CAS: 18292-38-1; Trimethyl(2-Methylallyl)Silane

上下游产品

chlorodimethyl(2-methyl-2-propen-1-yl)silane methylmagnesium chloride trichloro(2-methyl-2-propenyl)silane chloro-trimethyl-silane 3-Dimethoxymethyl-6-methyl-4-phenyl-hept-6-en-2-one trimethylsilyl cyanide 4-(2-methyl-2-propenyl)benzonitrile methyl (E)-8-methyl-4,8-nonadienoate

📜3-(三甲基甲硅烷基甲基)丁-3-烯酸 130.0~140.0 °C,101.32 Kpa 条件下,反应 1.0H,以92%的收率获得异丁烯基三甲基硅烷
参考文献:3-三甲基甲硅烷基甲基二烯酸酯的区域和立体选择性烷基化.3-烷基化的2-甲基烯丙基硅烷的新型合成
标题:3-三甲基甲硅烷基甲基二烯酸酯的区域和立体选择性烷基化.3-烷基化的2-甲基烯丙基硅烷的新型合成
摘要:从容易获得的3-三甲基甲硅烷基甲基-3-丁烯酸及其甲酯得到的3-三甲基甲硅烷基甲基二烯酸锂和铜阴离子进行区域选择性和立体选择性烷基化.通过热解,α-烷基化产物易于转化为3-烷基化2-甲基烯丙基硅烷.
Doi:10.1016/s0040-4039(01)90413-7

专利信息

专利号:US-7112700-B1
优先权日:2005-04-14
标 题 :Efficient and economic asymmetric synthesis of nootkatone, tetrahydronootkatone, their precursors and derivatives
发明人：SAUER ANNE M; CROWE WILLIAM E; LAINE ROGER A; HENDERSON GREGG
权利人:UNIV LOUISIANA STATE
摘要:An inexpensive, stereoselective synthesis for nootkatone, tetrahydronootkatone, and their derivatives is disclosed. The starting materials used in the synthesis are inexpensive. The principal starting material, (−)-β-Pinene, is on the GRAS list (generally recognized as safe).

专利号:US-2006235247-A1
优先权日:2005-04-14
标 题:Efficient and economic asymmetric synthesis of nootkatone, tetrahydronootkatone, their precursors and derivatives

专利号:US-11767388-B1
优先权日:2019-09-18
标 题 :Silicon-functionalized rubber
发明人：ENSIGN SETH CODY; VIELHABER MARGARET FLOOK; JOHNGRASS JENA LYNN; MA LIQING
权利人:GOODYEAR TIRE & RUBBER
摘要:The compatibility between silica fillers and synthetic rubbers which are synthesized utilizing lanthanide-based catalyst systems, such as neodymium catalyst systems can be improved by terminating the polymerization with a vinyl silane terminating agent. In doing so the vinyl silane is allowed to react with the polymer chain ends of the neodymium rubber to functionalize the chain ends of the polymer chains with silicon containing groups. This results in the rubber having better characteristics for utilization in tire rubber formulations, such a tire tread formulations, that exhibit improved wear characteristics and lower rolling resistance. The process for the synthesis of such functionalized polydiene rubber comprises (1) polymerizing a diene monomer in the presence of a lanthanide-based catalyst system, and (2) terminating the polymerization with a vinyl silane terminator. The functionalized polydiene rubber composition made by this method is comprised of a polydiene rubber which is functionalized at its chain ends with a silicon containing group.

专利号:EP-1868979-A1
优先权日:2005-04-14
标题 :Efficient and economic asymmetric synthesis of nootkatone, tetrahydronootkatone, their precursors and derivatives

专利号:JP-2008538363-A
优先权日:2005-04-14
标 题 :Efficient and economical asymmetric synthesis of nootkatone, tetrahydronootkatone, its precursors and derivatives

专利号:WO-2006113285-A1
优先权日:2005-04-14
标题 :Efficient and economic asymmetric synthesis of nootkatone, tetrahydronootkatone, their precursors and derivatives