专利号:US-7429672-B2 优先权日:2006-06-09 标题 :Process for the direct synthesis of trialkoxysilane 发明人:LEWIS KENRICK M; CAMERON RUDOLPH A; RITSCHER LEGAL REPRESENTATIVE KAREN 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:This invention discloses a process to improve reaction stability in the Direct Synthesis of trialkoxysilanes. The process is particularly effective in the Direct Synthesis of triethoxysilane and its higher alkyl cognates providing improved triethoxysilane yields.
专利号:US-12331007-B2 优先权日:2021-10-15 标题 :Use of a multidentate phosphite ligand in the catalytic synthesis of adiponitrile 发明人:CHEN ZHIRONG; WU WENBIN; YIN HONG; ZHA ZENGSHI; WANG KEYAN; MA LI; HUANG GUODONG; ZHOU GUIYANG; XU YONG 权利人:ZHEJIANG NHU CO LTD; ZHEJIANG NHU SPECIAL MAT CO LTD; ZHEJIANG NHU NYLON MAT CO LTD 摘要:A multidentate phosphite ligand is used in the catalytic synthesis of adiponitrile. The ligand is represented by the following general formula (I). The method of catalytic synthesis of adiponitrile comprises primary hydrocyanation, isomerization, and secondary hydrocyanation reactions, wherein the catalyst adopted each comprises a phosphite ligand-nickel complex composed of a nickel precursor and a multidentate phosphite ligand. The ligand molecule has a higher electron cloud density, and the phosphorus content capable of participating in coordination in the ligand molecule per unit mass is higher, so that the catalytic activity of the catalyst is improved, and the amount of the catalyst is reduced.
专利号:US-4756739-A 优先权日:1985-12-21 标题 :Pyridine derivatives and the N-oxides thereof, and the use thereof as intermediates for the synthesis of plant protecting agents 发明人:FUSS ANDREAS; KOCH VOLKER 权利人:HOECHST AG 摘要:The compounds of the formula I (I) in which A denotes N or N->O, Z denotes O or NH, R denotes H, (halo)alkyl, (halo)alkenyl, (halo)alkynyl or alkoxycarbonyl, R1 denotes hydrogen, halogen, amino, -NHOH, hydroxyl, (substituted) phenylazo or a radical of the formulae Y=C=N-, Y1Y2C=N-, Y3NH- or K denotes 0 or 1, and m and n, independently of one another, denote a number from 1 to 4, with the proviso that, when Z-R denotes OH or NH2, (R1)n denotes at least one radical of the formula or represents two radicals, in the 5 or 6 position of the heterocyclic ring, which, in the 5 position, denote halogen and, in the 6 position, denote a radical of the group comprising halogen, amino, hydroxyl or phenylazo, which may be substituted as specified above, are valuable intermediates in the synthesis of plant protection agents.
专利号:US-4918222-A 优先权日:1984-07-27 标 题 :Process for synthesis of N-acetylglycine 发明人:LIN JIANG-JEN; KNIFTON JOHN F; YEAKEY ERNEST L 权利人:TEXACO INC 摘要:An N-acetylglycine is manufactured by reacting paraformaldehyde with an acetamide and carbon monoxide in the present of a cobalt-containing catalyst promoted by a sulfoxide or dinitride compounds. The presence of sulfoxide or dinitrile ligands are essential for the high yield synthesis of N-acetylglycine and good cobalt recovery.
专利号:US-9249165-B2 优先权日:2013-08-30 标题 :Slurry phase direct synthesis of organohalosilanes from cyclone fines 发明人:LEWIS KENRICK MARTIN; ZHU YANJUN; MEREIGH ABELLARD T; RAZZANO JOHN; NEELY JOHN DAVID 权利人:MOMENTIVE PERFORMANCE MAT INC 摘要:The present invention is directed to a process for the synthesis of organohalosilane monomers, comprising the steps of (1) forming a slurry of cyclone fines, ultra fines and/or spent contact mass in a thermally stable solvent and reacting the agitated slurry with an organohalide of the formula R 1 X in the presence of an additive for a time and at a temperature sufficient to produce organohalosilane monomers having the formulae R 1 SiHX 2 , R 1 2 SiHX, R 1 3 SiX, R 1 SiX 3 , and R 1 2 SiX 2 ; wherein R 1 is a saturated or unsaturated aromatic group, a saturated or unsaturated aliphatic group, alkaryl group, or cycloaliphatic hydrocarbyl group, and X is a halogen; and (2) recovering said organohalosilane monomers.
专利号:EP-0723477-B1 优先权日:1993-10-12 标 题:Improved synthesis of nickel phosphine and phosphite catalysts 发明人:BRYNDZA HENRY E 权利人:DU PONT 摘要:An improved process for the synthesis of zerovalent nickel catalyst useful for the hydrocyanation of olefins, wherein catalyst formation is improved by applying sonication during formation of catalyst. The sonication may be applied to the catalyst reactant mixture containing elemental nickel and a ligand; or alternatively, the sonication may be applied to the elemental nickel prior to the addition of ligand to the reaction mixture.
1: Yang YF, Hu WB, Shi L, Li SG, Zhao XL, Liu YA, Li JS, Jiang B, Ke W. Guest-regulated chirality switching of planar chiral pseudo[1]catenanes. Org Biomol Chem. 2018 Mar 28;16(12):2028-2032. doi: 10.1039/c8ob00156a. Epub 2018 Feb 20. pii: E92. doi: 10.3390/molecules23010092. doi: 10.1107/S2053229617014620. Epub 2017 Oct 17. doi: 10.1007/s10529-017-2410-6. Epub 2017 Jul 31. doi: 10.1002/marc.201700161. Epub 2017 May 19. doi: 10.1002/cphc.201700058. Epub 2017 Apr 7. doi: 10.1016/j.nutres.2015.12.003. Epub 2015 Dec 7. doi: 10.1002/chem.201504709. Epub 2016 Feb 19. doi: 10.1002/chem.201502547. Epub 2015 Sep 23. doi: 10.1002/anie.201500109. Epub 2015 Apr 1. doi: 10.1038/ncomms5123. doi: 10.1021/jo400433m. Epub 2013 May 28. doi: 10.1158/1055-9965.EPI-12-1444. Epub 2013 May 7. 15: Dai JJ, Huang YB, Fang C, Guo QX, Fu Y. Electrochemical synthesis of adiponitrile from the renewable raw material glutamic acid. ChemSusChem. 2012 Apr;5(4):617-20. doi: 10.1002/cssc.201100776. Epub 2012 Mar 22. doi: 10.1021/ic202225g. Epub 2012 Jan 13. Epub 2011 Aug 1. doi: 10.1039/c0cc01452d. Epub 2010 Oct 25. doi: 10.1016/j.jbiotec.2009.06.004. Epub 2009 Jun 17. doi: 10.1021/ic801238a.
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