CAS: 97042-18-7; 4-((4-(Allyloxy)Phenyl)Sulfonyl)Phenol

• 英文名称4-((4-(Allyloxy)Phenyl)Sulfonyl)Phenol
• 中文名称4-羟基-4'-烯丙氧基二苯砜
• IUPAC名称4-((4-(allyloxy)phenyl)sulfonyl)phenol
• 其它别名4-((4-(烯丙氧基)苯基)磺酰基)苯酚; Bis-Mae; Bps-Mae; Phenol, 4-[[4-(2-Propen-1-Yloxy)Phenyl]Sulfonyl]-
• CAS编号97042-18-7
• MFCD编号:MFCD00551852
• EINECS号:479-880-7
• 分子式:C15H14O4S
• 分子量:290.34
• 产品CID: 2019806
• 产品分类有机原料→分子砌块→芳环类化合物→苯类化合物

• 相似结构搜索
• InChIKey: FKZIDBGIZLBDDF-UHFFFAOYSA-N
• InChI=1S/C15H14O4S/c1-2-11-19-13-5-9-15(10-6-13)20(17,18)14-7-3-12(16)4-8-14/h2-10,16H,1,11H2…
• 计算化学: 氢键受体数4.0氢键供体数1可旋转键数5

物理性质

• 熔点168-170 °C
• 沸点495.8±35.0 °C at 760 mmHg
• 闪点253.7±25.9 °C
• 密度1.271±0.06 g/cm3(预测)
• pKa:7.23±0.15(预测)
• PSA:63.6
• LogP:2.7898
• 蒸汽压0Pa at 25°C
• 溶解性Chloroform (Slightly, Heated), DMSO (Slightly), Methanol (Slightly)
• 外观形态白色至类白色固体
• 储存条件2-8°C

MSDS等安全信息

• GHS象形图
• GHS符号GHS09;
  注释: Environment
• 危险类别水生慢性毒性 类别1
• 警示词Warning(警告)
• 危险描述H410 |对水生生物毒性极大并具有长期持续影响.
• 防范说明P261-P264-P270-P271-P280-P302+P352-P304+P340-P330-P362+P364-P405-P501
• 危险品标志Xi
• 安全声明H303May be harmful if swallowed+H313Skin contact may be harmful+H333Inhalation may be harmful to the body

欧盟法规

上下游产品

合成工艺路线路线简述

• 80-09-1 = 97042-18-7
  反应条件:1.1 Catalysts: Tetrabutylammonium Iodide,Sodium Iodide Solvents: Ethanol,Water; 2 H,Rt -> 80 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; 80 °C -> 25 °C; 2 H,25 °C
  标题:Chemical Synthesis Of Bisphenol S Monoallyl Ether From Bisphenol S And Chloropropylene
  参考文献:China]
  
  41481-63-4 = 97042-18-7
  反应条件:1.1 Reagents: Hydrochloric Acid
  标题:Synthesis And Biological Activity Of Some Ethers Of 4,4'-Dihydroxydiphenyl Sulfone
  作者:Pisanenko,D. A.; Novikov,I. N.; Grib,O. K.; Abramova,K. A.; Smirnov-Zamkov,Yu. I.; Et Al
  参考文献:Vestn. Kiev. Politekhn. In-Ta. Khim. Mashinostr. I Tekhnol. 日期:1984 卷标:(21) 页码:25-8]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Catalysts: Potassium Hydroxide,Sodium Hydroxide Solvents: Water; 100 °C; 100 °C -> 70 °C1.2 6 H,65 - 70 °C; 3 H,65 - 70 °C
  标题:Preparation Of 4-Hydrocarbyloxy-4'-Hydroxydiphenyl Sulfones
  参考文献:Japan]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 3 H,60 °C1.2 Reagents: Sodium Hydroxide Solvents: Water; 1 H,Ph 12,80 °C1.3 Reagents: Sulfuric Acid Solvents: Water; 1 H,Ph 9,80 °C; 1 H,30 °C
  标题:Developing Substance For Heat-Sensitive Recording And The Heat-Sensitive Recording Material
  参考文献:Japan]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide,Sodium Chloride; 6 H,60 °C; 9 H,60 °C1.2 Reagents: Sulfuric Acid Solvents: Water; Ph 1,60 °C; 1 H,80 °C; 1 H,65 °C
  标题:Preparation Of High-Purity 4,4'-Dihydroxydiphenyl Sulfone Monoethers
  参考文献:Japan]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water
  标题:Process For Producing Diphenyl Sulfone Compounds
  参考文献:World Intellectual Property Organization]
  
