CAS: 2436-73-9; Methyl 2-(4-Chloro-2-Methylphenoxy)Acetate

该化合物是源自杀草剂MCPA(2-甲基-4-氯苯氧乙酸)的有机化合物,其特点是其酯性功能组,有助于有机溶剂中的溶性.MCPA甲基酯一般是无色的,不粉黄黄色液体,有独特的气味.主要用于农业用途,作为一种选择性除草剂,以控制不同作物的宽叶片杂草.该化合物对水生生物具有中度毒性,如果摄入或吸入,则可能有害,需要小心处理和应用.其化学结构允许它与植物生长调节器相互作用,从而有效地干扰目标杂草的生长,同时减少对草的危害.此外,MCPA甲基酯由于可能对非目标物种和生态系统产生影响,因此受环境规章的约束.在使用该物质时,应当注意适当的安全措施,以减少其应用的风险.

结构式图片

欧盟法规

ECHA物质ECHA物质C&L通报REACH预注册

上下游产品

2-methyl-4-chlorophenol methyl chloroacetate methanol MCPA 2-(4-chloro-2-methyl-phenoxy)-thioacetamide 2-(4-chloro-2-methylphenoxy)acetic acid hydrazide n-butyl 4-chloro-2-methylphenoxyacetate

合成工艺路线路线简述

    📜邻甲酚置于iron(III) Chloride,氯化亚砜,叔丁基硫化甲烷,Potassium Carbonate体系中,用 甲苯 用作溶剂,化学反应 1.0H,反应生成2-甲-4-氯苯氧基乙酸甲酯
    参考文献:一种苯氧羧酸酯类除草剂的制备方法
    标题:一种苯氧羧酸酯类除草剂的制备方法
    摘要:本发明提供了一种苯氧羧酸酯类除草剂的制备方法,包括:S1,将酚在碱性物质存在下与氯代羧酸酯缩合反应,得到苯氧羧酸酯;所述氯代羧酸酯通式为clr1Coor,R1为c1~3的亚烷基或次烷基,R为c1~10的烷基或c3~10的环烷基;S2,将所述苯氧羧酸酯在第一催化剂和第二催化剂存在条件下,与氯化剂进行选择性氯化,得到氯代苯氧羧酸酯;所述第一催化剂选自路易斯酸,所述第二催化剂为c5~22的硫醚类,噻唑类,异噻唑类或噻吩类化合物;S3,将所述氯代苯氧羧酸酯与醇进行反应,得到式i所示苯氧羧酸酯类除草剂;R3为h,Cl或ch3,R'为c4~20的烷基或环烷基.本发明能改善产品品质和生产环境,三废低.

    海关参考信息

    专利信息


    专利号:US-9999223-B2
    优先权日:2008-05-21
    标 题 :Herbicidal composition comprising glyphosate, glufosinate or their salts
    发明人:SIEVERNICH BERND; MOBERG WILLIAM KARL; SIMON ANJA; WALTER HELMUT; EVANS RICHARD R
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal composition which comprises:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, and b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone]. nn The present invention relates in particular to a herbicidal composition comprising:n a) at least one herbicide A selected from glyphosate, glufosinate and their salts, b) a herbicide B which is 3-[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-ylmethylsulfonyl]-4,5-dihydro-5,5-dimethyl-1,2-oxazole [common name: pyroxasulfone], and c) at least one further herbicide C, which is selected from the herbicide groups C.1 to C.8:n C.1 herbicides of the group of acetolactate synthase inhibitors (ALS inhibitors), C.2 herbicides of the group of protoporphyrinogen oxidase inhibitors (PPO inhibitors), C.3 herbicides of the group of auxines, C.4 herbicides of the group of 4-hydroxyphenyl-pyruvate-dioxygenase inhibitors (HPPD inhibitors), C.5 herbicides of the group of phytoene desaturase inhibitors (PDS inhibitors), C.6 herbicides of the group of photosystem II inhibitors (PSII inhibitors), C.7 herbicides of the group of microtubulin inhibitors, and C.8 herbicides of the group of inhibitors of the synthesis of very long chain fatty acids (VLCFA inhibitors).

    专利号:US-10506809-B2
    优先权日:2015-01-15
    标 题:Herbicidal combination comprising saflufenacil and glufosinate
    发明人:MASSA DARIO; EVANS RICHARD; WITSCHEL MATTHIAS; SEISER TOBIAS; LIEBL REX; FRATESCHI ALEXANDRE
    权利人:BASF SE
    摘要:The present invention relates to a herbicidal combination which comprises:n a) a herbicide A which is 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl-(1-methylethyl)-amino]sulfonyl]benzamide, b) a herbicide B which is glufosinate or one of its salts, and c) at least one herbicide C different from herbicides A and B which is selected fromn C.1) herbicides of the group of acetolactate synthase inhibitors which are selected from the group of triazolopyrimidine herbicides, sulfonylamino-carbonyl-triazolinone herbicides and pyrimidinyl(thio) benzoate herbicides, C.2) herbicides of the group of protoporphyrinogen oxidase inhibitors, C.3) herbicides of the group of synthetic auxins, C.4) herbicides of the group of microtubule inhibitors, C.5) herbicides of the group of acetyl-CoA carboxylase inhibitors, C.6) herbicides of the group of photosystem II inhibitors, C.7) herbicides of the group of pigment synthesis inhibitors, and C.8) herbicides of the group of VLCFA inhibitors which are selected from the group of oxyacetamide herbicides and chloroacetamide herbicides.

    专利号:ES-2760600-T3
    优先权日:2015-07-10
    标 题:Herbicidal composition comprising cinmethyline and non-ACCase inhibitors of specific lipid synthesis

    供应商参考报价(招募中)

    品牌试剂参考报价(招募中)

    📌 第三方产品分析报告

    ✅ COA系统入驻 | 共享模式

    合成参考文献


    参考文献:10.1007/s10646-018-1929-1
    摘要:Gil FN, Gonçalves AC, Becker JD, Viegas CA. Comparative analysis of transcriptomic responses to sub-lethal levels of six environmentally relevant pesticides in Saccharomyces cerevisiae. Ecotoxicology. 2018 Sep;27(7):871–89. doi: 10.1007/s10646-018-1929-1.
    📝 需求与反馈
    尽可能描述清楚需求与问题信息
    ×

    通知