CAS: 770-09-2; Benzyltrimethylsilane
该化合物是一种有机硅化合物,配有分子式C10H16Si. 它通常用作有机合成的多用途试剂,尤其是通过丝状反应来保护氢氧基组. 该化合物在中性和基本条件下的稳定性,加上在温酸条件下的易脱酸性,使它成为多步骤合成途径中的宝贵工具. 它的疏水性也增加了非极溶剂的溶性,促进了极化介质的反应. 此外,苯基甲基硅烷是其他功能化硅的前体,有助于其在材料科学和药物应用中的效用.
- 相似结构搜索
- 产品信息参考
; - InChIKey: MRIWRLGWLMRJIW-UHFFFAOYSA-N
- InChI=1S/C10H16Si/c1-11(2,3)9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3
- 计算化学: 氢键受体数*氢键供体数*可旋转键数2.0
物理性质
MSDS等安全信息
- GHS象形图
- GHS符号GHS02;
注释: Flame - 危险类别急性毒性 类别4(吸入)
急性毒性 类别4(经皮)
急性毒性 类别4(经口)
易燃液体 类别3 - 警示词Warning(警告)
- 危险描述H332 |吸入有害.
H312 |皮肤接触有害.
H302 |吞咽有害.
H226 |易燃液体和蒸气. - 防范说明P210-P233-P240-P241-P242-P243-P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362-P370+P378-P501
- 危险等级3
- UN编号1993.0
- 危险品标志Xi
- 包装等级Ⅲ
- 安全声明23-24/25
- 危险类别码36/37/38
- WGK Germany3
欧盟法规
ECHA物质C&L通报REACH预注册上下游产品
methyl magnesium iodide benzyltrichlorosilane diethyl ether methylmagnesium bromide(α,α-dibromotolyl)-α-trimethylsilane phenyl(trimethylsilyl)methyl bromide trimethyl(2-nitrobenzyl)silane trimethyl(4-nitrobenzyl)silane合成工艺路线路线简述
📜苄甲醚置于sodium体系中,用 甲苯 作为反应溶剂,化学反应 24.0H,以82%的收率获得产物苄基三甲基硅烷
参考文献:Reaction Of Allylic And Benzylic Methyl Ethers With Sodium And Trimethylchlorosilane. Evidence For The Intermediacy Of Allylic Radicals And Anions
标题:Reaction Of Allylic And Benzylic Methyl Ethers With Sodium And Trimethylchlorosilane. Evidence For The Intermediacy Of Allylic Radicals And Anions
摘要:
DOI:10.1021/jo00315A007
海关参考信息
- 2902300000-甲苯
- 💡 提示：海关信息按照顺序优先匹配，如需确认的海关信息，请参考相关资料。
- 详情请参考：📖 海关编码查询和海关进出口税则
专利信息
专利号:US-7456298-B2
优先权日:2002-06-03
标题:Synthesis of acetonides from aryl silanes
发明人：MCAULIFFE JOSEPH C; WHITED GREGORY M; SMITH WYATT CHARLES
权利人:GENENCOR INT
摘要:The present invention is related to cis-diols and biological methods of producing cis-diols. The present invention further relates to processes for subsequently converting such silane cis-diols to the more stable acetonide derivatives, as well as a process for converting silane cis-diols to the corresponding catechols and the compounds produced thereby. The present invention also provides chemical methods for the conversion of said silane cis-diols and acetonide compounds to epoxy, saturated and otherwise modified derivatives. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that is will not be used to interpret or limit the scope or meaning of the claims.
专利号:US-2004033574-A1
优先权日:2002-06-03
标题 :Synthesis of cis-diols from aryl silanes
专利号:US-2007213550-A1
优先权日:2002-06-03
标题 :Synthesis of cis-diols from aryl silanes
专利号:US-2007213541-A1
优先权日:2002-06-03
标 题 :Synthesis of acetonides from aryl silanes
专利号:US-7381830-B2
优先权日:2002-06-03
标 题 :Synthesis of cis-diols from aryl silanes
专利号:EP-1534783-A2
优先权日:2002-06-03
标 题:Synthesis of cis-diols from aryl silanes
供应商参考报价(招募中)
品牌试剂参考报价(招募中)
📌 第三方产品分析报告
合成参考文献
摘要:Ager, D. J., Science of Synthesis, (2010) 47, 87.
摘要:Snaith, J. S., Science of Synthesis Knowledge Updates, (2011) 2, 174.
摘要:Rey, Y. P.; Hepburn, H. B.; Melchiorre, P., Science of Synthesis: Photocatalysis in Organic Synthesis, (2018) 1, 265.
摘要:Zhou, M.; Qin, T., Science of Synthesis, (2020) , 517.
摘要:Miyagishi, H. V.; Nagaki, A., Science of Synthesis: Knowledge Updates, (2024) 1, 208.
📝 需求与反馈
尽可能描述清楚需求与问题信息
