CAS: 56883-33-1; 1,3,4,6-Tetra-O-Acetyl-2-Azido-2-Deoxy-Alpha-D-Glucopyranose
该化合物是一种化学化合物,属于亚兹多糖类,是经过修改的碳水化合物,具有一种亚兹德功能组,其特征为:四乙酰基化合物与脱氧甘蓝盐的氢氧基化合物组相连,增强了其在有机溶剂中的稳定性和溶解性.亚兹德类(-N3)因其再活动性而引人注目,特别是在点击化学应用中,允许形成各种生物合成.四乙酰二氧基丙烯菊酯通常用于生物化学研究,特别是在气相反应和合成甘油蛋白或甘油的合成中.其结构特征有助于研究碳水化合物的相互作用和形成对基因化学学的开发.由于亚兹德组的存在,该化合物一般会受到标准实验室安全防范措施的处理,因为在某种条件下,该类可能具有危险性.
- 英文名称1,3,4,6-Tetra-O-Acetyl-2-Azido-2-Deoxy-Alpha-D-Glucopyranose
- 中文名称1,3,4,6-O-四乙酰基-2-叠氮-2-脱氧-α-D-吡喃葡萄糖
- IUPAC名称(2R,3R,4R,5S,6R)-6-(acetoxymethyl)-3-azidotetrahydro-2H-pyran-2,4,5-triyl triacetate
- 其它别名1,3,4,6-Tetra-O-Acetyl-2-Azido-2-Deoxy-Alpha-D-Glucopyranose; [(2R,3S,4R,5R,6R)-3,4,6-Triacetyloxy-5-Azidooxan-2-Yl]Methyl Acetate; 1,3,4,6-Tetra-O-Acetyl-2-Azido-2-Deoxy-A-D-Glucopyranose; Qkghbqjlehamk
- CAS编号56883-33-1
- MFCD编号:MFCD01076183
- 分子式:C14H19N3O9分子量:373.32
- 产品CID: 1543124
- 产品分类生物化工 → 糖类化合物 → 单糖
物理性质
MSDS等安全信息
上下游产品
CAS号127-09-3 乙酸钠 | CAS号668481-16-1 (2R,3S,4R)-2-(a... | CAS号1078691-95-8 2-Amino-2-deoxy... | CAS号2873-29-2 三乙酰葡萄糖烯合成工艺路线路线简述
海关参考信息
- 2905122000-异丙醇
2905310000-1,2-乙二醇
2905320000-1,2-丙二醇
2905399001-1,3-丙二醇 - 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-4362720-A
优先权日:1977-04-14
标题:Synthesis of 2-amino-2-deoxyglycoses and 2-amino-2-deoxyglycosides from glycals
发明人：LEMIEUX RAYMOND U; RATCLIFFE R MURRAY
权利人:CHEMBIOMED LTD
摘要:O-acetylated glycals react with ceric ammonium nitrate in the presence of sodium azide to provide, in good yield, O-acetylated 2-azido-2-deoxy glycosyl nitrates. These nitrates can be used to prepare 2-amino-2-deoxy sugars, such as D-galactosamine and lactosamine. The O-acetylated 2-azido-2-deoxy glycosyl nitrates can alternately be converted to O-acetylated 2-azido-2-deoxy glycosyl halides which are useful in the preparation of O-acetylated 2-azido-2-deoxy glycosides, which in turn can be reduced to 2-amino-2-deoxy glycosides. Of particular interest are the syntheses of 2-amino-2-deoxy glycosides which correspond to the terminal units of the antigenic determinant for the human A blood group. Attachment of these glycosides to a solid support provides immunoabsorbents which efficiently and preferentially absorb anti-A antibodies from blood plasma.
专利号:US-4308376-A
优先权日:1977-04-14
标 题 :Synthesis of 2-amino-2-deoxyglycoses and 2-amino-2-deoxyglycosides from glycals
发明人：LEMIEUX RAYMOND U; RATCLIFFE R MURRAY
权利人:CHEMBIOMED LTD
摘要:O-acetylated glycals react with ceric ammonium nitrate in the presence of sodium azide to provide, in good yield, O-acetylated 2-azido-2-deoxy glycosyl nitrates. These nitrates can be used to prepare 2-amino-2-deoxy sugars, such as D-galactosamine and lactosamine. The O-acetylated 2-azido-2-deoxy glycosyl nitrates can alternately be converted to O-acetylated 2-azido-2-deoxy glycosyl halides which are useful in the preparation of O-acetylated 2-azido-2-deoxy glycosides, which in turn can be reduced to 2-amino-2-deoxy glycosides. Of particular interest are the syntheses of 2-amino-2-deoxy glycosides which correspond to the terminal units of the antigenic determinant for the human A blood group. Attachment of these glycosides to a solid support provides immunoabsorbents which efficiently and preferentially absorb anti-A antibodies from blood plasma.
专利号:US-4195174-A
优先权日:1977-04-14
标题 :Synthesis of 2-amino-2-deoxyglycoses and 2-amino-2-deoxyglycosides from glycals
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合成参考文献
参考DOI号:10.1016/S0008-6215(00)87138-4
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