CAS: 56850-59-0; 3-Benzyloxy-2-Methyl-1-Propanol

上下游产品

((2-methylallyloxy)methyl)benzene Benzyl 3-(phenylmethoxy)-2-methylpropanoate 2-methyl-1.3-propanediol benzyl bromide (R)-3-(benzyloxy)-2-methylpropan-1-ol (S)-3-benzyloxy-2-methylpropan-1-ol (S)-3-benzyloxy-2-methylpropyl acetate (R)-3-benzyloxy-2-methylpropyl acetate

5-Methyl-2-Phenyl-1,3-Dioxane置于lithium Aluminium Tetrahydride,三氯化铝体系中,用 乙醚 作为反应溶剂,以92%的收率获得产物3-苄氧基-2-甲基-1-丙醇
参考文献:(+)-(R)-甲基对甲苯基亚砜与腈反应的手性β-酮亚砜的新型合成
标题:(+)-(R)-甲基对甲苯基亚砜与腈反应的手性β-酮亚砜的新型合成
摘要:通过与由(+)-(R)-甲基对甲苯基亚砜形成的阴离子反应和在水溶液中进行酸性后处理,腈官能团可有效地转化为β-酮亚砜部分.
DOI:10.1016/s0040-4039(99)01951-6

专利信息

专利号:US-4277610-A
优先权日:1975-01-27
标 题 :Synthesis of 2,6,10-trimethyl-undecan-1-ol
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of 2,6,10-trimethyl-undecan-1-ol, an intermediate for producing vitamin E, from methacrolein, crotonaldehyde, β-hydroxy-isobutyric acid including intermediates in this synthesis.

专利号:US-4151205-A
优先权日:1975-01-27
标题 :Synthesis of vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of vitamin E in racemic or optically active forms from methacryolein or beta-hydroxyisobutyric acid including intermediates in this synthesis.

专利号:US-4163021-A
优先权日:1975-01-27
标 题 :Synthesis of 2,6,10-trimethyl-undecan-1-ol
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of 2,6,10-trimethyl-undecan-1-ol, an intermediate for producing vitamin E, from methacrolein, crotonaldehyde, β-hydroxy-isobutyric acid including intermediates in this synthesis.

专利号:US-4041058-A
优先权日:1975-01-27
标题 :Synthesis of 2,6,10-trimethyl-undecan-1-ol
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of 2,6,10-trimethyl-undecan-1-ol, an intermediate for producing vitamin E, from methacrolein, crotonaldehyde, β-hydroxy-isobutyric acid including intermediates in this synthesis.

专利号:US-4051153-A
优先权日:1975-01-27
标题 :Intermediates in the synthesis of vitamin E
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of vitamin E in racemic or optically active forms from methacryolein or beta-hydroxyisobutyric acid including intermediates in this synthesis.

专利号:US-4169209-A
优先权日:1975-01-27
标 题 :Ethers of 2,6-dimethyl-octane-1,8-diols
发明人：COHEN NOAL; SAUCY GABRIEL
权利人:HOFFMANN LA ROCHE
摘要:A synthesis of 2,6,10-trimethyl-undecan-1-ol, an intermediate for producing vitamin E, from methacrolein, crotonaldehyde, β-hydroxy-isobutyric acid including intermediates in this synthesis.