CAS: 1439-36-7; 1-(Triphenylphosphoranylidene)Propan-2-One

相似化合物

129986-67-0 2136-75-6 24720-64-7

上下游产品

[(acetyl)(phenylcarbamoyl)methylene]triphenylphosphorane acetylmethyltriphenylphosphonium iodide (trimethylsilyl)methylenetriphenylphosphorane acetic anhydride (E)-triphenyl(2-ethoxyprop-1-enyl)phosphonium iodide 1-(diphenylphosphinoyl)propan-2-one acetylmethyltriphenylphosphonium iodide acetonyltriphenylphosphonium chloride

📜乙酰三苯基氯化磷置于sodium Carbonate体系中,化学反应 0.33H,以89%的收率获得1-三苯基膦-2-丙酮
参考文献:On The Reaction Of Prop-2-Enylidenetriphenylphosphorane Derivatives. Novel Synthesis Of The Azulene Ring System
标题:On The Reaction Of Prop-2-Enylidenetriphenylphosphorane Derivatives. Novel Synthesis Of The Azulene Ring System
摘要:丙-2-烯基三苯基正膦衍生物与 对几种托酮进行了研究,试图提供一个简短的新方法 通向甘菊环系统的路线. (2-乙氧基丙-2-亚乙烯基)三苯基正膦 4 与 2-氯-,2-甲氧基-和 2,3,5,7-四氯托酮 7A-c 得到甘菊环 衍生物8和9的收率适中.另一方面,反应 [2-乙氧基-3-(乙氧基羰基)丙-2-亚乙烯基]三苯基正膦 6 与 托酮 7A,C 导致形成甘菊酯 10 和 11 产率低,而使用托品酮 7B 则不产生甘菊环和底物 7B被恢复.为了深入了解机制途径,正膦 4 和 6 与氘化托酮 14A,B 的反应 是化合物 7A,B 相应的三氘代衍生物,有 也被研究过.此外,化合物4还与 5-(二甲基氨基亚甲基)环戊-1,3-二烯甲醛 33 得到 6-乙氧基甘菊环37,产率中等.
Doi:10.1039/a605581H

专利信息

专利号:US-11078178-B2
优先权日:2017-09-04
标 题 :6-chromanol derivatives and their synthesis
发明人：BEUMER RAPHAEL; BONRATH WERNER; DELPHO JAN-MARC; JORAY MARCEL; MEDLOCK JONATHAN ALAN; NETSCHER THOMAS; SORIANO DOMENICO; STEMMLER RENÉ TOBIAS
权利人:DSM IP ASSETS BV
摘要:The present invention relates to novel compounds which are particularly useful for the synthesis of novel chromanol derivatives. These compounds have interesting properties. Particularly, the novel chromanol derivatives have interesting antioxidant properties as well as flavours and fragrances.

专利号:US-9938228-B2
优先权日:2014-09-09
标题:Process for the preparation of spiro[2.5]octane-5,7-dione and spiro[3.5]nonane-6,8-dione
发明人：JIN XIANGLE; DONG WEITONG; FU YAN; LU JUN; XIE LE; XU WEI; YANG JINSONG; ZHU QIAN
权利人:BOEHRINGER INGELHEIM INT
摘要:This invention relates to methods for the synthesis of spiro[2.5]octane-5,7-dione and spiro[3.5]nonane-6,8-dione which are useful as intermediates in the manufacture of pharmaceutically active ingredients.

专利号:US-4536334-A
优先权日:1979-06-28
标题 :Preparation of β-lactam derivatives
发明人：SUNAGAWA MAKOTO; MATSUMURA HARUKI; INOUE TAKAAKI; HIROHASHI TOSHIYUKI
权利人:SUMITOMO CHEMICAL CO
摘要:A process for preparing a β-lactam derivative having a hydrogen atom on the nitrogen atom of the β-lactam ring, which comprises reacting a β-lactam derivative having a mono- or diarylmethyl group on the nitrogen atom of the β-lactam ring with an acid or ceric ammonium nitrate to cleave the bond between the nitrogen atom and the mono- or diarylmethyl group; and novel β-lactam derivatives useful as intermediates for the synthesis of pharmaceutical agents.

专利号:US-3424799-A
优先权日:1966-04-01
标 题:General synthesis of diketophosphoranes and acetylenic ketones
发明人：CHOPARD PIERRE-ANTOINE; SEARLE ROBERT J G
权利人:AMERICAN CYANAMID CO

专利号:EP-0872466-A1
优先权日:1997-04-18
标题 :Process for the synthesis of 1,7-diaryl or 1,7-heteroarylheptan-4-ols and synthetic intermediates

专利号:DE-2711008-A1
优先权日:1977-03-14
标题 :2-OXO-ALKANYLIDEN-TRIARYLPHOSPHORANES, PROCESS FOR THEIR PRODUCTION AND THEIR USE FOR THE SYNTHESIS OF NEW PROSTAGLANDIN ANALOGS