyl or 2-thienyl group. The process includes the steps of (1) reacting a 3-(1H-imidazol-1-yl)benzamine with cyanamide and a halogen acid while controlling the pH of the reaction between pH about 2 to abourt 3.5 and recovering a [3-(1H-imidazol-1-yl)phenyl] guanidine dihydrohalide and (2) reacting the [3-(1H-imidazol-1-yl)phenyl] guanidine dihydrohalide so recovered with an appropriately substituted 3-dimethylamino-1-(substituted)-2-propen-1-one and a base at a pH of from about 10.5 to about 11.5 and recovering the N-[3-(1H-imidazol-1-yl)phenyl-4-(substituted)-2-pyrimidamine compound so produced. The novel process provides improved yield and purity by adhering to the stated crucial pH ranges.

专利号:EP-0453731-A2
优先权日:1990-04-25
标题 :Improved process for the synthesis of N-3-(1H-imidazol-1-yl)phenyl-4-(substituted)-2-pyrimidinamines

专利号:HU-211774-B
优先权日:1990-04-25
标 题:Improved process for the synthesis of n-[3-(1h-imidazol-1-yl)phenyl]-4-substituted-2-pyrimidinamines

专利号:EP-0453731-B1
优先权日:1990-04-25
标 题:Improved process for the synthesis of N-3-(1H-imidazol-1-yl)phenyl-4-(substituted)-2-pyrimidinamines

专利号:EP-0453731-A3
优先权日:1990-04-25
标 题 :Improved process for the synthesis of n-3-(1h-imidazol-1-yl)phenyl-4-(substituted)-2-pyrimidinamines

专利号:JP-H04225975-A
优先权日:1990-04-25
标题:Improved method for synthesis of N-[3-(1H-imidazol-1-yl)phenyl]-4-(substituted)-2-pyrimidinamine