CAS: 61439-59-6; 2-(4-(Benzyloxy)Phenyl)Ethanol

上下游产品

2-[4-(benzyloxy)benzyl]acetic acid (4-benzyloxy-phenyl)-acetic acid methyl ester acetic acid ethyl ester2-4-(phenylmethoxy)phenylacetic acid ethyl ester p-hydroxyphenethyl alcohol 1-benzyloxy-4-(2-methanesulfonyloxyethyl)benzene β-(4-Benzyloxy)phenylethyl nonanoate 1-benzyloxy-4-(2-cyclopropylmethoxyethyl)benzene -1-(phenylmethoxy)benzene4-(cyclobutylmethoxy)ethyl-1-(phenylmethoxy)benzene

对羟基苯乙酸置于lithium Aluminium Tetrahydride,Potassium Carbonate体系中,用 四氢呋喃,丙酮 作为反应溶剂,化学反应 14.0H,反应生成 2-(4-苯甲氧基苯基)乙醇
参考文献:用于立体选择性分子内c-n键形成的ddq促进的benzylic / Allylic Sp 3 C-h活化:在(-)-Codonopsinine,(+)-5-Epi-Codonopsinine,(+)-Radicamine B的总合成中的应用,和(-)-Codonopsinol
标题:用于立体选择性分子内c-n键形成的ddq促进的benzylic / Allylic Sp 3 C-h活化:在(-)-Codonopsinine,(+)-5-Epi-Codonopsinine,(+)-Radicamine B的总合成中的应用,和(-)-Codonopsinol
摘要:这是关于在中性条件下使用ddq的酰胺束缚的苄基/烯丙基系统的分子内c-n键形成的首次报道,该技术已成功应用于天然存在的吡咯烷生物碱的全合成.合成相应前体的关键步骤涉及julia-Kociensky烯烃化/交叉复分解和二羟基化反应,并且该方法学还扩展到ω-不饱和n-磺酰胺提供哌啶.
DOI:10.1021/acs.Joc.5B02275

专利信息

专利号:US-3876682-A
优先权日:1973-06-04
标题 :Substituted benzoates of cyclpropane carboxylic acids
发明人：HENRICK CLIVE A; STALL GERARDUS B
权利人:HENRICK CLIVE A; STALL GERARDUS B
摘要:Organic esters characterized by the presence of a cyclopropane moiety, synthesis thereof, and compositions thereof for the control of mites and ticks.

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