  = 97042-18-7 [标题:Reaction Conditions
  标题:Preparation Of 4,4'-Dihydroxydiphenyl Sulfone Diethers And 4,4'-Dihydroxydiphenyl Sulfone Monoethers
  参考文献:Japan]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Catalysts: Tetrabutylammonium Iodide,Sodium Iodide Solvents: Methanol,Water; Rt -> 78 °C; 2 H,78 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 7
  标题:Production Process For Improving Reaction Rate And Yield Of Bisphenol S Monoallyl Ether
  参考文献:China]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 8 H,0.8 - 1 Kg/cm2,55 - 60 °C; 1 H,80 °C1.2 85 - 90 °C1.3 Reagents: Sulfuric Acid Solvents: Water; Ph 8.9,90 °C -> 35 °C
  标题:Production Of Diphenyl Sulfone Compounds
  参考文献:World Intellectual Property Organization]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Triethylamine Solvents: Tetrahydrofuran; Rt -> 50 °C1.2 Solvents: Tetrahydrofuran; 2 H,50 °C; 4 H,50 °C
  标题:Enhanced Properties Of The Incorporation Of A Novel Reactive Phosphorus- And Sulfur-Containing Flame-Retardant Monomer Into Unsaturated Polyester Resin
  作者:Dai,Kang; Song,Lei; Yuen,Richard K. K.; Jiang,Saihua; Pan,Haifeng; Et Al
  参考文献:Industrial & Engineering Chemistry Research 日期:2012 卷标:51(49) 页码:15918-15926]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Water; 4 H,55 °C; 3 H,55 - 65 °C; 65 °C -> 80 °C1.2 Reagents: Hydrochloric Acid Solvents: Water; Ph 9
  标题:Thermal Printing Material Containing Sensitizer
  参考文献:Japan]
  
  80-09-1 = 97042-18-7
  反应条件:1.1 Reagents: Potassium Carbonate,Potassium Hydroxide Solvents: 1,2-Dichlorobenzene,Water; Rt -> 90 °C; 15 H,90 - 100 °C
  标题:Preparation Of High-Purity Dihydroxydiphenyl Sulfone Monoethers As Color Developers For Thermal Printing Materials
  参考文献:Japan]
  
  80-09-1 = 97042-18-7 + 41481-63-4
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Toluene,Water; 1 H,80 °C; 16 H,80 °C
  标题:Developer Composition Comprising Sulfone,Its Application,And Method For Producing The Same
  参考文献:Japan]
  
  80-09-1 = 97042-18-7 + 41481-63-4
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Methanol,Water; Rt -> 83 °C; 0.6 H,83 °C; 83 °C -> 52 °C1.2 2.4 H,52 °C; 2.5 H,52 °C
  标题:A Process For Preparing Bisphenol S (Di)Allyl Ether
  参考文献:China]
  
  80-09-1 = 97042-18-7 + 41481-63-4
  反应条件:1.1 Reagents: Sodium Hydroxide Solvents: Ethanol,Water; Ph 10.7,Rt1.2 Catalysts: Tetrabutylammonium Bromide; Heated; 5 H,60 °C; Cooled1.3 Reagents: Sulfuric Acid Solvents: Water; Ph 9.1
  标题:Process For Preparation Of Bisphenol S Diallyl And Monoallyl Ethers
  参考文献:China]
  
  80-09-1 = 97042-18-7 + 41481-63-4
  反应条件:1.1 Reagents: Bis(2-Chloroethyl) Ether,Sodium Hydroxide Solvents: Water; 110 °C; 6.5 H,110 °C1.2 Reagents: Hydrochloric Acid Solvents: Methanol,Water1.3 Reagents: Sodium Hydroxide Solvents: Water; Ph 7.4,Rt -> 60 °C1.4 60 °C; 6 H,60 °C
  标题:Recording Material Composition Comprising Crosslinked Diphenylsulfone Compound
  参考文献:World Intellectual Property Organization

海关参考信息

• 2901210000-乙烯
  2901220000-丙烯
  2908199090-其他酚的卤化衍生物
  2908999090-其他酚的硝化衍生物
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