CAS: 628-02-4; Hexanamide

相似化合物

142-81-4 7334-95-4 629-54-9

上下游产品

CAS号628-73-9 己腈 | CAS号111-26-2 正己胺 | CAS号66-25-1 正己醛 | CAS号142-62-1 正己酸 | CAS号111-27-3 正己醇 | CAS号2051-49-2 正已酸酐 | CAS号108724-16-9 N-羟基己脒 | CAS号142-61-0 己酰氯 | CAS号10601-70-4 N-acetylhexanamide | CAS号3954-13-0 异氰酸戊酯 | CAS号142-65-4 戊胺氯 | CAS号628-73-9 己腈 | CAS号927-49-1 二正戊基酮 | CAS号60-35-5 乙酰胺 | CAS号142-62-1 正己酸 | CAS号111-27-3 正己醇 | CAS号66-25-1 正己醛 | CAS号24003-67-6 Hexanoyl Glycine

📜己酸置于硼烷铵络合物体系中,用 5,5-Dimethyl-1,3-Cyclohexadiene 作为反应溶剂,化学反应 12.0H,以90%的收率获得产物己酰胺
参考文献:氨基硼烷作为直接酰胺化羧酸的双重用途试剂
标题:氨基硼烷作为直接酰胺化羧酸的双重用途试剂
摘要:胺-硼烷用作直接酰胺化的两用试剂,可活化脂肪族和芳香族羧酸,随后以高达99%的收率递送胺以提供相应的酰胺.气态或低沸点胺作为硼烷络合物的输送提供了优于现有方法的主要优势.利用含有硼烷不相容官能团的胺-硼烷可以制备官能化的酰胺.提出了通过三酰氧基硼烷-胺络合物的分子间机制.
DOI:10.1021/acs.Orglett.0C03184

专利信息

专利号:US-5736626-A
优先权日:1996-01-29
标题:Solid support reagents for the direct synthesis of 3'-labeled polynucleotides
发明人：MULLAH KHAIRUZZAMAN BASHAR; ANDRUS WILLIAM A
权利人:PERKIN ELMER CORP
摘要:The compounds of the invention are exemplified by the class of diglycolate synthesis supports particularly useful as support reagents for the direct synthesis of 3'-labeled polynucleotides. Generally, the compounds of the invention have the structure ##STR1## where T is an acid-cleavable hydroxyl protecting group, e.g., 4,4'-dimethoxytrityl; L 1 is a linker for connecting a 3'-terminal nitrogen to carbon; L 2 and L 3 are linkers for connecting oxygen and carbon; W is a solid support, e.g., CPG or polystyrene; L 4 is a linker for connecting the solid support to nitrogen; R 1 and R 2 are nitrogen substituents, e.g., hydrogen, lower alkyl, nitrogen protecting group, or label; and R 3 through R 7 are carbon substituents, e.g., hydrogen or lower alkyl. In a first particularly preferred embodiment, the synthesis supports of the invention are exemplified by compounds having the structure ##STR2## where DMT is 4,4'-dimethoxytrityl and W is polystyrene. In a second particularly preferred embodiment, the synthesis supports of the invention are exemplified by compounds having the structure ##STR3## where DMT and W are defined above.

专利号:US-10253153-B2
优先权日:2015-04-24
标题 :Linker and support for solid phase synthesis of nucleic acid, and production method of nucleic acid using said support
发明人：MAETA ERI; MORI KENJIRO; HORIE SHOHEI; ITO TAKAHIKO; SAITO SHOICHIRO; NAGAO RYUHEI
权利人:NITTO DENKO CORP
摘要:The present invention provides a linker for solid phase synthesis of nucleic acid, which consists of a compound represented by the formula (I) or the formula (II), a support for solid phase synthesis of nucleic acid, which has a structure represented by the formula (III), and a production method of a nucleic acid, which uses the support: n nwherein each symbol is as defined in the SPECIFICATION.

专利号:US-4938940-A
优先权日:1988-01-14
标 题:Vapor-phase method for synthesis of diamond
发明人：HIROSE YOICHI; KOMAKI KUNIO
权利人:HIROSE YOICHI; SHOWA DENKO KK
摘要:A method for vapor-phase synthesis of diamond comprises burning a raw material compound for synthesis of diamond thereby forming a combustion flame, disposing a substrate for deposition of diamond in said combustion flame, and keeping said substrate at a prescribed temperature, thereby inducing deposition of diamond on said substrate.

专利号:US-4242256-A
优先权日:1977-03-15
标 题 :Synthesis of peptide analogues
发明人：SHARPE ROBERT; SZELKE MICHAEL
权利人:SHARPE ROBERT; SZELKE MICHAEL
摘要:Compounds being analogues of a dipeptide in which the nitrogen atom of the linking amide group of the dipeptide is replaced by trivalent group ##STR1## and in which, optionally, the carbonyl function of this linking group is replaced by the divalent group --CH 2 -- are of value in the synthesis of isosterically modified peptides.

专利号:WO-2024208876-A1
优先权日:2023-04-03
标题 :Ductile polyamide with the in situ synthesis of a polyimide phase by reactive extrusion
发明人：CASSAGNAU PHILIPPE; DELAGE KARIM; BOUNOR-LEGARE VÉRONIQUE; MARESTIN CATHERINE; DUBOIS CHARLOTTE; GAROIS NICOLAS
权利人:TOTALENERGIES ONETECH; UNIV CLAUDE BERNARD LYON 1 UCBL; CENTRE NAT RECH SCIENT; UNIV JEAN MONNET SAINT ETIENNE UJM; INSTITUT NAT DES SCIENCES APPLIQUEES DE LYON INSA LYON
摘要:The disclosure relates to a ductile polyamide and to a process to produce a ductile polyamide comprising providing components comprising one or more polyamides, one or more dianhydrides, and one or more diamines; wherein the one or more polyamides are provided at a content of at least 60 wt.% based on the total weight of the components; and wherein the one or more polyamides comprise at least one polyamide having amide groups separated by less than 10 carbon atoms; performing in situ synthesis of a polyimide by reactive extrusion of the components wherein the residence time is less than 10 minutes; and recovering a polyamide-polyimide blend being a ductile polyamide comprising a continuous polyamide phase and a dispersed polyimide phase.

专利号:WO-9507882-A1
优先权日:1993-09-14
标 题:Synthesis of amido acids from carboxylic acid esters and amino acid salts
发明人：HEINZMAN STEPHEN WAYNE; DUPONT JEFFREY SCOTT
权利人:PROCTER & GAMBLE
摘要:Chemical synthesis of amido acids, and their conversion to amido acid phenyl ester sulfonates for use as bleach activators, starting from carboxylic acid esters and amino acid salts.