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📜1-乙炔基-2-氟苯置于ammonia Borane体系中,用 甲醇 用作溶剂,化学反应生成2-氟苯乙烯
参考文献:金属-有机骨架中双金属纳米粒子上炔烃的化学和区域选择性加氢加速
标题:金属-有机骨架中双金属纳米粒子上炔烃的化学和区域选择性加氢加速
摘要:炔烃的选择性半氢化反应是一个长期而重要的目标,但仍然是一个巨大的挑战.在此,为此目的,已经合理地制造了金属-有机骨架(mof)中的双金属纳米粒子,即cupd @ Zif-8复合材料,具有立方cupd核和多孔zif-8壳.鉴于其独特的理化特性,Cu纳米立方体不仅可以将太阳能转化为热量以加速反应,而且还可以作为原位种子在其外表面形成pd纳米粒子(nps),以调节pd活性位点的化学选择性.Mof壳的额外生长有助于稳定cupd核并通过空间位阻效应提供区域选择性.氨硼烷提供了活性氢物质,可显着促进氢化作用并确保高选择性.结果,Cupd @ Mof表现出很高的效率,其转换频率(tof,6799 Min-1)是以前报告的5-10倍,高5倍,并且对炔烃的半氢化反应具有较高的化学和区域选择性.在室温下可见光照射下,存在nh 3 Bh 3作为氢源.
Doi:10.1021/acscatal.0C00177

专利信息

专利号:US-6475807-B1
优先权日:1996-04-08
标题:Mass-based encoding and qualitative analysis of combinatorial libraries
发明人：GEYSEN HENDRIK MARIO; KINDER DANIEL STUART; WAGNER CRAIG DANIEL
权利人:SMITHKLINE BEECHAM CORP
摘要:The insertion of isotopically labeled portions into solid state combinatorial synthesis constructs followed by mass spectrometer, mass-based nuclear magnetic resonance spectrometry or mass-based infrared spectrometry analysis allows for the physical, non-chemical encoding of large numbers of combinatorial synthesis products.

专利号:CN-104844534-A
优先权日:2015-05-20
标题 :A new method for the synthesis of 2,5-disubstituted oxazoles by cuprous catalyzed benzyl azide and styrene

专利号:US-2016186217-A1
优先权日:2013-06-13
标 题 :Method for biocatalytic synthesis of substituted or unsubstituted phenylacetic acids and ketones having enzymes of microbial styrene degradation

专利号:IT-SA20120007-A1
优先权日:2012-05-16
标题 :SYNTHESIS OF POLIALCHILSOLFONATI TO BE INTENDED FOR THE PRODUCTION OF IONOMERS AND POLYELETTROLITES BY SELECTIVE SULFONATION OF POLYDIENES AND COPOLYMERS OF CONJUGATED DIENS.

专利号:CN-106588811-B
优先权日:2016-12-07
标题 :A kind of method for asymmetric synthesis of chiral quaternary carbon center-containing benzolactone compounds

专利号:WO-2014198871-A2
优先权日:2013-06-13
标题 :Method for biocatalytic synthesis of substituted or unsubstituted phenylacetic acids and ketones having enzymes of microbial styrene degradation