CAS: 817-60-7; 2-Ethylheptan-1-Ol

上下游产品

2-ethylheptanoic acid formaldehyd 2-ethyl-1-hexene 3,6-diethyltetrahydro-2H-pyran-2-one 2-ethylheptanoic acid 2-ethylheptanal

📜3-Ethyl-5-Prop-(E)-Ylidene-5H-Furan-2-One置于(Acetylacetonato)Dicarbonylrhodium (L),Palladium On Activated Charcoal,Molybdenum Hexacarbonyl 氢气体系中,用 四氢呋喃,1,4-二氧六环 作为反应溶剂,60.0~180.0 °C,15.0 Mpa 条件下,反应 5.0H,反应生成 2-乙基庚烷-1-醇
参考文献:羧酸和内酯的双金属催化还原为醇和二醇
标题:羧酸和内酯的双金属催化还原为醇和二醇
摘要:研究了氢对羧酸的均相催化还原反应.由第8族或第9组晚过渡金属和第二族第6或7组过渡金属羰基组成的双金属催化剂具有协同作用,可在中等条件下以高收率转化.除了不同催化剂前体的影响外,还研究了温度,氢气压力和催化剂浓度的影响.[rh(acac)(co)2]和[mo(co)6的等摩尔混合物]显示出最高的活性,因此适用于将内酯还原为二醇.发现催化剂的还原电势取决于所用内酯的环大小.五元环内酯几乎不转化为二醇,而六元和七元环内酯则容易反应.
DOI:10.1002/1615-4169(200207)344:5<525::Aid-Adsc525>3.0.Co;2-U

专利信息

专利号:US-10000432-B2
优先权日:2014-01-13
标 题 :Processes for the synthesis of chiral 1-alkanols
发明人：NEGISHI EI-ICHI
权利人:PURDUE RESEARCH FOUNDATION
摘要:The invention relates to highly enantioselective processes for the synthesis of chiral 1-alkanols via Zr-catalyzed asymmetric carboalumination of alkenes.

专利号:US-4167513-A
优先权日:1977-09-06
标题 :Synthesis of unsaturated esters and lactone from butadiene and carbon dioxide
发明人：MUSCO ALFREDO; SANTI ROBERTO; CHIUSOLI GIAN P
权利人:MONTEDISON SPA
摘要:Octadienyl esters of 2-ethylidene-hepta-3,5-dienoic and 2-vinyl-hepta-3,5-dienoic acids of formula C 8 H 11 COOC 8 H 13 and δ-lactone of formula ##STR1## or 2-ethylidene-hepta-6-ene-5-olide, are prepared by reaction of 1,3-butadiene with CO 2 at a temperature comprised between about 20° and 150° C. and at a total pressure between about 10 and 500 atm in the presence of a phosphinic complex of palladium having the formula Pd[P(R) 3 ] x , wherein x is an integer from 2 to 4, and (R) 3 is a homogeneous or heterogeneous group consisting of alkyls, cycloalkyls having up to 8 carbon atoms and of phenyls, also substituted, in an inert atmosphere. n The obtained products are 'per se' new and are valuable intermediates for synthesis of chemicals (fungicides, pesticides, etc.) and in particular as effective plasticizers.

专利号:US-4451679-A
优先权日:1982-10-21
标题 :Alcohols and aldehydes prepared from olefins and synthesis gas
发明人：KNIFTON JOHN F; LIN JIANG-JEN; GRIGSBY JR ROBERT A; BRADER JR WALTER H
权利人:TEXACO INC
摘要:This invention concerns a process of preparing alcohols and aldehydes which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound dispersed in a low melting quaternary phosphonium or ammonium base or salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols and aldehydes.

专利号:US-4469895-A
优先权日:1982-10-21
标题 :Process for preparing alcohols from olefins and synthesis gas
发明人：KNIFTON JOHN F; GRIGSBY JR ROBERT A
权利人:TEXACO INC
摘要:This invention concerns an improved process of preparing predominantly linear alcohols which comprises the steps of contacting a mixture of terminal and/or internal olefins and synthesis gas with a catalyst system comprising a ruthenium-containing compound in conjunction with one or more tertiary amine promoters, dispersed in a low melting quaternary phosphonium salt and heating said resultant reaction mixture under a pressure of 100 psi or greater at a temperature of at least 50 DEG C. for a sufficient time to produce said alcohols.

专利号:EP-3679005-A2
优先权日:2017-06-12
标 题 :Synthesis of building blocks and feedstocks for manufacturing renewable polymers

专利号:EP-3094613-A1
优先权日:2014-01-13
标题:Processes for the synthesis of chiral 1-alkanols