📜四丙基锡置于ch3Cooh体系中,用 四氢呋喃 作为反应溶剂,化学反应生成 三正丙基锡乙酸酯 参考文献:Notes-Vinyl Derivatives Of The Metals. Vii. Preparation Of Organotin Esters By Cleavage Of Vinyltin Compounds 标题:Notes-Vinyl Derivatives Of The Metals. Vii. Preparation Of Organotin Esters By Cleavage Of Vinyltin Compounds 摘要: DOI:10.1021/jo01095A621
专利号:EP-0104197-B1 优先权日:1982-03-26 标题 :Process for the production of ethanol 摘要:Ethanol is produced by carbonylation of methanol by reaction with carbon monoxide in the presence of a carbonylation catalyst to form acetic acid which is then converted to an acetate ester followed by hydrogenolysis of the acetate ester formed to give ethanol or a mixture of ethanol and another alcohol which can be separated by distillation. Preferably the other alcohol or part of the ethanol recovered from the hydrogenolysis step is recycled for further esterification. Carbonylation can be effected using a CO/H2 mixture and hydrogenolysis can similarly be conducted in the presence of carbon monoxide, leading to the possibility of circulating gas between the carbonylation and hydrogenolysis zones with synthesis gas, preferably a 2:1 H2:CO molar mixture being used as make up gas.
摘要:Archives of Environmental Contamination and Toxicology., 14(111), 1985 [] 摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 1985. Acute oral toxicity and repellency of 933 chemicals to house and deer mice. Archives of Environmental Contamination and Toxicology 14:111-129. 摘要:Schafer, E. W., Jr., and W. A. Bowles Jr. 2004. Toxicity, Repellency of Phytotoxicity of 979 Chemicals to Birds, Mammals and Plants. Research Report No. 04-01. National Wildlife Research Center, Fort Collins, Colorado. 118 pp. https://www.aphis.usda.gov/ws/nwrc/chem-effects-db/U_schafer041_2004.pdf